Crystallographic characterization of a synthetic 1:1 end-on copper dioxygen adduct complex

Angewandte Chemie - International Edition

Volumn 45, Issue 23, 2006, Pages 3867-3869

  Würtele, Christian ^a   Gaoutchenova, Ekaterina ^b   Harms, Klaus ^b   Holthausen, Max C ^c   Sundermeyer, Jörg ^b   Schindler, Siegfried ^a  

^a JUSTUS LIEBIG UNIVERSITY   (Germany)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

^c GOETHE UNIVERSITY   (Germany)

Author keywords

Bioinorganic chemistry; Copper; Crystal structure; Dioxygen ligands; Tripodal ligands

Indexed keywords

COMPLEXATION; COPPER; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ENZYME KINETICS; INORGANIC COMPOUNDS; MATHEMATICAL MODELS;

BIOINORGANIC CHEMISTRY; DIOXYGEN LIGANDS; TRIPODAL LIGANDS;

COPPER COMPOUNDS;

COPPER; OXYGEN;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CRYSTALLOGRAPHY;

COPPER; CRYSTALLOGRAPHY; MOLECULAR STRUCTURE; OXYGEN;

EID: 33746217434     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600351     Document Type: Article

References (25)

1. L. Q. Hatcher, K. D. Karlin, J. Biol. Inorg. Chem. 2004, 9, 669.
2. E. A. Lewis, W. B. Tolman, Chem. Rev. 2004, 104, 1047.
3. L. M. Mirica, X. Ottenwaelder, T. D. P. Stack, Chem. Rev. 2004, 104, 1013.
4. S. Schindler, Eur. J. Inorg. Chem. 2000, 2311.
5. S. V. Kryatov, E. Rybak-Akimova, S. Schindler, Chem. Rev. 2005, 105, 2175.
6. L. J. Que, W. B. Tolman, Angew. Chem. 2002, 114, 1160;
7. Angew. Chem. Int. Ed. 2002, 41, 1114.
8. E. I. Solomon, P. Chen, M. Metz, S.-K. Lee, A. E. Palmer, Angew. Chem. 2001, 113, 4702;
9. Angew. Chem. Int. Ed. 2001, 40, 4570.
10. K. Fujisawa, M. Tanaka, Y. Moro-oka, N. Kitajima, J. Am. Chem. Soc. 1994, 116, 12 079.
11. D. J. E. Spencer, N. W. Aboelella, A. M. Reynolds, P. L. Holland, W. B. Tolman, J. Am. Chem. Soc. 2002, 124, 2108.
12. P. Chen, D. E. Root, C. Campochiaro, K. Fujisawa, E. I. Solomon, J. Am. Chem. Soc. 2003, 125, 466.
13. N. W. Aboelella, S. V. Kryatov, B. F. Gherman, W. W. Brennessel, V. G. Young, Jr., R. Sarangi, E. V. Rybak-Akimova, K. O. Hodgson, B. Hedman, E. I. Solomon, C. J. Cramer, W. B. Tolman, J. Am. Chem. Soc. 2004, 126, 16 896.
14. A. M. Reynolds, B. F. Gherman, C. J. Cramer, W. B. Tolman, Inorg. Chem. 2005, 44, 6989.
15. S. T. Prigge, B. A. Eipper, R. E. Mains, L. M. Amzel, Science 2004, 304, 864.
16. M. Weitzer, M. Schatz, F. Hampel, F. W. Heinemann, S. Schindler, J. Chem. Soc. Dalton Trans. 2002, 5, 686.
17. M. Weitzer, S. Schindler, G. Brehm, S. Schneider, E. Hörmann, S. Jung, S. Kaderli, A. D. Zuberbühler, Inorg. Chem. 2003, 42, 1800.
18. C. X. Zhang, S. Kaderli, M. Costas, E.-I. Kim, Y.-M. Neuhold, K. D. Karlin, A. D. Zuberbühler, Inorg. Chem. 2003, 42, 1807.
19. +) value more than six orders of magnitude higher than that of the most basic tertiary amines. Typically they are used as ligands for protons ("proton sponges"); see: V. Raab, J. Kipke, R. M. Gschwind, J. Sundermeyer, Chem. Eur. J. 2002, 8, 1682.
20. V. Raab, J. Kipke, O. Burghaus, J. Sundermeyer, Inorg. Chem. 2001, 40, 6964.
21. M. Schatz, V. Raab, S. P. Foxon, G. Brehm, S. Schneider, M. Reiher, M. C. Holthausen, J. Sundermeyer, S. Schindler, Angew. Chem. 2004, 116, 4460;
22. Angew. Chem. Int. Ed. 2004, 43, 4360.
23. B. A. Jazdzeweski, A. M. Reynolds, P. L. Holland, V. G. Young, Jr., S. Kaderli, A. D. Zuberbühler, W. B. Tolman, J. Biol. Inorg. Chem. 2003, 8, 381.
24. K. Komiyama, H. Furutachi, S. Nagatomo, A. Hashimoto, H. Hayashi, S. Fujinami, M. Suzuki, T. Kitagawa, Bull. Chem. Soc. Jpn. 2004, 77, 59.
25. [19] we erroneously reported an angle α(Cu-O-O) of 132.2° in Figure 3 - the correct value, however, is α(Cu-O-O) = 121.4°. 3869-3874