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Volumn 99, Issue 7, 1999, Pages 1643-1663

Interlocked Macromolecules

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EID: 0001675749     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr970081q     Document Type: Article
Times cited : (727)

References (322)
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    • The term rotaxane derives from the Latin words rota and axis meaning wheel and axle, respectively, see: Schill, G.; Zollenkopf, H. Liebigs Ann. Chem. 1969, 721, 53-74.
    • (1969) Liebigs Ann. Chem. , vol.721 , pp. 53-74
    • Schill, G.1    Zollenkopf, H.2
  • 2
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    • Academic Press: New York
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
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    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1985) Tetrahedron , vol.41 , pp. 3161-3212
    • Walba, D.M.1
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    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1987) Chem. Rev. , vol.87 , pp. 795-810
    • Dietrich-Buchecker, C.O.1    Sauvage, J.-P.2
  • 5
    • 0000958966 scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1991) Bioorg. Chem. Front. , vol.2 , pp. 195-248
    • Dietrich-Buchecker, C.O.1    Sauvage, J.-P.2
  • 6
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    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.-C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1993) Top. Curr. Chem. , vol.165 , pp. 131-162
    • Chambron, J.-C.1    Dietrich-Buchecker, C.O.2    Sauvage, J.-P.3
  • 7
    • 0002608120 scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1993) Adv. Mater. , vol.5 , pp. 11-21
    • Gibson, H.W.1    Marand, H.2
  • 8
    • 0000067181 scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1994) Prog. Polym. Sci. , vol.19 , pp. 843-945
    • Gibson, H.W.1    Bheda, M.C.2    Engen, P.T.3
  • 9
    • 0000996533 scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146-152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1994) Trends Polym. Sci. , vol.2 , pp. 146-152
    • Amabilino, D.B.1    Parsons, I.W.2    Stoddart, J.F.3
  • 10
    • 2842587248 scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1995) Chem. Rev. , vol.95 , pp. 2725-2828
    • Amabilino, D.B.1    Stoddart, J.F.2
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    • Semlyen, J. A., Ed.; Wiley: New York
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1996) Large ring Molecules , pp. 191-262
    • Gibson, H.W.1
  • 12
    • 21344464192 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1996) Collect. Czech. Chem. Commun. , vol.61 , pp. 1-43
    • Belohradsky, M.1    Raymo, F.M.2    Stoddart, J.F.3
  • 13
    • 0000954208 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1996) Trends Polym. Sci. , vol.4 , pp. 208-211
    • Raymo, F.M.1    Stoddart, J.F.2
  • 14
    • 0031484860 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527-557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1997) Collect. Czech. Chem. Commun. , vol.62 , pp. 527-557
    • Belohradsky, M.1    Raymo, F.M.2    Stoddart, J.F.3
  • 15
    • 0038475417 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1997) Angew. Chem., Int. Ed. Engl. , vol.36 , pp. 930-944
    • Jäger, R.1    Vögtle, F.2
  • 16
    • 0013322341 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1998) Curr. Opin. Solid State Mater. Sci. , vol.3 , pp. 579-584
    • Clarkson, G.J.1    Leigh, D.A.2    Smith, D.A.3
  • 17
    • 0002449198 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1999) Chem. Ind. (London) , pp. 178-183
    • Leigh, D.A.1    Murphy, A.2
  • 18
    • 0033597149 scopus 로고    scopus 로고
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265-5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • (1999) Tetrahedron , vol.55 , pp. 5265-5293
    • Breault, G.A.1    Hunter, C.A.2    Mayers, P.C.3
  • 19
    • 0003542983 scopus 로고    scopus 로고
    • VCH-Wiley: Weinheim, in press
    • For books and reviews on (poly)rotaxanes and (poly)catenanes, see: (a) Schill, G. Catenanes, Rotaxanes and Knots; Academic Press: New York, 1971. (b) Walba, D. M. Tetrahedron 1985, 41, 3161-3212. (c) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Chem. Rev. 1987, 87, 795-810. (d) Dietrich-Buchecker, C. O.; Sauvage, J.-P. Bioorg. Chem. Front. 1991, 2, 195-248. (e) Chambron, J.- C.; Dietrich-Buchecker, C. O.; Sauvage, J.-P. Top. Curr. Chem. 1993, 165, 131-162. (f) Gibson, H. W.; Marand, H. Adv. Mater. 1993, 5, 11-21. (g) Gibson, H. W.; Bheda, M. C.; Engen, P. T. Prog. Polym. Sci. 1994, 19, 843-945. (h) Amabilino, D. B.; Parsons, I. W.; Stoddart, J. F. Trends Polym. Sci. 1994, 2, 146- 152. (i) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. 1995, 95, 2725-2828. (j) Gibson, H. W. Large Ring Molecules; Semlyen, J. A., Ed.; Wiley: New York, 1996; pp 191-262. (k) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1996, 61, 1-43. (l) Raymo, F. M.; Stoddart, J. F. Trends Polym. Sci. 1996, 4, 208-211. (m) Belohradsky, M.; Raymo, F. M.; Stoddart, J. F. Collect. Czech. Chem. Commun. 1997, 62, 527- 557. (n) Jäger, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 930-944. (o) Clarkson, G. J.; Leigh, D. A.; Smith, D. A. Curr. Opin. Solid State Mater. Sci. 1998, 3, 579-584. (p) Leigh, D. A.; Murphy, A. Chem. Ind. (London) 1999, 178-183. (q) Breault, G. A.; Hunter, C. A.; Mayers, P. C. Tetrahedron 1999, 55, 5265- 5293. (r) Catenanes, Rotaxanes and Knots; Dietrich-Buckecher, C. O., Sauvage, J.-P., Eds.; VCH-Wiley: Weinheim, in press.
    • Catenanes, Rotaxanes and Knots
    • Dietrich-Buckecher, C.O.1    Sauvage, J.-P.2
  • 20
    • 37049083591 scopus 로고
    • as the noninterlocked counterparts of rotaxanes, in which one or more linear "rods" or "threads" are encircled by one or more "wheels" or "beads" to form inclusion complexes. As distinct from rotaxanes, these supramolecular complexes are free to dissociate into their separate components since they do not possess bulky stopper groups
    • Pseudorotaxanes have been defined (Ashton, P. R.; Philp, D.; Spencer, N.; Stoddart, J. F. J. Chem. Soc., Chem. Commun. 1991, 1677-1679) as the noninterlocked counterparts of rotaxanes, in which one or more linear "rods" or "threads" are encircled by one or more "wheels" or "beads" to form inclusion complexes. As distinct from rotaxanes, these supramolecular complexes are free to dissociate into their separate components since they do not possess bulky stopper groups.
    • (1991) J. Chem. Soc., Chem. Commun. , pp. 1677-1679
    • Ashton, P.R.1    Philp, D.2    Spencer, N.3    Stoddart, J.F.4
  • 24
    • 0029735643 scopus 로고    scopus 로고
    • The term pseudopolyrotaxanes was introduced by us in 1994 (see ref 2h) to describe polyrotaxanes lacking at least one if not both stoppers, i.e., pseudopolyrotaxanes are to polyrotaxanes what pseudorotaxanes are to rotaxanes (see ref 3). The use of the term was subsequently extended to embrace supramolecular arrays, reminiscent of V (Figure 5) but lacking terminal stoppers, and incorporating a polymeric-like backbone held together by a combination of covalent and noncovalent bonds, see, for example: (a) Asakawa, M.; Ashton, P. R.; Brown, G. R.; Hayes, W.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Adv. Mater. 1996, 8, 37-41. (b) Newton, S. P.; Stoddart, J. F.; Hayes, W. Supramol. Sci. 1996, 3, 221-236. (c) Asakawa, M.; Ashton, P. R.; Brown, C. L.; Fyfe, M. C. T.; Menzer, S.; Pasini, D.; Scheuer, C.; Spencer, N.; Spencer, N.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1997, 3, 1136-1150. (d) Ashton, P. R.; Fyfe, M. C. T.; Hickingbottom, S. K.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1998, 4, 577-589.
    • (1996) Adv. Mater. , vol.8 , pp. 37-41
    • Asakawa, M.1    Ashton, P.R.2    Brown, G.R.3    Hayes, W.4    Menzer, S.5    Stoddart, J.F.6    White, A.J.P.7    Williams, D.J.8
  • 25
    • 0030382165 scopus 로고    scopus 로고
    • The term pseudopolyrotaxanes was introduced by us in 1994 (see ref 2h) to describe polyrotaxanes lacking at least one if not both stoppers, i.e., pseudopolyrotaxanes are to polyrotaxanes what pseudorotaxanes are to rotaxanes (see ref 3). The use of the term was subsequently extended to embrace supramolecular arrays, reminiscent of V (Figure 5) but lacking terminal stoppers, and incorporating a polymeric-like backbone held together by a combination of covalent and noncovalent bonds, see, for example: (a) Asakawa, M.; Ashton, P. R.; Brown, G. R.; Hayes, W.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Adv. Mater. 1996, 8, 37-41. (b) Newton, S. P.; Stoddart, J. F.; Hayes, W. Supramol. Sci. 1996, 3, 221-236. (c) Asakawa, M.; Ashton, P. R.; Brown, C. L.; Fyfe, M. C. T.; Menzer, S.; Pasini, D.; Scheuer, C.; Spencer, N.; Spencer, N.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1997, 3, 1136-1150. (d) Ashton, P. R.; Fyfe, M. C. T.; Hickingbottom, S. K.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1998, 4, 577-589.
    • (1996) Supramol. Sci. , vol.3 , pp. 221-236
    • Newton, S.P.1    Stoddart, J.F.2    Hayes, W.3
  • 26
    • 0030839784 scopus 로고    scopus 로고
    • The term pseudopolyrotaxanes was introduced by us in 1994 (see ref 2h) to describe polyrotaxanes lacking at least one if not both stoppers, i.e., pseudopolyrotaxanes are to polyrotaxanes what pseudorotaxanes are to rotaxanes (see ref 3). The use of the term was subsequently extended to embrace supramolecular arrays, reminiscent of V (Figure 5) but lacking terminal stoppers, and incorporating a polymeric-like backbone held together by a combination of covalent and noncovalent bonds, see, for example: (a) Asakawa, M.; Ashton, P. R.; Brown, G. R.; Hayes, W.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Adv. Mater. 1996, 8, 37-41. (b) Newton, S. P.; Stoddart, J. F.; Hayes, W. Supramol. Sci. 1996, 3, 221-236. (c) Asakawa, M.; Ashton, P. R.; Brown, C. L.; Fyfe, M. C. T.; Menzer, S.; Pasini, D.; Scheuer, C.; Spencer, N.; Spencer, N.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1997, 3, 1136-1150. (d) Ashton, P. R.; Fyfe, M. C. T.; Hickingbottom, S. K.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1998, 4, 577-589.
    • (1997) Chem. Eur. J. , vol.3 , pp. 1136-1150
    • Asakawa, M.1    Ashton, P.R.2    Brown, C.L.3    Fyfe, M.C.T.4    Menzer, S.5    Pasini, D.6    Scheuer, C.7    Spencer, N.8    Spencer, N.9    Stoddart, J.F.10    White, A.J.P.11    Williams, D.J.12
  • 27
    • 0031859995 scopus 로고    scopus 로고
    • The term pseudopolyrotaxanes was introduced by us in 1994 (see ref 2h) to describe polyrotaxanes lacking at least one if not both stoppers, i.e., pseudopolyrotaxanes are to polyrotaxanes what pseudorotaxanes are to rotaxanes (see ref 3). The use of the term was subsequently extended to embrace supramolecular arrays, reminiscent of V (Figure 5) but lacking terminal stoppers, and incorporating a polymeric-like backbone held together by a combination of covalent and noncovalent bonds, see, for example: (a) Asakawa, M.; Ashton, P. R.; Brown, G. R.; Hayes, W.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Adv. Mater. 1996, 8, 37-41. (b) Newton, S. P.; Stoddart, J. F.; Hayes, W. Supramol. Sci. 1996, 3, 221-236. (c) Asakawa, M.; Ashton, P. R.; Brown, C. L.; Fyfe, M. C. T.; Menzer, S.; Pasini, D.; Scheuer, C.; Spencer, N.; Spencer, N.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1997, 3, 1136-1150. (d) Ashton, P. R.; Fyfe, M. C. T.; Hickingbottom, S. K.; Menzer, S.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. Chem. Eur. J. 1998, 4, 577-589.
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    • note
    • The term catenane derives from the Latin word catena meaning chain. See refs 2a and 11a.
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    • A similar procedure was employed (see ref 25a) to synthesize pseudopolyrotaxanes incorporating β-CD and poly(vinylidene chloride/allyl chloride). For the dehydrochlorination of 5, see: (a) Maciejewski, M. J. Macromol. Sci., Chem. 1979, A13, 1175-1202. (b) Maciejewski, M.; Durski, Z. J. Macromol. Sci., Chem. 1981, A16, 441-450.
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    • For preliminary reports on polyester pseudopolyrotaxanes and polyrotaxanes, see: (a) Gibson, H. W.; Engen, P. T.; Lecavalier, P. R. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1988, 29 (1), 248-249. (b) Lecavalier, P. R.; Engen, P. T.; Shen, Y. X.; Joardar, S,; Ward, T.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1989, 30 (1), 189-190. (c) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (1), 637-638. (d) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 593-594. (e) Marand, H.; Prasad, A.; Wu, C.; Bheda, M.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 639- 640. (f) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Prasad, A.; Marand, H.; Keith, D. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (1), 235-236. (g) Sze, J. Y.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (2), 331-332.
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    • For preliminary reports on polyester pseudopolyrotaxanes and polyrotaxanes, see: (a) Gibson, H. W.; Engen, P. T.; Lecavalier, P. R. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1988, 29 (1), 248-249. (b) Lecavalier, P. R.; Engen, P. T.; Shen, Y. X.; Joardar, S,; Ward, T.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1989, 30 (1), 189-190. (c) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (1), 637-638. (d) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 593-594. (e) Marand, H.; Prasad, A.; Wu, C.; Bheda, M.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 639- 640. (f) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Prasad, A.; Marand, H.; Keith, D. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (1), 235-236. (g) Sze, J. Y.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (2), 331-332.
    • (1991) Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. , vol.32 , Issue.1 , pp. 637-638
    • Gibson, H.W.1    Wu, C.2    Shen, Y.X.3    Bheda, M.4    Sze, J.5    Engen, P.T.6    Prasad, A.7    Marand, H.8    Loveday, D.9    Wilkes, G.10
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    • For preliminary reports on polyester pseudopolyrotaxanes and polyrotaxanes, see: (a) Gibson, H. W.; Engen, P. T.; Lecavalier, P. R. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1988, 29 (1), 248-249. (b) Lecavalier, P. R.; Engen, P. T.; Shen, Y. X.; Joardar, S,; Ward, T.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1989, 30 (1), 189-190. (c) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (1), 637-638. (d) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 593-594. (e) Marand, H.; Prasad, A.; Wu, C.; Bheda, M.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 639- 640. (f) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Prasad, A.; Marand, H.; Keith, D. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (1), 235-236. (g) Sze, J. Y.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (2), 331-332.
    • (1991) Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. , vol.32 , Issue.3 , pp. 593-594
    • Gibson, H.W.1    Wu, C.2    Shen, Y.X.3    Bheda, M.4    Sze, J.5    Engen, P.T.6    Prasad, A.7    Marand, H.8    Loveday, D.9    Wilkes, G.10
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    • For preliminary reports on polyester pseudopolyrotaxanes and polyrotaxanes, see: (a) Gibson, H. W.; Engen, P. T.; Lecavalier, P. R. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1988, 29 (1), 248-249. (b) Lecavalier, P. R.; Engen, P. T.; Shen, Y. X.; Joardar, S,; Ward, T.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1989, 30 (1), 189-190. (c) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (1), 637-638. (d) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 593-594. (e) Marand, H.; Prasad, A.; Wu, C.; Bheda, M.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 639-640. (f) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Prasad, A.; Marand, H.; Keith, D. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (1), 235-236. (g) Sze, J. Y.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (2), 331-332.
    • (1991) Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. , vol.32 , Issue.3 , pp. 639-640
    • Marand, H.1    Prasad, A.2    Wu, C.3    Bheda, M.4    Gibson, H.W.5
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    • For preliminary reports on polyester pseudopolyrotaxanes and polyrotaxanes, see: (a) Gibson, H. W.; Engen, P. T.; Lecavalier, P. R. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1988, 29 (1), 248-249. (b) Lecavalier, P. R.; Engen, P. T.; Shen, Y. X.; Joardar, S,; Ward, T.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1989, 30 (1), 189-190. (c) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (1), 637-638. (d) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 593-594. (e) Marand, H.; Prasad, A.; Wu, C.; Bheda, M.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 639- 640. (f) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Prasad, A.; Marand, H.; Keith, D. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (1), 235-236. (g) Sze, J. Y.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (2), 331-332.
    • (1992) Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. , vol.33 , Issue.1 , pp. 235-236
    • Gibson, H.W.1    Wu, C.2    Shen, Y.X.3    Bheda, M.4    Prasad, A.5    Marand, H.6    Keith, D.7
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    • For preliminary reports on polyester pseudopolyrotaxanes and polyrotaxanes, see: (a) Gibson, H. W.; Engen, P. T.; Lecavalier, P. R. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1988, 29 (1), 248-249. (b) Lecavalier, P. R.; Engen, P. T.; Shen, Y. X.; Joardar, S,; Ward, T.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1989, 30 (1), 189-190. (c) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (1), 637-638. (d) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Sze, J.; Engen, P. T.; Prasad, A.; Marand, H.; Loveday, D.; Wilkes, G. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 593-594. (e) Marand, H.; Prasad, A.; Wu, C.; Bheda, M.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1991, 32 (3), 639- 640. (f) Gibson, H. W.; Wu, C.; Shen, Y. X.; Bheda, M.; Prasad, A.; Marand, H.; Keith, D. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (1), 235-236. (g) Sze, J. Y.; Gibson, H. W. Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. 1992, 33 (2), 331-332.
    • (1992) Am. Chem. Soc., Div. Polym. Chem., Polym. Prepr. , vol.33 , Issue.2 , pp. 331-332
    • Sze, J.Y.1    Gibson, H.W.2
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    • A similar design logic was employed to synthesize polyrotaxanes incorporating 30-crown-10 and dibenzo-24-crown-8 or bis-paraphenylene-34-crown-10 around the same acyclic component. Gong, C.; Gibson, H. W. Macromolecules 1997, 30, 8524-8525.
    • (1997) Macromolecules , vol.30 , pp. 8524-8525
    • Gong, C.1    Gibson, H.W.2
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    • Pseudopolyrotaxane 69 was also prepared by threading 42-crown-14 onto a preformed polyurethane. Gong, C.; Ji, Q.; Subramaniam, C.; Gibson, H. W. Macromolecules 1998, 31, 1814-1818.
    • (1998) Macromolecules , vol.31 , pp. 1814-1818
    • Gong, C.1    Ji, Q.2    Subramaniam, C.3    Gibson, H.W.4
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    • A combination of [C-H⋯O] hydrogen bonds and [π⋯π] stacking interactions was also exploited to prepare pseudopolyrotaxanes incorporating π-electron-rich macrocycles encircling π-electron-deficient units located along a polyurethane backbone. Loveday, D.; Wilkes, G. L.; Bheda, M. C.; Shen, Y. X.; Gibson, H. W. J. Macromol. Sci., Pure Appl. Chem. 1996, A32, 1-27.
    • (1996) J. Macromol. Sci., Pure Appl. Chem. , vol.A32 , pp. 1-27
    • Loveday, D.1    Wilkes, G.L.2    Bheda, M.C.3    Shen, Y.X.4    Gibson, H.W.5
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    • The term semirotaxane indicates (see ref 64) a pseudorotaxane composed of a macrocycle encircling an acyclic component stoppered at only one of its two ends
    • The term semirotaxane indicates (see ref 64) a pseudorotaxane composed of a macrocycle encircling an acyclic component stoppered at only one of its two ends.
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