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-
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33751308061
-
-
note
-
298 value of A was previously reported as -6.1 kcal/mol [12]. This time, slightly more stable C-O single bond rotamer was obtained.
-
-
-
-
32
-
-
33751309014
-
-
note
-
2 was used as a solvent, no formation of Si(1 1 1)-Cl was detected by XPS spectra (Cl 2p (200 eV) and Cl 2s (270 eV)) of the surfaces S1d, S1e and S2.
-
-
-
-
33
-
-
33751308783
-
-
note
-
For the reaction of Si(1 1 1)-H with 2b, formation of the surface S1b was assumed from the model reaction result. The reaction of 1 and 2b gave 3b as major product and no O-silylated product was identified. However, because of the reported results of competing reactions of Si(1 1 1)-H with C{double bond, long}C and OH groups [4c] and formation of Si-OR by thermal reaction of Si(1 1 1)-H and alcohols, [41] a close analysis of the surface will be needed to rule out the reaction of the OH groups with the Si-H bonds.
-
-
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34
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0001722531
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Zhang J., Cui C.Q., Lim T.B., Kang E.-T., Neoh K.G., Lim S.L., and Tan K.L. Chem. Mater. 11 (1999) 1061
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35
-
-
33751350778
-
-
note
-
The conflicting intensity of C-C and C{double bond, long}O in C 1s peak of XPS spectra for surface S2 may arise from contaminated carbon. The coverage ratio for S2 was estimated by C 1s (C{double bond, long}O) peak.
-
-
-
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36
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0029941832
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Lee E.J., Bitner T.W., Ha J.S., Shane M.J., and Sailor M.J. J. Am. Chem. Soc. 118 (1996) 5375
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33751322279
-
-
note
-
x may include silicon oxidation both on the surface and under the surface (formation of silicon oxide layer in partial area).
-
-
-
-
41
-
-
33751310020
-
-
note
-
3) leading to 14% coverage ratio was reported [8]. The comparable low coverage for S2 may also arise from the surface steric factor.
-
-
-
-
42
-
-
33751345972
-
-
note
-
The surface reaction does not require an explicit radical initiator or high reaction temperature, similar to the reaction of Si(1 1 1) with propiolate esters or tris(trimethylsilyl)silane with propiolate esters [12,8]. According to the proposed mechanism for the reaction of tris(trimethylsilyl)silane with propiolate esters [8] autoxidation of surface Si-H group by contaminated molecular oxygen to generate a silicon radical on the surface may be the speculative initial step of the total radical chain reaction.
-
-
-
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43
-
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33751323803
-
-
note
-
In order to examine the role of charge carriers and obtain some insight into the reaction mechanisms, the reaction of p-type Si(1 1 1)-H with trifluoroethyl propiolate was carried out. The reaction gave a 46% coverage ratio by F1s XPS spectra. We believe the value is similar to that of n-Si(1 1 1) within the experimental error and the effect of charge carriers may be small [42].
-
-
-
-
44
-
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0032021791
-
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Sieval A.B., Damirel A.L., Nissink J.W.M., Linford M.R., van der Maas J.H., de Jeu W.H., Zuilhof H., and Sudhölter E.J.R. Langmuir 14 (1998) 1759
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33751339626
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54
-
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33751326011
-
-
note
-
x = 0.87).
-
-
-
-
55
-
-
33751348170
-
-
note
-
3 gave the surface with 38% coverage by XPS. Further study on application to various surfaces is planned in due course.
-
-
-
-
57
-
-
33751312152
-
-
note
-
Surface S10 was prepared from reactions of Si(1 1 1)-H surface with octadecyl propiolate at room temperature for 40 h [8].
-
-
-
-
58
-
-
33751327426
-
-
note
-
-4 mol/L was prepared and measured by GC to draw the calibration plots. A linear relationship between the GC intensity (peak integral) and the solution concentration was obtained.
-
-
-
-
59
-
-
33751309762
-
-
note
-
3) was also prepared from reaction of Si(1 1 1)-H surface with 4-trifluoromethylbenzyl propiolate [8] and subsequent reduction and GC analysis were performed. Coverage of surface S11 was estimated to be 24%, which is quite lower than that of 56% previously reported by XPS [8]. The possible loss of more volatile trifluoromethylbenzyl alcohol (b.p. 78-80 °C/4 mmHg) than 1-octadecanol (b.p. 170-171 °C/2 mmHg) during the concentration of the solution might cause the decrease of the coverage ratio. Investigation of other methods to preconcentrate other than evaporation (e.g. solid phase extraction) is required for volatile alcohols.
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61
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0034271246
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Boukherroub R., Morin S., Sharpe P., Wayner D.D.M., and Allongue P. Langmuir 16 (2000) 7429
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Sun Q.-Y., de Smet L.C.P.M., van Lagen B., Wright A., Zuilhof H., and Sudhölter E.J.R. Angew. Chem., Int. Ed. 43 (2004) 1352
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