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The lower activity of the in situ generated cationic species compared to that of 3 is most probably due to the fact that it is generated in THF instead of acetonitrile, and that THF does not have sufficient coordinating ability to stabilize such cationic species. Indeed no cationic complex of [Ni(NHC)LCp] + type could ever be isolated when the halide was scavenged in a weakly coordinating solvent: V. Ritleng, M. J. Chetcuti, unpublished results. For other nickel hydride species generated by reaction with Ph 2SiH2 or PhSiH3 as a hydride source, see
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A control experiment revealed that the reaction of 3 with 20 equiv. of Ph2SiH2 also generated less than 10% of 1.
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