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Volumn 21, Issue 2, 2002, Pages 401-408

Dehydrogenative oligomerization of PhSiH3 catalyzed by (1-Me-Indenyl)Ni(PR3)(Me)

Author keywords

[No Author keywords available]

Indexed keywords

OLIGOMERIZATION;

EID: 0001100413     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010757e     Document Type: Article
Times cited : (65)

References (54)
  • 4
    • 12044257523 scopus 로고
    • For a few leading references see: (a) Tilley, T. D. Acc. Chem. Res. 1993, 26, 22.
    • (1993) Acc. Chem. Res. , vol.26 , pp. 22
    • Tilley, T.D.1
  • 16
    • 0003775768 scopus 로고
    • Enraf-Nonius: Delft, The Netherlands
    • CAD-4 Software, version 5.0; Enraf-Nonius: Delft, The Netherlands, 1989.
    • (1989) CAD-4 Software, Version 5.0
  • 18
    • 0004150157 scopus 로고
    • Program for the Solution of Crystal Structures; University of Gottingen: Germany
    • Sheldrick, G. M. SHELXL96, Program for the Solution of Crystal Structures; University of Gottingen: Germany, 1990.
    • (1990) SHELXL96
    • Sheldrick, G.M.1
  • 19
    • 0038251114 scopus 로고    scopus 로고
    • note
    • n are only partially oxidized even after being exposed to air for 12 h in refluxing xylene. We have found, however, that the samples obtained from our Ni-catalyzed reactions are very air-sensitive even at ambient temperature. It is not clear whether this apparently increased air-sensitivity of our polysilane samples is due to the presence of trace amounts of Ni particles left over from the catalytic reactions.
  • 22
    • 0038251113 scopus 로고
    • Ph.D. Thesis, MCGill University
    • (b) Gauvin, F. Ph.D. Thesis, MCGill University, 1992.
    • (1992)
    • Gauvin, F.1
  • 34
    • 0038589597 scopus 로고    scopus 로고
    • note
    • n (ref 13).
  • 38
    • 0038251096 scopus 로고    scopus 로고
    • note
    • 4 samples.
  • 39
    • 0037913581 scopus 로고    scopus 로고
    • note
    • ‡ = -40 ± 4 eu (ref 8).
  • 40
    • 0038251094 scopus 로고    scopus 로고
    • note
    • 3.
  • 41
    • 0038589593 scopus 로고    scopus 로고
    • note
    • 3.
  • 51
    • 0004152918 scopus 로고
    • Robert E. Krieger: Malabar, FL
    • Unusually large kinetic isotope effects are thought to result from the involvement of quantum mechanical tunneling effects in the rate-determining step: Melander, L.; Saunders: W. H., Jr. Reaction Rates of Isotopic Molecules; Robert E. Krieger: Malabar, FL, 1987; p 140.
    • (1987) Reaction Rates of Isotopic Molecules , pp. 140
    • Melander, L.1    Saunders W.H., Jr.2
  • 52
    • 0038589591 scopus 로고    scopus 로고
    • note
    • 3)(X) are stable to hydrolysis, the formation of 3-Me-Ind is unlikely to be related to the residual moisture present in the reaction medium.
  • 53
    • 0038589590 scopus 로고    scopus 로고
    • note
    • n(Me) followed by reductive elimination.
  • 54
    • 0038251092 scopus 로고    scopus 로고
    • note
    • 4 (ref 6).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.