Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis

Journal of the American Chemical Society

Volumn 135, Issue 29, 2013, Pages 10626-10629

  Liu, Wen Bo ^a   Reeves, Corey M ^a   Virgil, Scott C ^a   Stoltz, Brian M ^a  

^a California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC ALKYLATION; ASYMMETRIC ALLYLIC ALKYLATIONS; CATALYTIC REACTIONS; ENANTIOSELECTIVE; QUATERNARY CENTERS; QUATERNARY STEREOCENTERS; REACTION PARTNERS; STEREOCHEMICAL CONTROL;

ALLYLATION; CARBON; IRIDIUM;

CATALYSIS;

2 (TRIMETHYLSILYL)ETHYL BETA KETOESTER; BETA OXOCARBOXYLIC ACID ESTER; CARBON; ESTER DERIVATIVE; IRIDIUM; OXAZOLINE DERIVATIVE; PALLADIUM; PHOSPHINOOXAZOLINE; PHOSPHORAMIDOUS ACID; UNCLASSIFIED DRUG;

ALKYLATION; ALLYLATION; ARTICLE; CATALYSIS; CHIRALITY; CRYSTAL STRUCTURE; DECARBOXYLATION; DIASTEREOISOMER; ENANTIOSELECTIVITY; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SUBSTITUTION REACTION;

ALKYLATION; ALLYL COMPOUNDS; CARBON; CATALYSIS; IRIDIUM; PALLADIUM; STEREOISOMERISM;

EID: 84880784188     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4052075     Document Type: Article

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