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Volumn 20, Issue 10, 2001, Pages 1992-1999

A dinuclear palladium(I) ethynyl complex: Synthesis, structure, and dynamics

Author keywords

[No Author keywords available]

Indexed keywords

DINUCLEAR PALLADIUM ETHYNYL COMPLEX; HEPTADIENE; MONONUCLEAR PALLADIUM ACETYLIDE;

EID: 0035858958     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000765f     Document Type: Article
Times cited : (48)

References (62)
  • 4
    • 0011392009 scopus 로고
    • Diplomarbeit, Universität Düsseldorf, 1990; Dissertation, Universität Düsseldorf
    • Krause, J. Diplomarbeit, Universität Düsseldorf, 1990; Dissertation, Universität Düsseldorf, 1993.
    • (1993)
    • Krause, J.1
  • 14
    • 0011483947 scopus 로고
    • Dissertation, Universität Bochum
    • Schick, K.-P. Dissertation, Universität Bochum, 1982.
    • (1982)
    • Schick, K.-P.1
  • 15
    • 0011435018 scopus 로고
    • Dissertation, Universität Bochum
    • (c) Schenker, G. Dissertation, Universität Bochum, 1984.
    • (1984)
    • Schenker, G.1
  • 18
    • 0011491342 scopus 로고    scopus 로고
    • note
    • I bond and trans to one another.
  • 19
    • 0011440177 scopus 로고    scopus 로고
    • note
    • 2 is not accessible by this route.
  • 24
    • 0011393032 scopus 로고    scopus 로고
    • note
    • 0] unit, thereby avoiding the partial thermolysis (20 °C) of 1.
  • 26
    • 0011392126 scopus 로고    scopus 로고
    • Unpublished results
    • Pörschke, K.-R.; et al. Unpublished results.
    • Pörschke, K.-R.1
  • 29
    • 0011436464 scopus 로고    scopus 로고
    • note
    • 2)Li(C≡CH), which is about 90-95% pure. We realize that there is a dearth of well-defined transfer reagents for the C≡CH anion. (b) Complex 5b does not react with ethyne at ambient temperature to give 5a and methane.
  • 35
    • 0011483745 scopus 로고    scopus 로고
    • note
    • I centers by donation of (at least) four electrons.
  • 38
    • 0000711315 scopus 로고
    • Palladium-carbon π-bonded complexes
    • Pergamon: Oxford, U.K.
    • Davies, J. A. Palladium-Carbon π-Bonded Complexes. In Comprehensive Organometallic Chemistry II; Pergamon: Oxford, U.K., 1995; Vol. 9, p 325.
    • (1995) Comprehensive Organometallic Chemistry II , vol.9 , pp. 325
    • Davies, J.A.1
  • 42
    • 0011483746 scopus 로고    scopus 로고
    • note
    • 2 at 27 °C the signals of the terminal allyl C atoms (C1 and C3) are broadened, indicating the occurrence of an additional dynamic process in this solvent.
  • 43
    • 0011446695 scopus 로고
    • note
    • 3P)Pd(allyl)(acetate) complexes appear to exhibit the same dynamic behavior as 4a and it is accepted that trifluormethane-sulfonate acts purely as a monodentate ligand, there is no need to postulate that acetate functions as a bidentate ligand. (a) Van Leeuwen, V. N. M.; Praat, A. P. J. Organomet. Chem. 1970, 21, 501.
    • (1970) J. Organomet. Chem. , vol.21 , pp. 501
    • Van Leeuwen, V.N.M.1    Praat, A.P.2
  • 44
    • 0011484711 scopus 로고    scopus 로고
    • note
    • 3, but addition of LiCl and pyridine enhanced the exchange.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.