Asymmetric Addition of Dimethylzinc to Benzaldehyde Catalyzed by (2S)-3-exo-(Dimethylamino)isobornenol. A Theoretical Study on the Origin of Enantioselection

Organometallics

Volumn 18, Issue 2, 1999, Pages 128-133

  Yamakawa, Masashi ^a   Noyori, Ryoji ^b  

^a KINJO GAKUIN UNIVERSITY   (Japan)

^b NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000414234     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9807405     Document Type: Article

References (40)

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36. The calculation of the model system suggested the possibility of an additional chairlike six-membered transition state which is considerably less stable than anti- and syn-6.
37. The model 6, lacking the bornane skeleton, is strucurally more relaxed than the real system 4. The five-membered ring is skewed by rotation about the C(3)-C(4) bond, while the N(5)-C(4) and O(2)-C(3) linkages in 4 are eclipsed.
38. 9 is not appropriate for correct prediction.
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