Asymmetric synthesis of (diene)Fe(CO)3 complexes via catalytic enantioselective alkylation with dialkylzinc

Tetrahedron Letters

Volumn 37, Issue 19, 1996, Pages 3345-3346

  Takemoto, Yoshiji ^a   Baba, Yasutaka ^a   Noguchi, Izumi ^a   Iwata, Chuzo ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPLEX;

ALKYLATION; ARTICLE; COMPLEX FORMATION; DRUG SYNTHESIS; ENANTIOMER; REACTION ANALYSIS;

EID: 0029947253     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)00512-6     Document Type: Article

References (21)

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19. The ψ-exo and ψ-endo stereochemistry of 2 (polar) and 3 (less polar) were assigned by analogy to previous report: Clinton, N. A.; Lillya, C. P. J. Am. Chem. Soc. 1970, 92, 3058-3064. Their absolute configurations were assumed to be (2R,6S) and (2S,6S), respectively, from their CD spectra [2a (c 0.0247, MeOH) λ 398nm (Δε +2.38), 3a (c 0.017, MeOH) λ 398nm (Δε -2.34), 2 b (c 0.0179, MeOH) λ 396nm (Δε +1.98), 3 b (c 0.023, MeOH) λ 397nm (Δε -1.17)] according to the empirical rule: Djedaini, F.; Grée, D.; Martelli, J.; Grée, R.; Leroy, L.; Bolard, J.; Toupet, L. Tetrahedron Lett. 1989, 30, 3781-3784.
20. The ψ-exo and ψ-endo stereochemistry of 2 (polar) and 3 (less polar) were assigned by analogy to previous report: Clinton, N. A.; Lillya, C. P. J. Am. Chem. Soc. 1970, 92, 3058-3064. Their absolute configurations were assumed to be (2R,6S) and (2S,6S), respectively, from their CD spectra [2a (c 0.0247, MeOH) λ 398nm (Δε +2.38), 3a (c 0.017, MeOH) λ 398nm (Δε -2.34), 2 b (c 0.0179, MeOH) λ 396nm (Δε +1.98), 3 b (c 0.023, MeOH) λ 397nm (Δε -1.17)] according to the empirical rule: Djedaini, F.; Grée, D.; Martelli, J.; Grée, R.; Leroy, L.; Bolard, J.; Toupet, L. Tetrahedron Lett. 1989, 30, 3781-3784.
21. 3 moiety and dialkylzinc has been reported: Jones, G. B.; Heaton, S. B. Tetrahedron: Asymmetry 1993, 4, 261-272.