Construction of an all-carbon quaternary stereocenter by the peptide-catalyzed asymmetric michael addition of nitromethane to β-disubstituted α,β-unsaturated aldehydes

Angewandte Chemie - International Edition

Volumn 51, Issue 51, 2012, Pages 12786-12789

  Akagawa, Kengo ^a   Kudo, Kazuaki ^a  

^a INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

Author keywords

amino acids; asymmetric synthesis; heterogeneous catalysis; Michael addition; peptides

Indexed keywords

AQUEOUS MEDIA; ASYMMETRIC SYNTHESIS; HIGH ENANTIOSELECTIVITY; LOW MOLECULAR WEIGHT; MICHAEL ADDITIONS; NITROMETHANE; QUATERNARY STEREOCENTERS; UNSATURATED ALDEHYDES;

ADDITION REACTIONS; ALDEHYDES; AMINO ACIDS; CATALYSIS; CATALYSTS; ENANTIOSELECTIVITY; ORGANIC COMPOUNDS; UNSATURATED POLYMERS;

PEPTIDES;

ALDEHYDE; AMINO ACID; CARBON; DRUG DERIVATIVE; METHANE; NITROALKANE; NITROMETHANE; PEPTIDE;

ARTICLE; CATALYSIS; CHEMISTRY; STEREOISOMERISM;

ALDEHYDES; AMINO ACIDS; CARBON; CATALYSIS; METHANE; NITROPARAFFINS; PEPTIDES; STEREOISOMERISM;

EID: 84871025337     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201206916     Document Type: Article

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