Generating Active L-Pd(0) via Neutral or Cationic π-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines: Synthetic, Mechanistic, and Structure-Activity Studies in Challenging Cross-Coupling Reactions

Journal of Organic Chemistry

Volumn 80, Issue 13, 2015, Pages 6794-6813

  Deangelis, A J ^a   Gildner, Peter G ^a   Chow, Ruishan ^a   Colacot, Thomas J ^a  

^a Johnson Matthey Catalysis and Chiral Technologies   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CHEMICAL ACTIVATION; CHEMICAL REACTIONS; LIGANDS; SCAFFOLDS; SINGLE CRYSTALS;

ALLYLPALLADIUM COMPLEXES; CATALYST LOADINGS; COUPLING REACTION; CROSS COUPLING REACTIONS; KINETIC STUDY; ORGANIC SYNTHESIS; SHORT REACTION TIME; STRUCTURE ACTIVITY STUDY;

PALLADIUM COMPOUNDS;

ALLYL COMPOUND; BIARYL DERIVATIVE; BIPYRAZOLYLPHOSPHINE DERIVATIVE; LIGAND; PALLADIUM COMPLEX; PHOSPHINE DERIVATIVE; PI ALLYLPALLADIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CONTROLLED STUDY; CROSS COUPLING REACTION; CRYSTAL STRUCTURE; DIMERIZATION; KINETIC PARAMETERS; REACTION TIME; STRUCTURE ACTIVITY RELATION; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 84941063036     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/acs.joc.5b01005     Document Type: Article

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