cis-μ-1,2-peroxo diiron complex: Structure and reversible oxygenation

Journal of the American Chemical Society

Volumn 118, Issue 3, 1996, Pages 701-702

  Ookubo, Takaharu ^a   Sugimoto, Hideki ^a   Nagayama, Toshihiko ^a   Masuda, Hideki ^b   Sato, Takahisa ^c   Tanaka, Koji ^d   Maeda, Yonezo ^e   Okawa, Hisashi ^e   Hayashi, Yoshihito ^a   Uehara, Akira ^a   Suzuki, Masatatsu ^a  

^a KANAZAWA UNIVERSITY   (Japan)

^b NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

^c RIGAKU CORPORATION   (Japan)

^d INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^e KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000736293     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953705n     Document Type: Article

References (33)

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19. 4-tpdp = N,N,N′,N′-tetrakis{2-(6-methylpyridyl)methyl}-1,3-diaminopropan-2- olate; bimp = 2,6-bis[bis{2-(1-methylimidazolyl)methyl}aminomethyl]-4-methylphenolate: Ph-tidp = N,N,N′,N′-tetrakis{2-(1-methyl-4,5-diphenylimidazolyl)methyl}-1,3- diaminopropan-2-olate; tpdp = N,N,N′,N′-tetrakis(2-pyridylmethyl)-1,3-diaminopropan-2-olate; N-Et-HPTB = N,N,N′,N′-tetrakis{2-(1-ethylbenzimidazolyl)methyl}-1,3- diaminopropan-2-olate.
20. +.
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30. In order to confirm the peroxide oxidation state, we attempted to detect the O-O stretching mode in the resonance Raman spectrum. Attempts so far were unsuccessful.
31. Mashuta, M. S.; Webb, R. J.; McCusker, J. K.; Schmitt, E. A.; Oberhausen, K. J.; Richardson, J. F.; Buchanan, R. M.; Hendrickson, D. N. J. Am. Chem. Soc. 1992, 114, 3815-3827.
32. +. Suzuki, M., et al., unpublished result.
33. 4-tpdp and Ph-tidp complexes will be published elsewhere.