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Volumn 37, Issue 9, 1998, Pages 1294-1297

Supramolecular daisy chains

Author keywords

Crown compounds; Host guest chemistry; Noncovalent interactions; Self assembly; Supramolecular chemistry

Indexed keywords


EID: 0032543069     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980518)37:9<1294::AID-ANIE1294>3.0.CO;2-F     Document Type: Article
Times cited : (200)

References (41)
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    • note
    • The term "daisy chain" is defined in Webster's Third New International Dictionary (Ed.: P. Babcock-Gove), Merrian-Webster, Springfield MA, 1993, as "a string of daisies with stems linked to form a chain, ... such a chain carried by chosen students at a class day or other celebration in some women's colleges." A daisy chain may be acyclic [a] - that is, linear, as shown in Figure 1 - or it may have its ends linked together to afford a cyclic [c] assembly; thus, a [c]daisy chain resembles a necklace. In the molecular world, an [a]daisy chain has a free pair of potentially matching recognition sites, whereas a [c]daisy chain experiences maximal occupancy of its recognition sites (see ref. [4], pp. 182-183), following the closure of an [a]daisy chain using its last pair of complementary recognition sites located at the termini of the growing chain.
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    • The spectrum was obtained with a VG Zabspec mass spectrometer (positive-ton mode at a scan speed of 10 s per decade) equipped with a cesium ion source and utilizing a m-nitrobenzyl alcohol matrix.
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    • +.
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    • note
    • 2 = 0.222. Computations were carried out with the SHELXTL 5.03 package. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100961. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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    • note
    • 2-symmetric supramolecular stereoisomers.
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    • S. J. Cantrill, MPhil Thesis, University of Birmingham (UK), 1997
    • S. J. Cantrill, MPhil Thesis, University of Birmingham (UK), 1997.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.