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Volumn 39, Issue 19, 2000, Pages 4358-4369

Synthesis, structure, and H2O2-dependent catalytic functions of disulfide-bridged dicopper(I) and related thioether-copper(I) and thioether-copper(II) complexes

Author keywords

[No Author keywords available]

Indexed keywords

BIS[2 [N,N BIS(2 PYRIDYLETHYL)AMINO] 1,1 DIMETHYLETHYL]DISULFIDE; COPPER COMPLEX; DISULFIDE; N (2 METHYL 2 PHENETHYLTHIO)PROPYL N,N BIS 2 (2 PYRIDYL)ETHYLAMINE; N,N BIS [2 (2 PYRIDYL)ETHYL] 1,1 DIMETHYL 2 MERCAPTOETHYLAMINE; PEROXIDE; SULFIDE; UNCLASSIFIED DRUG;

EID: 0034683465     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic000018a     Document Type: Article
Times cited : (92)

References (91)
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    • 3 with an N4-donor ligand was also reported in ref 36a, while a reductant for the initially formed Fe(II) complex was not specified. Thus, the reduction of metal centers during the formation of a complex with donor ligands seems to have occurred, while in many cases the determination of reductants in reaction mixtures should be difficult.
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    • Extended Hückel calculations were carried out using YAeHMOP: Landrum, G., Cornell University, Ithaca, NY, 1995
    • Extended Hückel calculations were carried out using YAeHMOP: Landrum, G., Cornell University, Ithaca, NY, 1995.
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    • note
    • 2. See the Experimental Section. (c) We could not observe the band of a Cu-O stretching mode reproducibly. Such a stretching mode for a Cu-OOH species would show a weak signal as reported in ref 44d, but our low S/N ratio spectra seem to be unable to delineate weak bands.


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