Surface-enhanced Raman spectroscopy

Annual Review of Analytical Chemistry

Volumn 1, Issue 1, 2008, Pages 601-626

  Stiles, Paul L ^a   Dieringer, Jon A ^a   Shah, Nilam C ^a   Van Duyne, Richard P ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

Electromagnetic enhancement; Nanofabrication; Nanoparticles; Plasmonics; Sensing; Vibrational spectroscopy

Indexed keywords

ANALYTICAL TOOL; BIOLOGICAL MOLECULE; DETECTION OF CHEMICALS; ELECTROMAGNETIC ENHANCEMENT; FUNDAMENTAL FEATURES; LOCALIZED SURFACE PLASMON RESONANCE; METAL FILM OVER NANOSPHERE; METAL ISLAND FILMS; NANO SPHERE LITHOGRAPHY; NANOFABRICATION; NANOSTRUCTURED SURFACE; PLASMONICS; SERS SUBSTRATE; SURFACE CHARACTERISTICS; SURFACE ENHANCED RAMAN SPECTROSCOPY;

CHEMICAL DETECTION; CHEMICAL WARFARE; CONTROL SURFACES; NANOPARTICLES; NANOSPHERES; PLASMONS; RAMAN SCATTERING; RAMAN SPECTROSCOPY; SUBSTRATES; SURFACE CHEMISTRY; SURFACE PLASMON RESONANCE; VIBRATIONAL SPECTROSCOPY;

SURFACES;

CHEMICAL WARFARE AGENT; ION; METAL; NANOPARTICLE;

ANIMAL; CHEMICAL MODEL; CHEMISTRY; CYCLOTRON; ELECTROMAGNETIC FIELD; HUMAN; METHODOLOGY; NANOTECHNOLOGY; RADIATION SCATTERING; RAMAN SPECTROMETRY; REVIEW; SURFACE PLASMON RESONANCE; SURFACE PROPERTY;

ANIMALS; CHEMICAL WARFARE AGENTS; CYCLOTRONS; ELECTROMAGNETIC PHENOMENA; HUMANS; IONS; METALS; MODELS, CHEMICAL; NANOPARTICLES; NANOTECHNOLOGY; SCATTERING, RADIATION; SPECTRUM ANALYSIS, RAMAN; SURFACE PLASMON RESONANCE; SURFACE PROPERTIES;

EID: 60849092056     PISSN: 19361327     EISSN: 19361335     Source Type: Book Series    
DOI: 10.1146/annurev.anchem.1.031207.112814     Document Type: Review

References (88)

1. Jeanmarie DL, Van Duyne RP. 1977. Surface Raman spectroelectrochemistry, part 1: heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. J. Electroanal. Chem. 84:120
2. Albrecht MG, Creighton JA. 1977. Anomalously intense Raman spectra of pyridine at a silver electrode. J. Am. Chem. Soc. 99:5215-5217
3. Campion A, Kambhampati P. 1998. Surface-enhanced Raman scattering. Chem. Soc. Rev. 27:241-250
4. Kneipp K, Kneipp H, Itzkan I, Dasari RR, Feld MS. 1999. Surface-enhanced Raman scattering: a new tool for biomedical spectroscopy. Curr. Sci. 77:915-924
5. Moskovits M. 1985. Surface-enhanced spectroscopy. Rev. Mod. Phys. 57:783-826
6. Stuart DA, Yonzon CR, Zhang XY, Lyandres O, Shah NC, et al. 2005. Glucose sensing using near-infrared surface-enhanced Raman spectroscopy: gold surfaces, 10-day stability, and improved accuracy. Anal. Chem. 77:4013-4019
7. Braun G, Lee SJ, Dante M, Nguyen TQ, Moskovits M, Reich N. 2007. Surfaceenhanced Raman spectroscopy for DNA detection by nanoparticle assembly onto smooth metal films. J. Am. Chem. Soc. 129:6378-6379
8. Braun G, Pavel I, Morrill AR, Seferos DS, Bazan GC, et al. 2007. Chemically patterned microspheres for controlled nanoparticle assembly in the construction of SERS hot spots. J. Am. Chem. Soc. 129:7760-7761
9. Ren B, Liu GK, Lian XB, Yang ZL, Tian ZQ. 2007. Raman spectroscopy on transition metals. Anal. Bioanal. Chem. 388:29-45
10. Chen LC, Ueda T, Sagisaka M, Hori H, Hiraoka K. 2007. Visible laser desorption/ ionization mass spectrometry using gold nanorods. J. Phys. Chem. C 111:2409-2415
11. Willets KA, Van Duyne RP. 2007. Localized surface plasmon resonance spectroscopy and sensing. Annu. Rev. Phys. Chem. 58:267-297
12. Schatz GC, Young MA, Van Duyne RP. 2006. Electromagnetic mechanism of SERS. See Ref. 88, pp. 19-45
13. Kneipp K, Kneipp H, Bohr HG. 2006. Single-molecule SERS spectroscopy. See Ref. 88, pp. 261-277
14. Kneipp J. 2006. Nanosensors based on SERS for applications in living cells. See Ref. 88, pp. 335-349
15. Yonzon CR, Lyandres O, Shah NC, Dieringer JA, Van Duyne RP. 2006. Glucose sensing with surface-enhanced Raman spectroscopy. See Ref. 88, pp. 367-379 (Pubitemid 44406330)
16. Vo-Dinh T, Yan F,Wabuyele MB. 2006. Surface-enhanced Raman scattering for biomedical diagnostics and molecular imaging. See Ref. 88, pp. 409-426
17. Stuart DA, Biggs KB, Van Duyne RP. 2006. Surface-enhanced Raman spectroscopy of half-mustard agent. Analyst 131:568-572
18. Stokes DL, Alarie JP, Ananthanarayanan V, Vo-Dinh T. 1999. Fiber optic SERS sensor for environmental monitoring. Proc. SPIE. 3534:647-654
19. Kundu S, Mandal M, Ghosh SK, Pal T. 2004. Photochemical deposition of SERS active silver nanoparticles on silica gel and their application as catalysts for the reduction of aromatic nitro compounds. Journal of Colloid and Interface Science. 272:134-144
20. Sylvia JM, Janni JA, Klein JD, Spencer KM. 2000. Surface-enhanced Raman detection of 2,4-dinitrotoluene impurity vapor as a marker to locate landmines. Anal. Chem. 72:5834-5840
21. Fleischmann M, Hendra PJ, McQuillan AJ. 1974. Raman spectra of pyridine adsorbed at a silver electrode. Chem. Phys. Lett. 26:163-166
22. Kerker M. 1984. Electromagnetic model for surface-enhanced Raman-scattering (SERS) on metal colloids. Acc. Chem. Res. 17:271-277
23. Metiu H, Das P. 1984. The electromagnetic theory of surface enhanced spectroscopy. Annu. Rev. Phys. Chem. 35:507-536
24. Moskovits M. 2005. Surface-enhanced Raman spectroscopy: a brief retrospective. J. Raman Spectrosc. 36:485-496
25. Schatz GC, Van Duyne RP. 2002. Electromagnetic mechanism of surfaceenhanced spectroscopy. In Handbook of Vibrational Spectroscopy, ed. JM Chalmers, PR Griffiths, pp. 759-774 New York:Wiley
26. Dick LA, McFarland AD, Haynes CL, Van Duyne RP. 2002. Metal film over nanosphere (MFON) electrodes for surface-enhanced Raman spectroscopy (SERS): improvements in surface nanostructure stability and suppression of irreversible loss. J. Phys. Chem. B 106:853-860
27. Jensen TR, MalinskyMD,Haynes CL,Van Duyne RP. 2000. Nanosphere lithography: tunable localized surface plasmon resonance spectra of silver nanoparticles. J. Phys. Chem. B 104:10549-10556
28. Malinsky MD, Kelly KL, Schatz GC, Van Duyne RP. 2001. Nanosphere lithography: effect of substrate on the localized surface plasmon resonance spectrum of silver nanoparticles. J. Phys. Chem. B 105:2343-2350
29. Zhang X, Young MA, Lyandres O, Van Duyne RP. 2005. Rapid detection of an anthrax biomarker by surface-enhanced Raman spectroscopy. J. Am. Chem. Soc. 127:4484-4489
30. Lyandres O, Shah NC, Yonzon CR, Walsh JT, Glucksberg MR, Van Duyne RP. 2005. Real-time glucose sensing by surface-enhanced Raman spectroscopy in bovine plasma facilitated by a mixed decanethiol/mercaptohexanol partition layer. Anal. Chem. 77:6134-6139
31. Nie SM, Emery SR. 1997. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275:1102-1106
32. Kneipp K, Wang Y, Kneipp H, Perelman LT, Itzkan I, et al. 1997. Single molecule detection using surface-enhanced Raman scattering (SERS). Phys. Rev. Lett. 78:1667-1670
33. Haynes CL, Van Duyne RP. 2003. Plasmon-sampled surface-enhanced Raman excitation spectroscopy. J. Phys. Chem. B 107:7426-7433
34. McFarland AD, Young MA, Dieringer JA, Van Duyne RP. 2005. Wavelengthscanned surface-enhanced Raman excitation spectroscopy. J. Phys. Chem. B 109:11279-11285
35. Dieringer JA, McFarland AD, Shah NC, Stuart DA, Whitney AV, et al. 2005. Surface enhanced Raman spectroscopy: new materials, concepts, characterization tools, and applications. Faraday Discuss. 132:9-26
36. Kennedy BJ, Spaeth S, Dickey M, Carron KT. 1999. Determination of the distance dependence and experimental effects for modified SERS substrates based on self-assembled monolayers formed using alkanethiols. J. Phys. Chem. B 103:3640-3646
37. Yang W-H, Schatz GC, Van Duyne RP. 1995. Discrete dipole approximation for calculating extinction and Raman intensities for small particles with arbitrary shapes. J. Chem. Phys. 103:869-875
38. Zeman EJ, Schatz GC. 1987. An accurate electromagnetic theory study of surface enhancement factors for silver, gold, copper, lithium, sodium, aluminum, gallium, indium, zinc, and cadmium. J. Phys. Chem. 91:634-643
39. Kelly KL, Coronado E, Zhao L, Schatz GC. 2003. The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J. Phys. Chem. B 107:668-677
40. Kreibig U, Vollmer M. 1995. Optical Properties of Metal Clusters. Berlin: Springer
41. Bohren CR, Huffman DF. 1983. Absorption and Scattering of Light by Small Particles. New York:Wiley
42. Mie G. 1908. Contributions to the optics of turbid media, especially colloidal metal solutions. Ann. Phys. 25:377-445
43. Link S, El-Sayed MA. 1999. Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nano-dots and nano-rods. J. Phys. Chem. B 103:8410-8426
44. Purcell EM, Pennypacker CR. 1973. Scattering and absorption of light by nonspherical dielectric grains. Astrophys. J. 186:705-714
45. Draine BT, Flatau PJ. 1994. Discrete-dipole approximation for scattering calculations. J. Opt. Soc. Am. A 11:1491-1499
46. Taflove A. 1995. Computational Electrodynamics: The Finite-Difference Time Domain Method. Boston: Artech House
47. McCreery RL. 2000. Raman Spectroscopy for Chemical Analysis. New York:Wiley Intersci. 420 pp.
48. Kerker M, Wang DS, Chew H. 1980. Surface enhanced Raman-scattering (SERS) by molecules adsorbed at spherical particles. Appl. Opt. 19:4159-4174
49. Wang DS, Kerker M. 1981. Enhanced Raman scattering by molecules adsorbed at the surface of colloidal spheroids. Phys. Rev. B 24:1777-1790
50. Van Duyne RP. 1979. Laser excitation of Raman scattering from adsorbed molecules on electrode surfaces. Chem. Biochem. Appl. Lasers 4:101-185
51. Dick LA, Haes AJ,Van Duyne RP. 2000. Distance and orientation dependence of heterogeneous electron transfer: a surface-enhanced resonance Raman scattering study of cytochrome c bound to carboxylic acid terminated alkanethiols adsorbed on silver electrodes. J. Phys. Chem. B 104:11752-11762
52. Whitney AV, Elam JW, Zou SL, Zinovev AV, Stair PC, et al. 2005. Localized surface plasmon resonance nanosensor: a high-resolution distance-dependence study using atomic layer deposition. J. Phys. Chem. B 109:20522-20528
53. Blatchford CG, Campbell JR, Creighton JA. 1982. Plasma resonance enhanced Raman scattering by adsorbates on gold colloids: the effects of aggregation. Surf. Sci. 120:435-455
54. Felidj N, Aubard J, Levi G, Krenn JR, Hohenau A, et al. 2003. Optimized surfaceenhanced Raman scattering on gold nanoparticle arrays. Appl. Phys. Lett. 82:3095-3097
55. Vlckova B, Gu XJ, Moskovits M. 1997. SERS excitation profiles of phthalazine adsorbed on single colloidal silver aggregates as a function of cluster size. J. Phys. Chem. B 101:1588-1593
56. Doron-Mor I, Barkay Z, Filip-Granit N, Vaskevich A, Rubinstein I. 2004. Ultrathin gold island films on silanized glass: morphology and optical properties. Chem. Mater. 16:3476-3483
57. Pieczonka NPW, Aroca RF. 2005. Inherent complexities of trace detection by surface-enhanced Raman scattering. Chemphyschem 6:2473-2484
58. Haynes CL, Van Duyne RP. 2001. Nanosphere lithography: a versatile nanofabrication tool for studies of size-dependent nanoparticle optics. J. Phys. Chem. B 105:5599-5611
59. Hicks EM, Zhang XY, Zou SL, Lyandres O, Spears KG, et al. 2005. Plasmonic properties of film over nanowell surfaces fabricated by nanosphere lithography. J. Phys. Chem. B 109:22351-22358
60. Baker GA, Moore DS. 2005. Progress in plasmonic engineering of surfaceenhanced Raman-scattering substrates toward ultra-trace analysis. Anal. Bioanal. Chem. 382:1751-1770
61. Aroca RF, Alvarez-Puebla RA, Pieczonka N, Sanchez-Cortez S, Garcia-Ramos JV. 2005. Surface-enhanced Raman scattering on colloidal nanostructures. Adv. Colloid Interface Sci. 116:45-61
62. Kneipp K, Kneipp H, Kneipp J. 2006. Surface-enhanced Raman scattering in local optical fields of silver and gold nanoaggregates: from single-molecule Raman spectroscopy to ultrasensitive probing in live cells. Acc. Chem. Res. 39:443-450
63. He L, Musick MD, Nicewarner SR, Salinas FG, Benkovic SJ, et al. 2000. Colloidal Au-enhanced surface plasmon resonance for ultrasensitive detection of DNA hybridization. J. Am. Chem. Soc. 122:9071-9077
64. Felidj N, Truong SL, Aubard J, Levi G, Krenn JR, et al. 2004. Gold particle interaction in regular arrays probed by surface enhanced Raman scattering. J. Chem. Phys. 120:7141-7146
65. Gunnarsson L, Bjerneld EJ, Xu H, Petronis S, Kasemo B, Kall M. 2001. Interparticle coupling effects in nanofabricated substrates for surface-enhanced Raman scattering. Appl. Phys. Lett. 78:802-804
66. Haes AJ, Haynes CL, McFarland AD, Schatz GC,Van Duyne RR, Zou SL. 2005. Plasmonic materials for surface-enhanced sensing and spectroscopy. MRS Bull. 30:368-375
67. 2-, and pyridine. J. Phys. Chem. B 88:5290-5296
68. Fornasiero D, Grieser F. 1987. Analysis of the visible absorption and SERS excitation spectra of silver sols. J. Chem. Phys. 87:3213-3217
69. Carron K, Peitersen L, Lewis M. 1992. Octadecylthiol-modified surfaceenhanced Raman spectroscopy substrates: a new method for the detection of aromatic compounds. Environ. Sci. Technol. 26:1950-1954
70. Ishida T, Hara M, Kojima I, Tsuneda S, Nishida N, et al. 1998. High resolution X-ray photoelectron spectroscopy measurements of octadecanethiol selfassembled monolayers on Au(111). Langmuir 14:2092-2096
71. Zhang ZS,Wilson OM, Efremov MY, Olson EA, Bruan PV, et al. 2004. Heat capacity measurements of two-dimensional self-assembled hexadecanethiol monolayers on polycrystalline gold. Appl. Phys. Lett. 84:5198-5200
72. Lewis M, Tarlov M, Carron K. 1995. Study of the photooxidation process of self-assembled alkanethiol monolayers. J. Am. Chem. Soc. 117:9574-9575
73. Schoenfisch MH, Pemberton JE. 1998. Air stability of alkanethiol self-assembled monolayers on silver and gold surfaces. J. Am. Chem. Soc. 120:4502-4513
74. Zhang Y, Terrill RH, Tanzer TA, Bohn PW. 1998. Ozonolysis is the primary cause of UV photooxidation of alkanethiolate monolayers at low irradiance. J. Am. Chem. Soc. 120:2654-2655
75. Love JC, Estroff LA, Kriebel JK, Nuzzo RG, Whitesides GM. 2005. Selfassembled monolayers of thiolates on metals as a form of nanotechnology. Chem. Rev. 105:1103-1169
76. King F. 1987. Aluminum and Its Alloys. New York: Ellis Harwood. 313 pp.
77. Zhang X, Zhao J, Whitney A, Elam J,Van Duyne RP. 2006. Ultrastable substrates for surface-enhanced Raman spectroscopy fabricated by atomic layer deposition: improved anthrax biomarker detection. J. Am. Chem. Soc. 128:10304-10309
78. Stuart DA, Yuen JM, Shah NC, Lyandres O, Yonzon CR, et al. 2006. In vivo glucose measurement by surface-enhanced Raman spectroscopy. Anal. Chem. 78:7211-7215 (Pubitemid 44607565)
79. Shah NC, Lyandres O, Walsh JT, Glucksberg MR, Van Duyne RP. 2007. Lactate and sequential lactate-glucose sensing using surface-enhanced Raman spectroscopy. Anal. Chem. 79:6927-6932
80. Abdelsalam ME, Mahajan S, Bartlett PN, Baumberg JJ, Russell AE. 2007. SERS at structured palladium and platinum surfaces. J. Am. Chem. Soc. 129:7399-7406
81. Mrozek MF, Xie Y, Weaver MJ. 2001. Surface-enhanced Raman scattering on uniform platinum-group overlayers: preparation by redox replacement of underpotential-deposited metals on gold. Anal. Chem. 73:5953-5960
82. Tian ZQ, Yang ZL, Ren B, Li JF, Zhang Y, et al. 2006. Surface-enhanced Raman scattering from transition metals with special surface morphology and nanoparticle shape. Faraday Discuss. 132:159-170
83. Park S, Yang PX, Corredor P, Weaver MJ. 2002. Transition metal-coated nanoparticle films: vibrational characterization with surface-enhanced Raman scattering. J. Am. Chem. Soc. 124:2428-2429
84. Litorja M, Haynes CL, Haes AJ, Jensen TR, Van Duyne RP. 2001. Surfaceenhanced Raman scattering detected temperature programmed desorption: optical properties, nanostructure, and stability of silver film over SiO2 nanosphere surfaces. J. Phys. Chem. B 105:6907-6915
85. Hulteen JC, Young MA, Van Duyne RP. 2006. Surface-enhanced hyper-Raman scattering (SEHRS) on Ag film over nanosphere (FON) electrodes: surface symmetry of centrosymmetric adsorbates. Langmuir 22:10354-10364
86. Cotton TM, Schultz SG, Van Duyne RP. 1980. Surface-enhanced resonance Raman-scattering from cytochrome c and myoglobin adsorbed on a silver electrode. J. Am. Chem. Soc. 102:7960-7962
87. Copeland RA, Fodor SPA, Spiro TG. 1984. Surface-enhanced Raman spectra of an active flavo enzyme: glucose oxidase and riboflavin binding protein on silver particles. J. Am. Chem. Soc. 106:3872-3874
88. Kneipp K, Moskovits M, Kneipp H, eds. 2006. Surface-Enhanced Raman Scattering: Physics and Applications. Berlin: Springer