Rhodium-catalyzed novel carbonylative carbotricyclization of enediynes [8]

Journal of the American Chemical Society

Volumn 122, Issue 10, 2000, Pages 2385-2386

  Ojima, Iwao ^a   Lee, Seung Yub ^a  

^a STONY BROOK UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL DERIVATIVE; RHODIUM; SILICON DERIVATIVE;

CATALYSIS; CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; CYCLIZATION; LETTER; REACTION ANALYSIS; STEREOSPECIFICITY;

EID: 0034654496     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja993977g     Document Type: Letter

References (22)

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22. 5a.7 Thus, the low concentration of hydrosilane should slow the reductive elimination in these two steps, leading to the selective formation of intermediate f and then the product 8.