Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex

Journal of the American Chemical Society

Volumn 136, Issue 28, 2014, Pages 9925-9937

  Lee, Jung Yoon ^a   Peterson, Ryan L ^a   Ohkubo, Kei ^b   Garcia Bosch, Isaac ^a   Himes, Richard A ^a   Woertink, Julia ^c   Moore, Cathy D ^a   Solomon, Edward I ^c   Fukuzumi, Shunichi ^b   Karlin, Kenneth D ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

^b OSAKA UNIVERSITY   (Japan)

^c STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICAL REACTIONS; HYDROGEN; ISOTOPES; OXYGENATION; PHENOLS; RATE CONSTANTS; REACTION KINETICS;

DEUTERIUM KINETIC ISOTOPE EFFECT; HYDROGEN ATOM ABSTRACTION; HYDROGEN ATOM TRANSFERS (HAT); POSITIVE CORRELATIONS; SECOND-ORDER RATE CONSTANTS; SUBSTITUTED PHENOL; TRANSFER OF CHARGES; TWO-ELECTRON OXIDATION;

COPPER COMPOUNDS;

COPPER COMPLEX; CUPRIC ION; CUPROUS ION; DEUTERIUM; HYDROGEN; OXYGEN 18; PHENOL DERIVATIVE; COPPER; OXYGEN; SUPEROXIDE;

ARTICLE; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; HYDROLYSIS; KINETICS; OXIDATION; OXYGENATION; PROTON TRANSPORT; RADICAL REACTION; SYNTHESIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; OXIDATION REDUCTION REACTION;

COPPER; DEUTERIUM; HYDROGEN; KINETICS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; OXYGEN RADIOISOTOPES; PHENOLS; SUPEROXIDES;

EID: 84904420273     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja503105b     Document Type: Article

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