메뉴 건너뛰기




Volumn 3, Issue 1, 2013, Pages 81-84

A convenient nickel-catalysed hydrosilylation of carbonyl derivatives

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL DERIVATIVES; CATALYTIC SYSTEM; NICKEL ACETATE; POLYMETHYLHYDROSILOXANES; REDUCING REAGENTS;

EID: 84870943913     PISSN: 20444753     EISSN: 20444761     Source Type: Journal    
DOI: 10.1039/c2cy20509b     Document Type: Article
Times cited : (35)

References (63)
  • 6
    • 77951145972 scopus 로고    scopus 로고
    • in, ed. M. Beller and C. Bolm, Wiley-VCH, Weinheim, 2nd edn, 2, 182-191
    • H. Nishiyama and K. Itoh, in Transition Metals for Organic Synthesis, ed., M. Beller, and, C. Bolm, Wiley-VCH, Weinheim, 2nd edn, 2004, vol. 2, pp. 182-191
    • (2004) Transition Metals for Organic Synthesis
    • Nishiyama, H.1    Itoh, K.2
  • 15
    • 62249128092 scopus 로고    scopus 로고
    • Selected examples of Cu-catalysed hydrosilylation
    • B. H. Lipshutz Synlett 2009 509
    • (2009) Synlett , pp. 509
    • Lipshutz, B.H.1
  • 49
    • 0028963515 scopus 로고
    • Examples of Ni-catalysed hydrosilylation of alkenes and/or alkynes
    • A. H. Vetter A. Berkessel Synthesis 1995 419
    • (1995) Synthesis , pp. 419
    • Vetter, A.H.1    Berkessel, A.2
  • 52
    • 84862858999 scopus 로고    scopus 로고
    • For examples of selective Ni-catalysed hydrosilylation of alkenes and/or alkynes versus C-heteroatom multiple bonds, see
    • M. I. Lipschutz T. D. Tilley Chem. Commun. 2012 48 7146
    • (2012) Chem. Commun. , vol.48 , pp. 7146
    • Lipschutz, M.I.1    Tilley, T.D.2
  • 56
    • 78149306058 scopus 로고    scopus 로고
    • 2O "99.998% trace metals basis" purchased from Aldrich was used to performed this study, ICP analysis was also performed on this salt, see ESI. For critical review about impurities in catalysis see
    • V. P. Ananikov K. A. Gayduk Z. A. Starikova I. P. Beletskaya Organometallics 2010 29 5098
    • (2010) Organometallics , vol.29 , pp. 5098
    • Ananikov, V.P.1    Gayduk, K.A.2    Starikova, Z.A.3    Beletskaya, I.P.4
  • 59
    • 84856938052 scopus 로고    scopus 로고
    • 3 led to a full conversion for the reduction of p-methoxybenzaldehyde, but only to 57% conversion for p-nitrobenzaldehyde while when using 5 mol% of nickel salt and 10 mol% of phosphine, the conversion for the nitro derivative rose to 87% (Table 2, entry 4). Indeed, these latter conditions were used as standard conditions for the scope of the reaction
    • E. Buitrago F. Tinnis H. Adolfsson Adv. Synth. Catal. 2012 354 217
    • (2012) Adv. Synth. Catal. , vol.354 , pp. 217
    • Buitrago, E.1    Tinnis, F.2    Adolfsson, H.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.