Mechanism of the Iron(II)-Catalyzed Hydrosilylation of Ketones: Activation of Iron Carboxylate Precatalysts and Reaction Pathways of the Active Catalyst

Journal of the American Chemical Society

Volumn 138, Issue 14, 2016, Pages 4972-4983

  Bleith, Tim ^a   Gade, Lutz H ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CARBOXYLATION; CATALYSIS; CATALYSTS; CHELATION; CHEMICAL ACTIVATION; COORDINATION REACTIONS; HYDROSILYLATION; IRON; KETONES; REACTION INTERMEDIATES; TEMPERATURE DISTRIBUTION;

ACTIVATION PARAMETER; CARBOXYLATE LIGANDS; CATALYTIC HYDROSILYLATION; KINETIC ISOTOPE EFFECTS; LINEAR RELATIONSHIPS; MECHANISTIC STUDIES; RATE DETERMINING STEP; TEMPERATURE DEPENDENCE;

IRON COMPOUNDS;

CARBOXYLIC ACID; HYDROGEN; IRON DERIVATIVE; ISOTOPE; KETONE DERIVATIVE; SILANE;

ANALYSIS; ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION KINETICS; DENSITY FUNCTIONAL THEORY; ENANTIOMERIC RATIO; ENANTIOSELECTIVITY; HAMMETT ANALYSIS; HYDROSILYLATION; KINETICS; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 84964720745     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.6b02173     Document Type: Article

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