Hydrosilylation of alkenes and ketones catalyzed by nickel(II) indenyl complexes

Canadian Journal of Chemistry

Volumn 81, Issue 11, 2003, Pages 1299-1306

  Fontaine, Frédéric Georges ^a   Nguyen, René Viet ^a   Zargarian, Davit ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

Cationic complexes; Hydride intermediates; Hydrosilylation; Nickel indenyl complexes

Indexed keywords

CARBON; CATALYSIS; ETHERS; ISOMERS; KETONES; NICKEL; OLEFINS; POSITIVE IONS; STYRENE; SUBSTRATES; THERMAL EFFECTS;

HYDROSILYLATION; REGIOSELECTIVITY;

STEREOCHEMISTRY;

ALKANE; ALUMINUM DERIVATIVE; CATION; CHLORINE; KETONE; NICKEL COMPLEX; NORBORNENE DERIVATIVE; SILANE DERIVATIVE; STYRENE;

ADDITION REACTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; HYDROSILYLATION; ROOM TEMPERATURE; STEREOISOMERISM;

EID: 1642471639     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-133     Document Type: Article

References (40)

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4. For reviews on the hydrosilylation of alkenes and alkynes see: (a) I. Ojima. In The chemistry of organosilicon compounds. Edited by S. Patai and Z. Rappoport. John Wiley, Chichester. 1989. p. 1479; (b) B. Marciniec. Comprehensive handbook on hydrosilylation. Vol. 8. Pergamon Press, Oxford. 1991. p. 763.
5. For a sampling of hydrosilylation systems based on transition metals and lanthanides see the following reports and the references therein: (a) M.B. Carter, B. Schiøtt, A. Gultiérrez, and S. Buchwald. J. Am. Chem. Soc. 116, 11 667 (1994); (b) X. Verdaguer, U.E.W. Lango, and S. Buchwald. Angew. Chem. Int. Ed. 37, 1103 (1998); (c) M.P. Doyle, K.G. High, C.L. Nesloney, T.W. Clayton, Jr., and J. Lin. Organometallics, 10, 1225 (1991); (d) R. Takeuchi and H. Yasue. Organometallics, 15, 2098 (1996); (e) M.L. Christ, S. Sabo-Etienne, and B. Chaudret. Organometallics, 14, 1082 (1995); (f) J.F. Harrod and S. Yun. Organometallics, 6, 1381 (1987); (g) R.S. Tannke and R.H. Crabtree. Organometallics, 10, 415 (1991); (h) G.A. Molander and C.P. Corrette. Organometallics, 17, 5504 (1998); (i) M.F. Lappert and R.K. Maskell. J. Organomet. Chem. 264, 217 (1984).
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7. For a sampling of hydrosilylation systems based on transition metals and lanthanides see the following reports and the references therein: (a) M.B. Carter, B. Schiøtt, A. Gultiérrez, and S. Buchwald. J. Am. Chem. Soc. 116, 11 667 (1994); (b) X. Verdaguer, U.E.W. Lango, and S. Buchwald. Angew. Chem. Int. Ed. 37, 1103 (1998); (c) M.P. Doyle, K.G. High, C.L. Nesloney, T.W. Clayton, Jr., and J. Lin. Organometallics, 10, 1225 (1991); (d) R. Takeuchi and H. Yasue. Organometallics, 15, 2098 (1996); (e) M.L. Christ, S. Sabo-Etienne, and B. Chaudret. Organometallics, 14, 1082 (1995); (f) J.F. Harrod and S. Yun. Organometallics, 6, 1381 (1987); (g) R.S. Tannke and R.H. Crabtree. Organometallics, 10, 415 (1991); (h) G.A. Molander and C.P. Corrette. Organometallics, 17, 5504 (1998); (i) M.F. Lappert and R.K. Maskell. J. Organomet. Chem. 264, 217 (1984).
8. For a sampling of hydrosilylation systems based on transition metals and lanthanides see the following reports and the references therein: (a) M.B. Carter, B. Schiøtt, A. Gultiérrez, and S. Buchwald. J. Am. Chem. Soc. 116, 11 667 (1994); (b) X. Verdaguer, U.E.W. Lango, and S. Buchwald. Angew. Chem. Int. Ed. 37, 1103 (1998); (c) M.P. Doyle, K.G. High, C.L. Nesloney, T.W. Clayton, Jr., and J. Lin. Organometallics, 10, 1225 (1991); (d) R. Takeuchi and H. Yasue. Organometallics, 15, 2098 (1996); (e) M.L. Christ, S. Sabo-Etienne, and B. Chaudret. Organometallics, 14, 1082 (1995); (f) J.F. Harrod and S. Yun. Organometallics, 6, 1381 (1987); (g) R.S. Tannke and R.H. Crabtree. Organometallics, 10, 415 (1991); (h) G.A. Molander and C.P. Corrette. Organometallics, 17, 5504 (1998); (i) M.F. Lappert and R.K. Maskell. J. Organomet. Chem. 264, 217 (1984).
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