Challenges posed to bornyl diphosphate synthase: Diverging reaction mechanisms in monoterpenes

Journal of the American Chemical Society

Volumn 132, Issue 18, 2010, Pages 6349-6360

  Weitman, Michal ^a   Major, Dan Thomas ^a  

^a BAR ILAN UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

AB INITIO; BIFURCATION POINTS; CARBOCATIONS; CATION INTERMEDIATES; COMPLEX POTENTIALS; CYCLIC PRODUCTS; DENSITY FUNCTIONAL THEORY METHODS; DIPHOSPHATES; ENERGY SURFACE; ENZYMATIC CONTROL; GAS-PHASE REACTIONS; GASPHASE; MOLECULAR DYNAMICS SIMULATIONS; MONOTERPENES; MULTIPLE PRODUCTS; QUANTUM MECHANICS; REACTION MECHANISM; SYNTHASE REACTIONS; SYNTHASES; TERPENOIDS; TRANSIENT SPECIES;

DENSITY FUNCTIONAL THEORY; DYNAMICS; MOLECULAR DYNAMICS; PHASE INTERFACES; POSITIVE IONS; POTENTIAL ENERGY; QUANTUM CHEMISTRY; QUANTUM THEORY; REACTION INTERMEDIATES; SYNTHESIS (CHEMICAL);

REACTION KINETICS;

BORNYL DIPHOSPHATE SYNTHASE; CATION; DIMETHYLALLYLTRANSFERASE; SYNTHETASE; TERPENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; ENZYME SUBSTRATE COMPLEX; MOLECULAR DYNAMICS; MOLECULAR MECHANICS; MOLECULAR MODEL; PHASE TRANSITION; QUANTUM MECHANICS; SYNTHESIS;

ALKYL AND ARYL TRANSFERASES; GASES; MOLECULAR CONFORMATION; MOLECULAR DYNAMICS SIMULATION; MONOTERPENES; QUANTUM THEORY; SALVIA OFFICINALIS; THERMODYNAMICS;

EID: 77952083065     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910134x     Document Type: Article

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