Atom-efficient gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols: Substrate scope and experimental and theoretical mechanistic investigation

Chemistry - A European Journal

Volumn 19, Issue 52, 2013, Pages 17939-17950

  Biswas, Srijit ^a   Dahlstrand, Christian ^a   Watile, Rahul A ^a   Kalek, Marcin ^b   Himo, Fahmi ^a,b   Samec, Joseph S M ^a  

^a UPPSALA UNIVERSITY   (Sweden)

^b STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

gold; homogeneous catalysis; reaction mechanisms; sulfenylation; synthetic methods

Indexed keywords

CYCLIC TRANSITIONS; DEUTERIUM LABELING; HOMOGENEOUS CATALYSIS; PROPARGYLIC ALCOHOLS; REACTION MECHANISM; SULFENYLATION; SYNTHETIC METHODS; THEORETICAL STUDY;

ALCOHOLS; CATALYSIS; CHEMICAL BONDS; CHLORINE COMPOUNDS; COORDINATION REACTIONS; DENSITY FUNCTIONAL THEORY; GOLD; HYDRIDES; KETONES; PROTONATION; PROTONS; REACTION INTERMEDIATES; REACTION KINETICS; REGIOSELECTIVITY;

EXPERIMENTS;

EID: 84891011870     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201302485     Document Type: Article

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