Importance of Inherent Substrate Reactivity in Enzyme-Promoted Carbocation Cyclization/Rearrangements

Angewandte Chemie - International Edition

Volumn 56, Issue 34, 2017, Pages 10040-10045

  Tantillo, Dean J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

carbocations; enzymes; inherent reactivity; intrinsic reactivity; terpenes

Indexed keywords

TERPENES;

CARBOCATIONS; EXPERIMENTAL TEST; GAS-PHASE REACTIVITY; INTRINSIC REACTIVITY; SUBSTRATE REACTIVITIES; SYNTHASE ENZYMES;

ENZYMES;

CATION; ISOTOPE; TERPENE; TERPENE SYNTHASE; TRANSFERASE;

CHEMICAL MODEL; CYCLIZATION; ENZYME SPECIFICITY; METABOLISM;

ALKYL AND ARYL TRANSFERASES; CATIONS; CYCLIZATION; ISOTOPES; MODELS, CHEMICAL; SUBSTRATE SPECIFICITY; TERPENES;

EID: 85026913105     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201702363     Document Type: Review

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