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Volumn 127, Issue 14, 2005, Pages 5212-5223

Synthesis and reactivity of a (μ-1,1-hydroperoxo)(μ-hydroxo) dicopper(II) complex: Ligand hydroxylation by a bridging hydroperoxo ligand

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; AMINES; COPPER COMPOUNDS; HYDROGEN PEROXIDE; HYDROPHOBICITY; HYDROXYLATION; POSITIVE IONS; SYNTHESIS (CHEMICAL);

EID: 20244372403     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja047437h     Document Type: Article
Times cited : (49)

References (50)
  • 30
    • 17244377848 scopus 로고    scopus 로고
    • note
    • 2 = bis{2-[N,N-bis(2-pyridylethyl)-amino]- 1,1-dimethylethyl}disulfide); TPPA = tris[(6-phenyl-2-pyridyl)methyl]amine.
  • 34
    • 0003528602 scopus 로고
    • Molecular Structure Corporation: The Woodlands, TX
    • teXsan: Crystal Structure Analysis Package; Molecular Structure Corporation: The Woodlands, TX, 1985 and 1992.
    • (1985) teXsan: Crystal Structure Analysis Package
  • 35
    • 17244370892 scopus 로고    scopus 로고
    • note
    • Prolonged standing for an additional 4 h revealed that further exchange reaction was still going on. Simulation of the isotope pattern of the spectrum measured after 16 h revealed that ca. 50% of conversion to 2-(OD)(OOD) occurs (not shown in Figure 5).
  • 40
    • 17244379865 scopus 로고    scopus 로고
    • note
    • Such a facile reduction of 2 may be partly attributable to strong hydrogen bonding between the hydroperoxide and the imidazole nitrogen, which makes the hydroperoxide a stronger reductant. In addition, a proton released upon reduction neutralizes synchronously the bridging hydroxide, leading to the stabilization of the copper(I) complex 5.
  • 45


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.