Interception of a rautenstrauch intermediate by alkynes for [5+2] cycloaddition: Rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9- diynes to bicyclo[5.3.0]decatrienes

Angewandte Chemie - International Edition

Volumn 50, Issue 35, 2011, Pages 8153-8156

  Shu, Xing Zhong ^a   Huang, Suyu ^a   Shu, Dongxu ^b   Guzei, Ilia A ^b   Tang, Weiping ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF WISCONSIN   (United States)

Author keywords

alkenynes; cycloaddition; cycloisomerization; polycycles; rhodium

Indexed keywords

1 ,5-CYCLOOCTADIENE; ALKENYNES; BICYCLIC COMPOUNDS; CYCLOHEPTATRIENES; CYCLOISOMERIZATIONS; ELECTROCYCLIZATION; MIGRATORY INSERTION; POLYCYCLES; REDUCTIVE ELIMINATION; RHODIUM-CATALYZED;

ACETYLENE; CATALYSIS; ISOMERIZATION; RHODIUM;

RHODIUM COMPOUNDS;

ALKYNE; ALKYNE DERIVATIVE; AZULENE DERIVATIVE; RHODIUM;

ARTICLE; CATALYSIS; CHEMISTRY; CYCLOADDITION; ISOMERISM;

ALKYNES; AZULENES; CATALYSIS; CYCLOADDITION REACTION; DIYNES; ISOMERISM; RHODIUM;

EID: 80051776993     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201103136     Document Type: Article

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