Rh(I)-catalyzed intramolecular allenic Pauson-Khand reaction: Construction of a bicyclo[5.3.0]dec-1,7-dien-9-one skeleton

Organic Letters

Volumn 4, Issue 10, 2002, Pages 1755-1758

  Mukai, Chisato ^a   Nomura, Izumi ^a   Yamanishi, Kei ^a   Hanaoka, Miyoji ^a  

^a KANAZAWA UNIVERSITY   (Japan)

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EID: 0001066504     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol020051w     Document Type: Article

References (44)

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40. During this investigation, the Rh(I)-catalyzed PKR of an allenyne leading to formation of the bicyclo[4.3.0]non-1,6-dien-8-one derivative in 61% yield was reported. See ref 13b.
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43. Rh(I)-catalyzed PKR of the sulfoxide derivative 10b was examined under conditions A and B; however, no reaction took place and the starting sulfoxide was completely recovered intact.
44. 2] at the C-1 position of an allenyl moiety instead of a sulfonyl group (e.g., 16a), upon exposure to the Rh(I)-catalyzed cyclization conditions, produced the corresponding bicyclo[5.3.0]dec-1,7-dien-9-one skeleton. The details of these results will be reported later.