Design of diastereomeric serf-inhibiting catalysts for control of turnover frequency and enantioselectivity [18]

Journal of the American Chemical Society

Volumn 122, Issue 13, 2000, Pages 3250-3251

  Balsells, Jaume ^a   Walsh, Patrick J ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; SULFONAMIDE;

CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; DIASTEREOISOMER; ENANTIOMER; LETTER; STEREOCHEMISTRY;

EID: 0034607311     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja993887b     Document Type: Letter

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25. Initial ee's were used due to variations in the ee's with conversion. The Δee is +1% for 2 and -12% for 3. See: Seebach, D.; Plattner, D. A.; Beck, A. K.; Wang, Y. M.; Hunziker, D.; Petter, W. Helv. Chim. Acta 1992, 75, 2171-2209. Balsells, J.; Walsh, P. J. Work in progress.