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D value has yet to be clarified.
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O values were determined as the reversible oxidation potentials by the CV and SHACV.
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89
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3 with DMA.
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note
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2.
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100
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0041371664
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note
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The addition interaction of a substrate to a 1:1 CT complex in nonpolar solvents may enhance the CT interaction as reported in ref 37.
-
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-
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101
-
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0041872412
-
-
note
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The larger g value of cumylperoxyl radical than the free spin value (2.0023) is ascribed to the spin-orbit coupling interaction on oxygen atom, which has a large spin-orbit coupling constant. The charge-transfer interaction of cumylperoxyl radical with electron donors results in a decrease in the spin density on oxygen, which causes the decrease in the g value (S8).
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102
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For the CT complex formation of cumylperoxyl radical with pyridine, see: Fukuzumi, S.; Ono, Y. Bull. Chem. Soc. Jpn. 1977, 50, 2063.
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