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4 catalyzed the diethylzinc addition to 1-naphthaldehyde with up to 89% ee, similar to BINOL. Chen, Y.; Yekta, S.; Martyn, L.J.P.; Zheng, J.; Yudin, A.K. Org. Lett. 2000, 2, 3433-3436.
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0034601952
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(c) Thiazolidine derivatives catalyzed the diethylzinc addition to aryl and alkyl aldehydes with 52-90% ee. Meng, Q.L.; Li, Y.L.; He, Y.; Guan, Y. Tetrahedron: Asymmetry 2000, 11, 4255-4261.
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Meng, Q.L.1
Li, Y.L.2
He, Y.3
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0034601947
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4 catalyzed the reaction of diethylzinc with aldehydes with up to 93% ee. Shen, X.Q.; Guo, H.; Ding, K.L. Tetrahedron: Asymmetry 2000, 11, 4321-4327.
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0034692859
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(e) Amino alcohols containing 2,2'-bridged binaphthyl unit showed up to 97% ee for the diethylzinc addition to aromatic aldehydes. Arroyo, N.; Haslinger, U.; Mereiter, K.; Widhalm, M. Tetrahedron: Asymmetry 2000, 11, 4207-4219.
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Widhalm, M.4
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0034715996
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(f) Cobaltocene- and ferrocene-based chiral oxazolines catalyzed the diethylzinc addition to benzaldehyde with 8-75% ee. Jones, G.; Butler, D.C.D.; Richards, C.J. Tetrahedron Lett. 2000. 41, 9351-9354.
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Jones, G.1
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(g) A ferrocenyl diselenide catalyzed the reaction of aldehydes with diethylzinc with low enantioselectivity (≤44% ee). Bolm, C.; Kesselgruber, M.; Grenz, A.; Hermanns, N.; Hildebrand, J.P. New J. Chem. 2001, 25, 13-15.
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335
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0000060085
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(h) Chiral amino acid-derived tetracoordinated zinc complexes were observed to catalyze the diethylzinc addition to aryl and alkyl aldehydes with up to 96% ee. The corresponding polystyrene-supported complex showed lower enantioselectivity (up to 79% ee). Dangel, B.D.; Polt, R. Org. Lett. 2000, 2, 3003-3006.
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(i) Amino alcohols containing various sizes of N-O heterocycles catalyzed the diethylzinc addition to benzaldehyde with up to 98% ee. Juanes, O.; Rodriguez-Ubis, J.C.; Brunet, E.; Pennemann, H.; Kossenjans, M.; Martens, J. Eur. J. Org. Chem. 1999, 12, 3323-3333.
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(j) Amino alcohols with a bispidine framework gave 52-98% ee for the diethylzinc addition to aromatic and aliphatic aldehydes. Spieler, J.; Huttenloch, O.; Waldmarm, H. Eur. J. Org. Chem. 2000, 3, 391-399.
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0343130520
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(k) 1,3-Dithian-2-yl-substituted aliphatic aldehydes reacted with diethylzinc in the presence of chiral amino alcohols with up to 70% ee. Wilken, J.; Winter, M.; Stahl, I.; Martens, J. Tetrahedron: Asymmetry 2000, 11, 1067-1071.
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4. Dreher, S.D.; Katz, T.J.; Lam, K.C.; Rheingold, A.L. J. Org. Chem. 2000, 65, 815-822.
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0034684706
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(m) Chiral hydroquinolines as ligands for the diethylzinc addition to benzaldehyde with up to 61% ee. Chelucci, G.; Craba, S.; Saba, A.; Soccolini, F.; Sotgiu, G. J. Mol. Catal. A: Chem. 2000, 164, 173-179.
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Sotgiu, G.5
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0032771218
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(n) Pyridine N-oxide-based ligands gave ≤64% ee for the reaction of diethylzinc with benzaldehyde. Derdau, V.; Laschat, S.; Hupe, E.; König, W.A.; Dix, I.; Jones, P.G. Eur. J. Inorg. Chem. 1999, 6. 1001-1007.
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0345279898
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(o) Chiral sulfinylamines catalyzed the diethylzinc addition to benzaldehyde with low enantioselectivity (≤14% ee). Chan, W.H.; Lee, A.W.M.; Lin, J. J. Chem. Research, Synop. 1999, 126-127.
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343
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0034303619
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(p) A chiral 5,5'-(3,3'-bipyridyl)dialkanediol was found to carry out an autocatalysis for the diisopropylzinc addition to the corresponding dialdehyde with up to 75% ee. Tanji, S.; Nakao, T.; Sato, I.; Soai, K. Heterocycles 2000, 53, 2183-2189.
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(q) A polyacetylene substituted with the ephedrine units was shown to catalyze the dialkylzinc addition to benzaldehyde with ≤49% ee. Yashima, E.; Maeda, Y.; Okamoto, Y. Polym. J. 1999, 31, 1033-1036.
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