Photophysical properties of a rhodium tetraphenylporphyrin-tin corrole dyad. The first example of a through metal-metal bond energy transfer

Photochemistry and Photobiology

Volumn 82, Issue 1, 2006, Pages 171-176

  Poulin, Jason ^a   Stern, Christine ^b   Guilard, Roger ^b   Harvey, Pierre D ^a  

^a UNIVERSITÉ DE SHERBROOKE   (Canada)

^b UNIVERSITÉ DE BOURGOGNE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

METAL; METALLOPORPHYRIN; RHODIUM; TETRAPHENYLPORPHYRIN TIN;

CHEMISTRY; CONFERENCE PAPER; ENERGY TRANSFER; PHOTOCHEMISTRY; SPECTROPHOTOMETRY;

ENERGY TRANSFER; METALLOPORPHYRINS; METALS; PHOTOCHEMISTRY; RHODIUM; SPECTROPHOTOMETRY;

EID: 33644770533     PISSN: 00318655     EISSN: None     Source Type: Journal    
DOI: 10.1562/2005-06-16-RA-577     Document Type: Conference Paper

References (33)

1. Faure, S., C. Stern, R. Guilard and P. D. Harvey (2004) Role of the spacer in the singlet-singlet ET mechanism (Förster vs Dexter) in cofacial bisporphyrins. J. Am. Chem. Soc. 126, 1253-1261.
2. Faure, S., C. Stern, E. Espinosa, J. Douville, R. Guilard and P. D. Harvey (2005) Triplet-triplet ET controlled by the D-A distance in rigidly held palladium-containing cofacial bisporphyrins. Chem. Eur. J. 11, 3469-3481.
3. Chang, C. J., E. A. Baker, B. J. Pistorio, Y. Deng, Z.-H. Loh, S. E. Miller, S. D. Carpenter and D. G. Nocera (2002) Structural, spectroscopic, and reactivity comparison of xanthene- and dibenzofuran-bridged cofacial bisporphyrins. Inorg. Chem. 41, 3102-3109.
4. Bolze, F., C. P. Gros, M. Drouin, E. Espinosa, P. D. Harvey and R. Guilard (2002) Fine tuning of the photophysical properties of cofacial diporphyrins via the use of different spacers. J. Organomet. Chem. 643-644, 89-97.
5. Bolze, F., M. Drouin, P. D. Harvey, C. P. Gros, E. Espinosa and R. Guilard (2003) X-ray structures and luminescence properties of Co(II) and Co(III) complexes of cofacial diporphyrins. J. Porphyrins Phthalocyanines 7, 474-483.
6. Förster, T. (1946) Energiewanderung und Fluorescenz. Naturwissenschaften 33, 166-175.
7. Förster, T. (1948) Zwischenmolekulare Energiewanderung und Fluoreszenz. Ann. Phys. 2, 55-73.
8. Dexter, D. L. (1953) A theory of sensitized luminescence in solids. J. Chem. Phys. 21, 836-850.
9. Balaban, T. S. (2004) Light-harversting hanostructures. In Encyclopedia of Nanoscience and Nanotechnology, Vol. 4, 505-559. American Scientific Publishers, Stevenson Ranch, CA.
10. Valeur, B. (2002) Molecular Fluorescence, Principles and Applications. Wiley-VCH, Weinheim, Germany.
11. Tremblay-Morin, J.-P., S. Faure, D. Samar, C. Stern, R. Guilard and P. D. Harvey (2005) Synthesis, characterization and photophysical properties of a free base and a biszinc(II) complex of 1,3-bisporphyrincalix[4]arene: evidence for "tunable intramolecular open and close conformations". Inorg. Chem. 44, 2836-2842.
12. See for example (2003) The Porphyrin Handbook (Edited by K. M. Kadish, K. M. Smith and R. Guilard) and the references therein. Academic Press, San Diego.
13. Barbe, J.-M., G. Morata, E. Espinosa and R. Guilard (2003) Synthesis of new singly M-M′-bonded heterobinuclear complexes involving a porphyrin and a corrole. X-ray structure of the rhodium tetraphenylporphyrin-tin(2,3,7,13,17, 18-hexamethyl-8,12-diethylcorrole) complex. J. Porphyrins Phthalocyanines 7, 120-124.
14. Seybold, P. G. and M. Gouterman (1969) Porphyrins XIII. Fluorescence spectra and quantum yields. J. Mol. Spectrosc. 31, 1-13.
15. Gouterman, M. (1978) Optical spectra and electronic structure of porphyrins and related rings. In The Porphyrins. Vol. III. (Edited by D. Dolphin), pp. 1-165. Academic Press, New York.
16. Strachan, J.-P., S. Gentemann, J. Seth, W. A. Kalsbeck, J. S. Lindsey, D. Holten and D. F. Bocian (1997) Effects of orbital ordering on electronic communication in multiporphyrin arrays. J. Am. Chem. Soc. 119, 11191-11201.
17. Harriman, A. (1981) Luminescence of porphyrins and metalloporphyrins. Part 3. Heavy atom effects. J. Chem. Soc., Faraday Trans. 2 77, 1281-1291
18. Murov, S. L., I. Carmichael and G. L. Hug (1993) Handbook of Photochemistry. Marcel Dekker, New York.
19. Lux, D., D. Daphnomili and A. G. Coutsolelos (1994) Action of alkyl halides on homo- and hetero-porphyrin dimers involving a rhodium-indium bond, producing porphyrin complexes containing metal-carbon and metal-halide bonds. Polyhedron 13, 2367-2377.
20. Coutsolelos, A. G., D. Lux and E. Mikros (1996) Synthesis and characterization of homo- and heteroporphyrin dimers involving a rhodium-indium bond. Polyhedron 15, 705-715.
21. Coutsolelos, A. G., D. Daphnomili, W. R. Scheidt and G. Ferraudi (1998) Photogeneration of monomeric porphyrins from the (tetraphenylporphyrin)Rh- In(octaethylporphyrin) dissociation of the Rh-In bond: investigation of their reactions in the picosecond-microsecond time domain. Inorg. Chem. 37, 2077-2079.
22. Paolesse, R., F. Sagone, A. Macagnano, T. Boschi, L. Prodi, M. Montalti, N. Zaccheroni, F. Bolletta and K. M. Smith (1999) Photophysical behaviour of corroie and its symmetrical and unsymmetrical dyads. J. Porphyrins Phthalocyanines 3, 364-370.
23. Gross, Z., N. Galili and I. Saltsman (1999) The first direct synthesis of corroies from pyrrole. Angew. Chem., Int. Ed. 38, 1427-1429.
24. Bendix, J., I. J. Dmochowski, H. B. Gray, A. Mahammed, L. Simkhovich and Z. Gross (2000) Structural, electrochemical, and photophysical properties of gallium(III) 5,10,15-tris(pentafluorophenyl)corrole. Angew. Chem., Int. Ed. 39, 4048-4051.
25. Weaver, J. J., K. Sorasaenee, M. Sheikh, R. Goldschmidt, E. Tkachenko, Z. Gross and H. B. Gray (2004) Gallium(III) corroles. J. Porphyrins Phthalocyanines 8, 76-81.
26. Hanson, L. K., M. Gouterman and J. C. Hanson (1973) Porphyrins. XXIX. Crystal and molecular structure and luminescence of bis(dimethylamine)etio(I) porphinatorhodium(III) chloride dihydrate. J. Am. Chem. Soc. 95, 4822-4829.
27. Kalyanasundaram, K. (1984) Luminescence and triplet-triplet absorption spectra of rhodium (III) porphyrins. Chem. Phys. Lett. 104, 357-362.
28. Vitols, S. E., D. A. Friesen, D. S. Williams, D. Melamed and T. G. Spiro (1996) Excited state dynamics of Rh(II) tetramesityl porphyrin monomer from nanosecond transient absorption and emission spectroscopy. J. Phys. Chem. 100, 207-213.
29. Vasil'ev, V. V., S. M. Borisov and I. V. Golovina (2003) Luminescence of water-soluble Rh(III) porphyrins. Opt. Spectrosc. 95, 29-34.
30. Vasil'ev, V. V., S. M. Borisov, A. Maldotti and A. Molinari (2003) Spectral properties of cationic water-soluble metallo-porphyrins immobilized in a perfluorosulfonated ion-exchange membrane. J. Porphyrins Phthalocyanines 7, 780-786.
31. Borisov, S. M. and V. V. Vasil'ev (2004) New optical sensors for oxygen based on phosphorescent cationic water-soluble Pd(II), Pt(II), and Rh(III) porphyrins. J. Anal. Chem. 59, 155-159.
32. Bolze, F., C. P. Gros, P. D. Harvey and R. Guilard (2001) Luminescence properties of a cofacial dipalladium porphyrin dimer under argon and in the presence of dioxygen. J. Porphyrins Phthalocyanines 5, 569-574.
33. Prodi, A., M. T. Indelli, C. J. Kleverlaan, F. Scandola, B. Alessio, T. Gianferrara and L. G. Marzilli (1999) Side-to-face ruthenium porphyrin arrays: photophysical behavior of dimeric and pentameric systems. Chem. Eur. J. 5, 2668-2679.