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Volumn 37, Issue 21, 1998, Pages 2922-2959

Nonlinear effects in asymmetric synthesis and stereoselective reactions: Ten years of investigation

Author keywords

Asymmetric amplification; Asymmetric catalysis; Asymmetric synthesis; Autocatalysis; Chiral auxiliaries

Indexed keywords

ALDEHYDE; BORON DERIVATIVE; CARBONYL DERIVATIVE; DIMER; EPOXIDE; GLYOXYLIC ACID; LIGAND; ZINC;

EID: 0032538773     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19981116)37:21<2922::aid-anie2922>3.0.co;2-1     Document Type: Review
Times cited : (702)

References (150)
  • 2
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    • note
    • [3] proposed the use of the expression "enantiomeric" excess (ee) defined as ee(%) = R - S/R + S × 100. This definition has the advantage that ee coincides with op, even when the measurement is performed by nonpolarimetric methods. (See also ref. [4] for a discussion on that topic.)
  • 19
    • 0040413887 scopus 로고
    • b) H. Wynberg, Chimia 1976, 30, 445.
    • (1976) Chimia , vol.30 , pp. 445
    • Wynberg, H.1
  • 20
    • 85085785562 scopus 로고    scopus 로고
    • note
    • [18]
  • 29
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    • (Ed. G. R. Stephenson), Blackie Academic and Professional, New York
    • C. Bolm in Advanced Asymmetric Synthesis (Ed. G. R. Stephenson), Blackie Academic and Professional, New York, 1996, pp. 9-26.
    • (1996) Advanced Asymmetric Synthesis , pp. 9-26
    • Bolm, C.1
  • 40
    • 84920313156 scopus 로고    scopus 로고
    • For a simulation of the curve of Figure 5 under the assumption of a dimeric titanium species with four DET, see ref. [31]
    • For a simulation of the curve of Figure 5 under the assumption of a dimeric titanium species with four DET, see ref. [31].
  • 99
    • 84920313152 scopus 로고    scopus 로고
    • note
    • B] (9)
  • 107
    • 84920313151 scopus 로고    scopus 로고
    • For a recent highlight on asymmetric autocatalysis with amplification of chirality, see ref. [79a]. For a possible asymmetric autocatalytic system (liquid phase autoxidation) see ref. [79b]
    • For a recent highlight on asymmetric autocatalysis with amplification of chirality, see ref. [79a]. For a possible asymmetric autocatalytic system (liquid phase autoxidation) see ref. [79b].
  • 109
    • 0029742482 scopus 로고    scopus 로고
    • and references therein
    • Angew. Chem. Int. Ed. Engl. 1996, 35, 1657 and references therein
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 1657
  • 117
    • 84920313150 scopus 로고    scopus 로고
    • For advantages or disadvantages of the use of the enantiomeric ratio (er) in stereochemical problems or Horeau amplification, see refs.[86, 87]
    • For advantages or disadvantages of the use of the enantiomeric ratio (er) in stereochemical problems or Horeau amplification, see refs.[86, 87].
  • 125
    • 85085786970 scopus 로고    scopus 로고
    • [87]
    • [87]
  • 126
  • 127
    • 85085787971 scopus 로고    scopus 로고
    • note
    • [3] the reaction involving the formation of L. As discussed above it is possible to introduce a (+)-NLE, which makes this system useful for self-replication of chirality.
  • 129
    • 85085786160 scopus 로고    scopus 로고
    • [97]
    • [97]
  • 130
    • 84920313146 scopus 로고    scopus 로고
    • manuscript in preparation
    • C. Girard, H. B. Kagan, manuscript in preparation.
    • Girard, C.1    Kagan, H.B.2
  • 133
    • 85085786574 scopus 로고    scopus 로고
    • [102]
    • [102]
  • 146
    • 84920313144 scopus 로고    scopus 로고
    • For the advantages and disadvantages of the use of ee, ec, or er in various problems, see ref. [86]
    • For the advantages and disadvantages of the use of ee, ec, or er in various problems, see ref. [86].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.