Rh(I)-catalyzed ring-closing reaction of allenynes: Selective construction of cycloheptene, bicyclo[5.3.0]decadienone, and bicyclo[5.2.0]nonene frameworks

Tetrahedron Letters

Volumn 45, Issue 21, 2004, Pages 4117-4121

  Mukai, Chisato ^a   Inagaki, Fuyuhiko ^a   Yoshida, Tatsunori ^a   Kitagaki, Shinji ^a  

^a KANAZAWA UNIVERSITY   (Japan)

Author keywords

Allenyne; Bicyclo 5.2.0 nonane; Bicyclo 5.3.0 decane; Cycloisomerization; Electrocyclic reaction; Pauson Khand reaction

Indexed keywords

ALLENE DERIVATIVE; CYCLOHEPTENE; RHENIUM;

ARTICLE; CATALYSIS; PAUSON KHAND REACTION; REACTION ANALYSIS; RING CLOSING METATHESIS; SUBSTITUTION REACTION;

EID: 2342636512     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.03.160     Document Type: Article

References (34)

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32. 2 for 9 h provided 6e in 60% yield, along with recovered 5e (11%), whereas only 42% yield of 6e and 10% of the recovered 5e were obtained in the absence of Rh(I) catalyst for 9 h
33. Refluxing 3f in xylene resulted in decomposition
34. Allenyne having TMS group at the alkyne terminus afforded the corresponding bicyclo[5.2.0]nonene derivative in 34% yield