Chelation-assisted intramolecular hydroacylation: Synthesis of medium ring sulfur heterocycles

Tetrahedron Letters

Volumn 43, Issue 39, 2002, Pages 7031-7034

  Bendorf, Holly D ^a   Colella, Christine M ^a   Dixon, Elizabeth C ^a   Marchetti, Melissa ^a   Matukonis, Alicia N ^a   Musselman, Jeffrey D ^a   Tiley, Tara A ^a  

^a LYCOMING COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; HETEROCYCLIC COMPOUND; RHODIUM; SULFUR DERIVATIVE;

ARTICLE; ATOM; CATALYST; CHELATION; CHEMICAL ANALYSIS; CHEMICAL REACTION; HYDROACYLATION; SYNTHESIS;

EID: 0037163266     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)01552-6     Document Type: Article

References (25)

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14. For chelation-assisted intermolecular hydroacylation, see: (a) Jun, C. H.; Hong, J. B.; Lee, D. Y. Synlett 1999, 1-12; (b) Jun, C. H.; Lee, H.; Hong, J. B. J. Org. Chem. 1997, 62, 1200-1201.
15. For chelation-assisted intermolecular hydroacylation, see: (a) Jun, C. H.; Hong, J. B.; Lee, D. Y. Synlett 1999, 1-12; (b) Jun, C. H.; Lee, H.; Hong, J. B. J. Org. Chem. 1997, 62, 1200-1201.
16. Derivatives of these compounds, most notably the tetrahydrobenzothiepines, exhibit diverse biological activity. For examples, see: (a) Shiraishi, M.; Baba, M.; Aramaki, Y.; Nishimura, O.; Kanzaki, N. US Patent 6 096 780, 2000; (b) Lee, L. F.; Banerjee, S. C.; Huang, H. C.; Li, J. J.; Miller, R. E.; Reitz, D. B.; Tremont, S. J. US Patent 5 994 391, 1999; (c) Frick, W.; Enhsen A.; Glombik, H.; Heuer, H. US Patent 6 221 897, 2001.
17. Derivatives of these compounds, most notably the tetrahydrobenzothiepines, exhibit diverse biological activity. For examples, see: (a) Shiraishi, M.; Baba, M.; Aramaki, Y.; Nishimura, O.; Kanzaki, N. US Patent 6 096 780, 2000; (b) Lee, L. F.; Banerjee, S. C.; Huang, H. C.; Li, J. J.; Miller, R. E.; Reitz, D. B.; Tremont, S. J. US Patent 5 994 391, 1999; (c) Frick, W.; Enhsen A.; Glombik, H.; Heuer, H. US Patent 6 221 897, 2001.
18. Derivatives of these compounds, most notably the tetrahydrobenzothiepines, exhibit diverse biological activity. For examples, see: (a) Shiraishi, M.; Baba, M.; Aramaki, Y.; Nishimura, O.; Kanzaki, N. US Patent 6 096 780, 2000; (b) Lee, L. F.; Banerjee, S. C.; Huang, H. C.; Li, J. J.; Miller, R. E.; Reitz, D. B.; Tremont, S. J. US Patent 5 994 391, 1999; (c) Frick, W.; Enhsen A.; Glombik, H.; Heuer, H. US Patent 6 221 897, 2001.
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22. 3), δ 205.7, 142.0, 138.0, 130.6, 130.4, 129.7, 125.6, 43.0, 39.7, 34.2, 15.3; LRMS (EI) m/z (%): 192 (65), 145 (100), 136 (28), 131 (18), 121 (25), 108 (18); HRMS (EI) m/z: calcd: 192.0608. Found: 192.0599.
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