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Volumn 3, Issue 12, 2013, Pages 3111-3116

Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; HYDROSILYLATION; ORGANIC COMPOUNDS;

EID: 84888234577     PISSN: 20444753     EISSN: 20444761     Source Type: Journal    
DOI: 10.1039/c3cy00514c     Document Type: Article
Times cited : (45)

References (80)
  • 3
    • 84859120511 scopus 로고    scopus 로고
    • For selected examples of Fe-catalyzed hydrosilylation of carbonyl derivatives, see
    • B. A. F. Le Bailly S. P. Thomas RSC Adv. 2011 1 1435
    • (2011) RSC Adv. , vol.1 , pp. 1435
    • Le Bailly, B.A.F.1    Thomas, S.P.2
  • 18
    • 62249128092 scopus 로고    scopus 로고
    • For selected examples of Cu-catalyzed hydrosilylation of carbonyl derivatives, see
    • B. H. Lipshutz Synlett 2009 509
    • (2009) Synlett , pp. 509
    • Lipshutz, B.H.1
  • 54
    • 0035527726 scopus 로고    scopus 로고
    • For selected examples of Ru-catalyzed hydrosilylation of imines, see
    • K. S. Hayes Appl. Catal., A 2001 221 187
    • (2001) Appl. Catal., A , vol.221 , pp. 187
    • Hayes, K.S.1
  • 77
    • 57549083778 scopus 로고    scopus 로고
    • The lower activity of the in situ generated cationic species compared to that of 3 is most probably due to the fact that it is generated in THF instead of acetonitrile, and that THF does not have sufficient coordinating ability to stabilize such cationic species. Indeed no cationic complex of [Ni(NHC)LCp] + type could ever be isolated when the halide was scavenged in a weakly coordinating solvent: V. Ritleng, M. J. Chetcuti, unpublished results. For other nickel hydride species generated by reaction with Ph 2SiH2 or PhSiH3 as a hydride source, see
    • V. Ritleng E. Brenner M. J. Chetcuti J. Chem. Educ. 2008 85 1646
    • (2008) J. Chem. Educ. , vol.85 , pp. 1646
    • Ritleng, V.1    Brenner, E.2    Chetcuti, M.J.3
  • 80
    • 0001100413 scopus 로고    scopus 로고
    • A control experiment revealed that the reaction of 3 with 20 equiv. of Ph2SiH2 also generated less than 10% of 1.
    • F.-G. Fontaine D. Zargarian Organometallics 2002 21 401
    • (2002) Organometallics , vol.21 , pp. 401
    • Fontaine, F.-G.1    Zargarian, D.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.