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The use of silica from Acros resulted in a complete deprotection whereas partial deprotection was observed with silica from Merck
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The use of silica from Acros resulted in a complete deprotection whereas partial deprotection was observed with silica from Merck.
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The common correction used to determine the CS state energy level in an a polar solvent from the values of the redox potentials in a polar solvent takes into account the Coulombic interaction term and the ion solvation energy based on the Born dielectric continuum model according to Weller (ref, 31, The energy of the charge-separated states relative to the ground state, ΔGCS, can thus be calculated by the following equation; ΔGCS, Eox, Ered, 14.32/R DAεS, 14.32(1/2rD+1/2r A)(1/εS, 1/εP) For the formation of the charge-separated state involving the transfer of an electron from the corrole to the perylene bisimide, Eox and Ered are the first oxidation potential of the corrole and the first reduction potential of perylene bisimide. respectively, which are +0.72 V versus SCE for C2, 0.86 V versus SCE for C3
-
D = 6 Å.
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The oxidation potential of PI0 in acetonitrile is of the order of + 1.6 V versus SCE and the reduction potential of corroles C2 and C3 are of the order of -0.75 V and -0.65 V versus SCE. respectively, in benzonitrile (M. Cembor, J. S. Jaworski, private communication), which would leave the CS energy level at about 1.7 eV after correction for the polarity of the solvent.
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