Rhodium(I)-catalyzed cyclization of allenynes with a carbonyl group through unusual insertion of a C=O bond into a rhodacycle intermediate

Angewandte Chemie - International Edition

Volumn 53, Issue 4, 2014, Pages 1135-1139

  Oonishi, Yoshihiro ^a   Yokoe, Takayuki ^a   Hosotani, Akihito ^a   Sato, Yoshihiro ^a,b  

^a HOKKAIDO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

alkynes; allenes; carbonyl compounds; cycloadditions; rhodium

Indexed keywords

ALKYNES; ALLENES; CYCLOADDITIONS; HYDRIDE ELIMINATION; REDUCTIVE ELIMINATION; SEVEN-MEMBERED RINGS; TRANSITION STATE; TRICYCLIC PRODUCTS;

CARBONYL COMPOUNDS; CATALYSIS; HYDRIDES; HYDROCARBONS; MUSCULOSKELETAL SYSTEM; REACTION INTERMEDIATES; RHODIUM;

CYCLIZATION;

8 OXABICYCLO(3.2.1)OCTANE; 8-OXABICYCLO(3.2.1)OCTANE; ALKYNE; CARBONYL DERIVATIVE; FUSED HETEROCYCLIC RINGS; ORGANOMETALLIC COMPOUND; RHODIUM;

ALLENES; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; CYCLOADDITIONS; SYNTHESIS;

ALKYNES; ALLENES; CARBONYL COMPOUNDS; CYCLOADDITIONS; RHODIUM;

ALKYNES; BICYCLO COMPOUNDS, HETEROCYCLIC; CATALYSIS; CYCLIZATION; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RHODIUM;

EID: 84893230673     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201308824     Document Type: Article

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