Mechanistic insights into the pd-catalyzed intermolecular asymmetric allylic dearomatization of multisubstituted pyrroles: Understanding the remarkable regio- and enantioselectivity

Journal of the American Chemical Society

Volumn 136, Issue 46, 2014, Pages 16251-16259

  Zheng, Chao ^a   Zhuo, Chun Xiang ^a   You, Shu Li ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; DENSITY FUNCTIONAL THEORY; LIGANDS; NUCLEOPHILES; POTASSIUM COMPOUNDS; STEREOCHEMISTRY; SUBSTITUTION REACTIONS;

CHIRAL LIGAND; DEAROMATIZATION; DENSITY FUNCTIONAL THEORY STUDIES; PYRROLE RING; STERIC INTERACTIONS;

ENANTIOSELECTIVITY;

LIGAND; NUCLEOPHILE; PALLADIUM; PYRROLE; PYRROLE DERIVATIVE;

AROMATIZATION; ARTICLE; CALCULATION; CATALYSIS; CHEMICAL REACTION; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; NUCLEOPHILICITY; SUBSTITUTION REACTION;

EID: 84912533610     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5080135     Document Type: Article

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