The mechanism of efficient asymmetric transfer hydrogenation of acetophenone using an iron(II) complex containing an (S, S)-Ph 2PCH 2CH=NCHPhCHPhN=CHCH 2PPh 2 ligand: Partial ligand reduction is the key

Journal of the American Chemical Society

Volumn 134, Issue 29, 2012, Pages 12266-12280

  Mikhailine, Alexandre A ^a   Maishan, Mazharul I ^a   Lough, Alan J ^a   Morris, Robert H ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACETOPHENONES; ACTIVATION STEPS; ACTIVE SYSTEMS; ASYMMETRIC TRANSFER HYDROGENATION; CATALYST ACTIVATION; CATALYTIC CYCLES; CATALYTIC PRODUCTION; HIGH RESOLUTION MASS SPECTROMETRY; INDUCTION PERIODS; INITIAL CONCENTRATION; IRON COMPLEX; ISO-PROPANOLS; ISO-PROPOXIDE; KINETIC MODELS; KINETIC STUDY; MULTINUCLEAR NMR; PRECATALYSTS; RAPID REACTIONS; REACTION PROFILE; SINGLE CRYSTAL X-RAY DIFFRACTION; THERMODYNAMIC PARAMETER;

ACETONE; CATALYSTS; ETHERS; HYDROGENATION; IRON COMPOUNDS; KINETIC THEORY; MASS SPECTROMETRY; RATE CONSTANTS; X RAY DIFFRACTION;

LIGANDS;

1 PHENYLETHANOL; 2 PROPANOL; ACETONE; ACETOPHENONE; FERROUS ION;

ARTICLE; ASYMMETRIC TRANSFER HYDROGENATION; CATALYST; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CONCENTRATION (PARAMETERS); HYDROGENATION; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REDUCTION; SIMULATION; THERMODYNAMICS; X RAY DIFFRACTION;

EID: 84864245150     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja304814s     Document Type: Article

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