Enantioselective formation of cyano-bearing all-carbon quaternary stereocenters: Desymmetrization by copper-catalyzed N-arylation

Angewandte Chemie - International Edition

Volumn 53, Issue 36, 2014, Pages 9555-9559

  Zhou, Fengtao ^a,d   Cheng, Gui Juan ^b   Yang, Wenqiang ^a   Long, Yan ^c   Zhang, Shasha ^a   Wu, Yun Dong ^b   Zhang, Xinhao ^b   Cai, Qian ^a  

^a GUANGZHOU INSTITUTES OF BIOMEDICINE AND HEALTH   (China)

^b PEKING UNIVERSITY   (China)

^c HUNAN NORMAL UNIVERSITY   (China)

^d CHUBU UNIVERSITY   (Japan)

Author keywords

asymmetric catalysis; chirality; copper; heterocycles; synthetic methods

Indexed keywords

AROMATIC COMPOUNDS; BIOCHEMISTRY; CARBON; CATALYSIS; CHIRALITY; COPPER;

ASYMMETRIC CATALYSIS; ENANTIOSELECTIVE CONSTRUCTION; ENANTIOSELECTIVE FORMATION; HETEROCYCLES; HIGH ENANTIOSELECTIVITY; QUATERNARY STEREOCENTERS; SYNTHETIC METHODS; TETRAHYDROQUINOLINES;

ENANTIOSELECTIVITY;

BENZAZEPINE DERIVATIVE; COPPER; ISOQUINOLINE DERIVATIVE; LIGAND;

CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; STEREOISOMERISM; SYNTHESIS;

BENZAZEPINES; CATALYSIS; COPPER; ISOQUINOLINES; LIGANDS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; STEREOISOMERISM;

EID: 84906946709     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201405575     Document Type: Article

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