Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

Journal of the American Chemical Society

Volumn 138, Issue 16, 2016, Pages 5234-5237

  Liu, Wen Bo ^a   Okamoto, Noriko ^a   Alexy, Eric J ^a   Hong, Allen Y ^a   Tran, Kristy ^a   Stoltz, Brian M ^a  

^a California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; ENANTIOSELECTIVITY;

ASYMMETRIC ALLYLIC ALKYLATIONS; COPE REARRANGEMENT; ENANTIOSELECTIVE; ENOLATES; KETO ESTER; MALONATES;

ALKYLATION;

1,5 DIENE DERIVATIVE; ALPHA,BETA UNSATURATED MALONATE; ESTER; IRIDIUM; KETOESTER DERIVATIVE; LIGAND; MALONIC ACID DERIVATIVE; PHOSPHORAMIDOUS ACID; TOLUENE; UNCLASSIFIED DRUG; ALLYL COMPOUND;

ALKYLATION; ARTICLE; CATALYSIS; CHIRALITY; COPE REARRANGEMENT; GAMMA ALKYLATION; ONE POT SYNTHESIS; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

ALKYLATION; ALLYL COMPOUNDS; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; ESTERS; IRIDIUM; MAGNETIC RESONANCE SPECTROSCOPY; MALONATES; STEREOISOMERISM;

EID: 84966440471     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.6b02153     Document Type: Article

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