Conversion of carbon dioxide into several potential chemical commodities following different pathways - A review

Materials Science Forum

Volumn 764, Issue , 2013, Pages 1-82

  Ganesh, Ibram ^a  

^a INTERNATIONAL ADVANCED RESEARCH CENTRE FOR POWDER METALLURGY AND NEW MATERIALS ARCI   (India)

Author keywords

Carbon dioxide; Carbon dioxide recycling; Co polymerization; F T synthesis; Global warming; Methanol; Paul sabatier process; Poly and cyclic carbonates; Renewable energy

Indexed keywords

CARBON CAPTURE; CARBON DIOXIDE PROCESS; COAL DEPOSITS; COST EFFECTIVENESS; FOSSIL FUELS; GLOBAL WARMING; HYDROCARBONS; INDICATORS (CHEMICAL); LIQUID FUELS; METHANOL; METHANOL FUELS; SODIUM CARBONATE; SODIUM COMPOUNDS; SOLAR ENERGY; UREA;

CHEMICAL COMMODITIES; COMMODITY CHEMICALS; CYCLIC CARBONATES; F-T SYNTHESIS; GLOBAL WARMING PROBLEMS; HIGH ENERGY DENSITIES; RENEWABLE ENERGIES; VALUE-ADDED CHEMICALS;

CARBON DIOXIDE;

EID: 84882945460     PISSN: 02555476     EISSN: 16629752     Source Type: Book Series    
DOI: 10.4028/www.scientific.net/MSF.764.1     Document Type: Article

References (360)

1. st Canadian CC&S Technology Roadmap Workshop, 2003, Sep., p. 18.
2. P. Tans, Trends in carbon dioxide, NOAA/ESRL, 2009.
3. C. Mandil, Prospects for CO2 capture and storage, International Energy Agency and Energy Technology Analysis, 20 04, IEA Publications: p. http://www.iea.org/textbase/nppdf/free/2004/prospects.pdf.
4. B.M. Reddy, and G. Thrimurthulu, Carbon dioxide-based technologies: converting greenhouse to value added chemicals, Chemical Industry Digest, 2009, July: p. 54.
5. H. Arakawa, M. Aresta, J. N. Armor, M. A. Barteau, E. J. Beckman, A. T. Bell, J. E. Bercaw, C. Creutz, E. Dinjus, D. A. Dixon, K. Domen, D. L. DuBois, J. Eckert, E. Fujita, D. H. Gibson, W. A. Goddard, D. W. Goodman, J. Keller, G. J. Kubas, H. H. Kung, J. E. Lyons, L. E. Manzer, T. J. Marks, K. Morokuma, K. M. Nicholas, R. Periana, L. Que, J. Rostrup-Nielson, W. M. Sachtler, L. D. Schmidt, A. Sen, G. A. Somorjai, P. C. Stair, B. R. Stults, and W. Tumas, Catalysis research of relevance to carbon management: progress, challenges, and opportunities, Chem. Rev., 101 (4) (2001) 953-996.
6. M. Halmann, Photoelectrochemical reduction of aqueous carbon-dioxide on p-type galliumphosphide in liquid junction solar-cells, Nature, 275 (1978) 115.
7. S. W. Xu, Y. Lu, J. Li, Z. Y. Jiang, and H. Wu, Efficient conversion of CO2 to methanol catalyzed by three dehydrogenases co-encapsulated in an alginate-silica (ALG-SiO2) hybrid gel, Ind. Eng. Chem. Res, 45 (2006) 4567.
8. G. A. Olah, A. Geoppert, and G. K. S. Prakash, Chemical recycling of carbon dioxide to methanol and dimethylether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons, J. Org. Chem., 74 (2009) 487.
9. D. J. Darensbourg, Chemistry of carbon dioxide relevant to its utilization: a personal perspective, Inorganic Chemistry, 49 (23) (2010) 10765.
10. E. Barton Cole, P. S. Lakkaraju, D. M. Rampulla, A. J. Morris, E. Abelev, A. B. Bocarsly, Using a one-electron shuttle for the multielectron reduction of CO2 to methanol: kinetic, mechanistic, and structural insights, J. Am. Chem. Soc., 132 (33) (2010) 11539-11551.
11. P. M. Zimmerman, Z. Zhang, and C.B. Musgrave, Simultaneous two-hydrogen transfer as a mechanism for efficient CO2 reduction, Inorganic Chemistry, 49 (19) (2010) 8724-8728.
12. A. J. Traynor, and R. J. Jensen, Direct solar reduction of CO2 to fuel: first prototype results, Ind. Eng. Chem. Res., 41 (8) (2002) 1935-1939.
13. M. Rakowski Dubois, and D. L. Dubois, Development of molecular electrocatalysts for CO2 reduction and H2 production/oxidation, Acc. Chem. Res., 42 (12) (2009) 1974-1982.
14. th International Conference on Greenhouse Gas Control Technology, 1998, Aug 30-Sept 2 (Interlaken, Switzerland).
15. C. Song, Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing, Catal. Today, 115 (2006) 2-32.
16. G. Centi, and S. Perathoner, CO2-based energy vectors for the storage of solar energy, Greenhouse Gas Sci. Technol., 1 (2011) 21.
17. G. A. Olah, A. Goeppert, and G. K. S. Prakash, Beyond oil and gas: the methanol economy, Book, Weinhein, Wiley-VCH, 2006.
18. I. Ganesh, Conversion of carbon dioxide to methanol using solar energy, Cur. Sci., 101 (6) (2011) 731-733.
19. I. Ganesh, Conversion of carbon dioxide to methanol using solar energy-a brief review, Mater. Sci. Appl., 2 (2011) 1407-1415.
20. E. S. Rubin, C. Chen, and A. B. Rao, Cost and performance of fossil fuel power plants with CO2 capture and storage, Energy Policy, 35 (9) (2007) 4444-4454.
21. Z. Jiang, T. Xiao, V. L. Kuznetsov, and P. P. Edwards, Turning carbon dioxide into fuel, Phil. Trans. R. Soc, 368 (A) (2010) 3343.
22. M. Peters, T. Mueller, and W. Leitner, CO2: from waste to value, Tce 813 (2009) 46.
23. M. Aresta, Carbon dioxide as chemical feedstock, Book, Wiley-VCH, Weinheim, 2010.
24. M. Aresta, and A. Dibenedetto, Utilisation of CO2 as a chemical feedstock: opportunities and challenges, Dalton Trans., (2007) 2975.
25. G. Centi, and S. Perathoner, Opportunities and prospects in the chemical recycling of carbon dioxide to fuels, Catal Today 148 (3-4) (2009) 191.
26. K. Hoekman, A. Broch, C. Robbins, and R. Purcell, CO2 recycling by reaction with renewably-generated hydrogen, Int. J. Greenhouse Gas Control, 4 (2010) 44.
27. J. Ma, N. Sun, X. Zhang, N. Zhao, F. Xiao, W. Wei, and Y. Sun, A short review of catalysis for CO2 conversion, Catal Today 148 (3-4) (2009) 221.
28. Y. P. Patil, P. J. Tambade, S. R. Jagtap, and B. M. Bhanage, Carbon dioxide: a renewable feedstock for the synthesis of fine and bulk chemicals, Front. Chem. Eng. China, 4 (2) (2010) 213.
29. T. Sakakura, J.-C. Choi, and H. Yasuda, Transformation of carbon dioxide, Chem. Rev., 107 (6) (2007) 2365.
30. M. Schaefer, F. Behrendt, and T. Hammer, Evaluation of strategies for the subsequent use of CO2, Front. Chem. Eng. China, 4 (2) (2010) 172.
31. M.-J. Choi, and D.-H. Chol, Review: research activities on the utilization of carbon dioxide in Korea, Clean, 36 (5-6) (2008) 426.
32. nd September, 1986.
33. th May), p. Publication number: US 2008/0287555 A1.
34. S. Inoue, H. Koinuma, and T. Tsuruta, Copolymerization of carbon dioxide and epoxide with organometallic compounds, Makromol. Chem., 130 (1969) 210-220.
35. F. Li, C. Xia, L. Xu, W. Sun, and G. Chen, A novel and effective Ni complex catalyst system for the coupling reactions of carbon dioxide and epoxides, Chem. Commun., (2003) 2042-2043.
36. J. Peng, and Y. Deng, Cycloaddition of carbon dioxide to propylene oxide catalyzed by ionic liquids, New J. Chem., 25 (2001) 639-641.
37. K. Yamaguchi, K. Ebitani, T. Yoshida, H. Yoshida, K. Kaneda, Mg-Al mixed oxides as highly active acid-base catalysts for cycloaddition of carbon dioxide to epoxides, J. Am. Chem. Soc., 121 (1999) 4526-4527.
38. H. Yasuda, L.-N. He, and T. Sakakura, Cyclic carbonate synthesis from supercritical carbon dioxide and epoxide over lanthanide oxychloride, J. Catal., 209 (2002) 547-550.
39. R. L. Paddock, and S. T. Nguyen, Chemical CO2 fixation: Cr(III) salen complexes as highly efficient catalysts for the coupling of CO2 and epoxides, J. Am. Chem. Soc., 123 (2001) 11498-11499.
40. X. -B. Lu, R. He, and C.-X. Bai, Synthesis of ethylene carbonate from supercritical carbon dioxide/ethylene oxide mixture in the presence of bifunctional catalyst, J. Mol. Catal. A: Chem., 186 (2002) 1-11.
41. M. Tu, and R. J. Davis, Cycloaddition of CO2 to Epoxides over Solid Base Catalysts, J. Catal., 199 (2001) 85-91.
42. P. Tascedda, M. Weidmann, E. Dinjus, and E. Dunach, Nickel-catalyzed electrochemical carboxylation of epoxides: mechanistic aspects, Appl. Organomet. Chem., 15 (2001) 141-144.
43. T. Yano, H. Matsui, T. Koike, H. Ishiguro, H. Fujihara, M. Yoshihara, T. Maeshima, Magnesium oxide-catalyzed reaction of carbon dioxide with an epoxide with retention of stereochemistry, Chem. Commun., (1997) 1129-1130.
44. D. J. Darensbourg, R. M. Mackiewicz, and D. R. Billodeaux, Pressure Dependence of the Carbon Dioxide/Cyclohexene Oxide Coupling Reaction Catalyzed by Chromium Salen Complexes. Optimization of the Comonomer-Alternating Enchainment Pathway, Organometallics, 24 (2005) 144-148.
45. D. J. Darensbourg, C. C. Fang, and J. L. Rodgers, Catalytic coupling of carbon dioxide and 2,3-Epoxy-1,2,3,4-tetrahydronaphthalene in the presence of a (Salen)CrIIICl derivative, Organometallics, 23 (2004) 924-927.
46. S. -W. Chen, R. B. Kawthekar, and G. -J. Kim, Efficient catalytic synthesis of optically active cyclic carbonates via coupling reaction of epoxides and carbon dioxide, Tetrahedron Lett., 48 (2007) 297-300.
47. M. Aresta, A. Dibenedetto, C. Dileo, I. Tommasi, and E. Amodio, A first synthesis of a cyclic carbonate from a ketal in supercritical CO2, J. Supercrit. Fluids, 25 (2003) 177.
48. D. J. Darensbourg, R. M. Mackiewicz, A. L. Phelps, D. R. Billodeaux, Copolymerization of CO2 and epoxides catalyzed by metal salen complexes, Acc. Chem. Res., 37 (2004) 836-844.
49. T. Bok, E. K. Noh, and B. Y. Lee, Coupling reaction of CO2 with epoxides by binary catalytic system of Lewis acids and onium salts, Bull. Korean Chem. Soc., 27 (2006) 1171-1174.
50. C. Hongfa, J. Tian, J. Andreatta, D. J. Darensbourg, and D. E. Bergbreiter, A phase separable polycarbonate polymerization catalyst, Chem. Commun., (2008) 975-977.
51. D. J. Darensbourg, A. Horn, Jr., and A. I. Moncada, A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide, Green Chem., 12 (2010) 1376-1379.
52. D. J. Darensbourg, P. Ganguly, and W. Choi, Metal salen derivatives as catalysts for the alternating copolymerization of oxetanes and carbon dioxide to afford polycarbonates, Inorg. Chem., 45 (2006) 3831-3833.
53. T. Bok, H. Yun, and B.Y. Lee, Bimetallic fluorine-substituted anilido-aldimine zinc complexes for CO2/(cyclohexene oxide) copolymerization, Inorg. Chem., 45 (2006) 4228-4237.
54. M. R. Kember, A. J. P. White, and C. K. Williams, Di- and tri-zinc catalysts for the lowpressure copolymerization of CO2 and cyclohexene oxide, Inorg. Chem., 48 (19) (2009) 9535-9542.
55. D. J. Darensbourg, and S. B. Fitch, (Tetramethyltetraazaannulene)chromium chloride: a highly active catalyst for the alternating copolymerization of epoxides and carbon dioxide, Inorg. Chem. 46 (2007) 5474-5476.
56. D. J. Darensbourg, J. R. Wildeson, J. C. Yarbrough, J. H. Reibenspies, Bis 2,6-difluorophenoxide dimeric complexes of zinc and cadmium and their phosphine adducts: lessons learned relative to carbon dioxide/cyclohexene oxide alternating copolymerization processes catalyzed by zinc phenoxides, J. Am. Chem. Soc., 122 (50) (2000) 12487-12496.
57. M. Cheng, D. R. Moore, J. J. Reczek, B. M. Chamberlain, E. B. Lobkovsky, G. W. Coates, Single-site β-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides: catalyst synthesis and unprecedented polymerization activity, J. Am. Chem. Soc., 123 (2001) 8738-8749.
58. C. T. Cohen, T. Chu, and G. W. Coates, Cobalt catalysts for the alternating copolymerization of propylene oxide and carbon dioxide: combining high activity and selectivity, J. Am. Chem. Soc., 127 (2005) 10869-10878.
59. D. J. Darensbourg, and R. M. Mackiewicz, Role of the cocatalyst in the copolymerization of CO2 and cyclohexene oxide utilizing chromium salen complexes, J. Am. Chem. Soc., 127 (2005) 14026-14038.
60. E. K. Noh, S. J. Na,; S. S, S.-W. Kim, x>and B. Y. Lee, Two components in a molecule: highly efficient and thermally robust catalytic system for CO2/epoxide copolymerization, J. Am. Chem. Soc., 129 (2007) 8082-8083.
61. B. Y. Lee, H. Y. Kwon, S. Y. Lee, S. J. Na, S. -i. Han, H. Yun, H. Lee, Y. -W. Park, Bimetallic anilido-aldimine zinc complexes for epoxide/CO2 copolymerization, J. Am. Chem. Soc., 127 (2005) 3031-3037.
62. L. Shi, X. -B. Lu, R. Zhang, X. -J. Peng, C. -Q. Zhang, J. -F. Li, and X. -M. Peng, Asymmetric alternating copolymerization and terpolymerization of epoxides with carbon dioxide at mild conditions, Macromolecules, 39 (2006) 5679-5685.
63. H. Sugimoto, and K. Kuroda, The cobalt porphyrin-lewis base system: a highly selective catalyst for alternating copolymerization of CO2 and epoxide under mild conditions, Macromolecules, 41 (2008) 312-317.
64. S. Mang, A. I. Cooper, M. E. Colclough, N. Chauhan, and A. B. Holmes, Copolymerization of CO2 and 1,2-cyclohexene oxide using a CO2-soluble chromium porphyrin catalyst, Macromolecules, 33 (2000) 303-308.
65. R. Eberhardt, M. Allmendinger, G. A. Luinstra, and B. Rieger, The ethylsulfinate ligand: a highly efficient initiating group for the zinc β-diiminate catalyzed copolymerization reaction of CO2 and epoxides, Organometallics, 22 (2003) 211-214.
66. M. F. Pilz, C. Limberg, B. B. Lazarov, K. C. Hultzsch, B. Ziemer, Dinuclear zinc complexes based on parallel β-diiminato binding sites: syntheses, structures, and properties as CO2/epoxide copolymerization catalysts, Organometallics, 26 (2007) 3668-3676.
67. C. Koning, J. Wildeson, R. Parton, B. Plum, P. Steeman, and D. J. Darensbourg, Synthesis and physical characterization of poly(cyclohexane carbonate), synthesized from CO2 and cyclohexene oxide, Polymer, 42 (2001) 3995-4004.
68. J. Sun, W. Cheng, W. Fan, Y. Wang, Z. Meng, and S. Zhang, Reusable and efficient polymer-supported task-specific ionic liquid catalyst for cycloaddition of epoxide with CO2, Catal. Today, 148 (2009) 361-367.
69. J. Sun, S. Zhang, W. Cheng, and J. Ren, Hydroxyl-functionalized ionic liquid: a novel efficient catalyst for chemical fixation of CO2 to cyclic carbonate, Tetrahedron Lett., 49 (2008) 3588-3591.
70. A. Baba, T. Nozaki, and H. Matsuda, Carbonate formation from oxiranes and carbon dioxide catalyzed by organotin halide-tetraalkylphosphonium halide complexes, Bull. Chem. Soc. Jpn., 60 (1987) 1552-1554.
71. H. Matsuda, A. Ninagawa, and R. Nomura, Reaction of carbon dioxide with epoxides in the presence of pentavalent organoantimony compounds, Chem. Lett., (1979) 1261-1262.
72. H. S. Kim, J. Y. Bae, J. S. Lee, O. S. Kwon, P. Jelliarko, S. D. Lee, and S. -H. Lee, Phosphine-bound zinc halide complexes for the coupling reaction of ethylene oxide and carbon dioxide, J. Catal., 232 (2005) 80-84.
73. H. S. Kim, J. J. Kim, H. N. Kwon, M. J. Chung, B. G. Lee, and H. G. Jang, Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides, J. Catal., 205 (2002) 226-229.
74. J. Sun, S. -I. Fujita, F. Zhao, and M. Arai, A highly efficient catalyst system of ZnBr2/n-Bu4NI for the synthesis of styrene carbonate from styrene oxide and supercritical carbon dioxide. Appl. Catal., A, 287 (2005) 221-226.
75. F. Ono, K. Qiao, D. Tomida, and C. Yokoyama, Rapid synthesis of cyclic carbonates from CO2 and epoxides under microwave irradiation with controlled temperature and pressure, J. Mol. Catal. A: Chem., 263 (2007) 223-226.
76. H. Kisch, R. Millini, and I. J. Wang, Preparation of cyclic carbonates from oxiranes and carbon dioxide in the presence of bifunctional catalysts, Chem. Ber., 119 (1986) 1090-1094.
77. S. -S. Wu, X. -W. Zhang, W. -L. Dai, S. -F. Yin, W. -S. Li, Y. -Q. Ren, C. -T. Au, ZnBr2-Ph4PI as highly efficient catalyst for cyclic carbonates synthesis from terminal epoxides and carbon dioxide, Appl. Catal., A, 341 (2008) 106-111.
78. H. Jing, and S. T. Nguyen, SnCl4-organic base: highly efficient catalyst system for coupling reaction of CO2 and epoxides, J. Mol. Catal. A: Chem., 261 (2007) 12-15.
79. J. -W. Huang, and M. Shi, Chemical fixation of carbon dioxide by NaI/PPh3/PhOH, J. Org. Chem., 68 (2003) 6705-6709.
80. C. R. Gomes, D. M. Ferreira, C. J. L. Constantino, and E. R. P. Gonzalez, Selectivity of the cyclic carbonate formation by fixation of carbon dioxide into epoxides catalyzed by Lewis bases, Tetrahedron Lett., 49 (2008) 6879-6881.
81. R. Srivastava, D. Srinivas, and P. Ratnasamy, Synthesis of polycarbonate precursors over titanosilicate molecular sieves, Catal. Lett., 91 (2003) 133-139.
82. R. Srivastava, D. Srinivas, and P. Ratnasamy, Syntheses of polycarbonate and polyurethane precursors utilizing CO2 over highly efficient, solid as-synthesized MCM-41 catalyst, Tetrahedron Lett., 47 (2006) 4213-4217.
83. K. Mori, Y. Mitani, T. Hara, T. Mizugaki, K. Ebitani, K. Kaneda, A single-site hydroxyapatite-bound zinc catalyst for highly efficient chemical fixation of carbon dioxide with epoxides, Chem. Commun., 3331-3333.
84. W. -L. Dai, S. -F. Yin, R. Guo, S. -L. Luo, X. Du, and C. -T. Au, Synthesis of propylene carbonate from carbon dioxide and propylene oxide using Zn-Mg-Al composite oxide as high-efficiency catalyst, Catal. Lett., 136 (2010) 35-44.
85. W. J. Kruper, and D. D. Dellar, Catalytic formation of cyclic carbonates from epoxides and O2 with chromium metalloporphyrinates, J. Org. Chem., 60 (1995) 725-727.
86. W. -L. Wong, K. -C. Cheung, P. -H. Chan, Z. -Y. Zhou, K. -H. Lee, and K. -Y. Wong, A tricarbonyl rhenium(I) complex with a pendant pyrrolidinium moiety as a robust and recyclable catalyst for chemical fixation of carbon dioxide in ionic liquid, Chem. Commun., (2007) 2175-2177.
87. X. Zhang, W. Dai, S. Yin, S. Luo, and C. -T. Au, Cationic organobismuth complex as an effective catalyst for conversion of CO2 into cyclic carbonates, Front. Environ. Sci. Eng. China, 3 (2009) 32-37.
88. J. Wang, J. Wu, and N. Tang, Synthesis, characterization of a new bicobalt complex [Co2L2(C2H5OH)2Cl2] and application in cyclic carbonate synthesis, Inorg. Chem. Commun., 10 (2007) 1493-1495.
89. M. Alvaro, C. Baleizao, D. Das, E. Carbonell, and H. Garcia, CO2 fixation using recoverable chromium Salen catalysts: use of ionic liquids as cosolvent or high-surface-area silicates as supports, J. Catal., 228 (2004) 254-258.
90. X. Zhang, Y. -B. Jia, X. -B. Lu, B. Li, H. Wang, and L. -C. Sun, Intramolecularly twocentered cooperation catalysis for the synthesis of cyclic carbonates from CO2 and epoxides, Tetrahedron Lett., 49 (2008) 6589-6592.
91. X. -B. Lu, Y. -J. Zhang, K. Jin, L. -M. Luo, and H. Wang, Highly active electrophilenucleophile catalyst system for the cycloaddition of CO2 to epoxides at ambient temperature, J. Catal., 227 (2004) 537-541.
92. X. -B. Lu, Y. -J. Zhang, B. Liang, X. Li, and H. Wang, Chemical fixation of carbon dioxide to cyclic carbonates under extremely mild conditions with highly active bi-functional catalysts. J. Mol. Catal. A: Chem., 210 (2004) 31-34.
93. H. Zhou, W. -Z. Zhang, C. -H. Liu, J. -P. Qu, and X. -B. Lu, CO2 adducts of N-heterocyclic carbenes: thermal stability and catalytic activity toward the coupling of CO2 with epoxides, J. Org. Chem., 73 (2008) 8039-8044.
94. X. -B. Lu, B. Liang, Y. -J. Zhang, Y. -Z. Tian, Y. -M. Wang, C. -X. Bai, H. Wang, and R. Zhang, Asymmetric catalysis with CO2: direct synthesis of optically active propylene carbonate from racemic epoxides, J. Am. Chem. Soc., 126 (2004) 3732-3733.
95. X. -B. Lu, J. -H. Xiu, R. He, K. Jin, L. -M. Luo, and X. -J. Feng, Chemical fixation of CO2 to ethylene carbonate under supercritical conditions: continuous and selective, Appl. Catal., A, 275 (2004) 73-78.
96. R. L. Paddock, and S. T. Nguyen, Chiral (salen) CoIII catalyst for the synthesis of cyclic carbonates, Chem. Commun., (2004) 1622-1623.
97. T. Chang, H. Jing, L. Jin, and W. Qiu, Quaternary onium tribromide catalyzed cyclic carbonate synthesis from carbon dioxide and epoxides, J. Mol. Catal. A: Chem., 264 (2007) 241-247.
98. L. Jin, Y. Huang, H. Jing, T. Chang, and P. Yan, Chiral catalysts for the asymmetric cycloaddition of carbon dioxide with epoxides, Tetrahedron: Asymmetry, 19 (2008) 1947-1953.
99. P. Yan, and H. Jing, Catalytic asymmetric cycloaddition of carbon dioxide and propylene oxide using novel chiral polymers of BINOL-Salen-cobalt(III) salts, Adv. Synth. Catal., 351 (2009) 1325-1332.
100. H. Jing, T. Chang, L. Jin, M. Wu, and W. Qiu, Ruthenium salen/phenyltrimethylammonium tribromide catalyzed coupling reaction of carbon dioxide and epoxides, Catal. Commun., 8 (2007) 1630-1634.
101. D. Guironnet, I. Göttker-Schnetmann, and S. Mecking, Catalytic polymerization in dense CO2 to controlled microstructure polyethylenes, Macromolecules, 42 (21) (2009) 8157-8164.
102. S. Inoue, H. Koinuma, and T. Tsuruta, Copolymerization of carbon dioxide and epoxide, J. Polym. Sci., Part B, 7 (1969) 287-292.
103. G. W. Coates, and D. R. Moore, Discrete metal-based catalysts for the copolymerization of CO2 and epoxides: Discovery, reactivity, optimization, and mechanism, Angew. Chem., Int. Ed., 43 (2004) 6618-6639.
104. D. J. Darensbourg, Making plastics from carbon dioxide: Salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2. Chem. Rev., 107 (2007) 2388-2410.
105. H. Sugimoto, and S. Inoue, Copolymerization of carbon dioxide and epoxide, J. Polym. Sci., Part A: Polym. Chem., 42 (2004) 5561-5573.
106. K. Nozaki, Asymmetric catalytic synthesis of polyketones and polycarbonates, Pure Appl. Chem., 76 (2004) 541-546.
107. D. R. Moore, M. Cheng, E. B. Lobkovsky, and G. W. Coates, Electronic and steric effects on catalysts for CO2/epoxide polymerization: subtle modifications resulting in superior activities, Angew. Chem., Int. Ed., 41 (2002) 2599-2602.
108. D. R. Moore, M. Cheng, E. B. Lobkovsky, and G. W. Coates, Mechanism of the alternating copolymerization of epoxides and CO2 using β-diiminate zinc catalysts: Evidence for a bimetallic epoxide enchainment, J. Am. Chem. Soc., 125 (2003) 11911-11924.
109. D. J. Darensbourg, and J. C. Yarbrough, Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, Using a chiral Salen chromium chloride catalyst, J. Am. Chem. Soc., 124 (2002) 6335-6342.
110. H. Zhou, W. -Z. Zhang, Y. -M. Wang, J. -P. Qu, and X. -B. Lu, N-heterocyclic carbine functionalized polymer for reversible fixation-release of CO2, Macromolecules, 42 (2009) 5419-5421.
111. B. Schaffner, F. Schaffner, S. P. Verevkin, and A. Borner, Organic carbonates as solvents in synthesis and catalysis, Chem. Rev., 110 (8) (2010) 4554-4581.
112. Z. Yu, L. Xu, Y. Wei, Y. Wang, Y. He, Q. Xia, X. Zhang, and Z. Liu, A new route for the synthesis of propylene oxide from bio-glycerol derivated propylene glycol, Chem. Commun., 14 (26) (2009) 3934-3936.
113. S. Chen, G. -R. Qi, Z. -J. Hua, and H. -Q. Yan, J. Polym. Sci. Part A: Polym. Chem., 42 (2004) 5284.
114. P. Ratnasamy, and D. Srinivas, Chemicals from carbon dioxide, Handbook of Heterogeneous Catalysis, G. Ertl, H. Knoezinger, F. Schueth, J. Weitkamp (eds.), 2nd edn., Wiley-VCH, Germany, (2008), p. 3717.
115. J. Melendez, M. North, and R. Pasquale, Synthesis of cyclic carbonates from atmospheric pressure carbon dioxide using exceptionally active aluminium(salen) complexes as catalysts, Eur. J. Inorg. Chem., (2007) 3323-3326.
116. M. North, and R. Pasquale, Mechanism of cyclic carbonate synthesis from epoxides and CO2, Angew. Chem., Int. Ed., 48 (2009) 2946-2948.
117. D. J. Darensbourg, and M. W. Holtcamp, Catalysts for the reactions of epoxides and carbon dioxide, Coord. Chem. Rev., 153 (1996) 155-174.
118. M. North, R. Pasquale, and C. Young, Synthesis of cyclic carbonates from epoxides and CO2, Green Chem., 12 (2010) 1514-1539.
119. E. N. Jacobsen, Asymmetric catalysis of epoxide ring-opening reactions, Acc. Chem. Res., 33 (2000) 421-431.
120. G. A. Luinstra, Poly(propylene carbonate), old copolymers of propylene oxide and carbon dioxide with new interests: catalysis and material properties, Polym. Rev., 48 (2008) 192-219.
121. S. Sujith, J. K. Min, J. E. Seong, S. J. Na, and B. Y. Lee, A highly active and recyclable catalytic system for CO2/propylene oxide copolymerization, Angew. Chem. Int. Ed. Engl., 47 (2008) 7306-7309.
122. A. Cyriac, S. H. Lee, J. K. Varghese, E. S. Park, J. H. Park, and B. Y. Lee, Immortal CO2/propylene oxide copolymerization: precise control of molecular weight and architecture of various block copolymers, Macromolecules, 43 (2010) 7398-7401.
123. D. J. Darensbourg, M. W. Holtcamp, G. E. Struck, M. S. Zimmer, S. A. Niezgoda, P. Rainey, J. B. Robertson, J. D. Draper, J. H. Reibenspies, Catalytic activity of a series of Zn(II) phenoxides for the copolymerization of epoxides and carbon dioxide, J. Am. Chem. Soc., 121 (1999) 107-116.
124. D. J. Darensbourg, J. R. Wildeson, J. C. Yarbrough, and J. H. Reibenspies, Bis 2,6-difluorophenoxide dimeric complexes of zinc and cadmium and their phosphine adducts: lessons learned relative to carbon dioxide/cyclohexene oxide alternating copolymerization processes catalyzed by zinc phenoxides, J. Am. Chem. Soc., 122 (2000) 12487-12496.
125. S. D. Allen, D. R. Moore, E. B. Lobkovsky, and G. W. Coates, High-activity, single-site catalysts for the alternating copolymerization of CO2 and propylene oxide, J. Am. Chem. Soc., 124 (2002) 14284-14285.
126. M. Cheng, E. B. Lobkovsky, and G. W. Coates, Catalytic reactions involving C1 feedstocks: new high-activity Zn(II)-based catalysts for the alternating copolymerization of carbon dioxide and epoxides, J. Am. Chem. Soc., 120 (1998) 11018-11019.
127. Z. Qin, C. M. Thomas, S. Lee, and G. W. Coates, Cobalt-based complexes for the copolymerization of propylene oxide and CO2: Active and for polycarbonate synthesis. Angew. Chem., Int. Ed., 42 (2003) 5484-5487.
128. Y. Xiao, Z. Wang, and K. Ding, Copolymerization of cyclohexene oxide with CO2 by using intramolecular dinuclear zinc catalysts, Chem. Eur. J., 11 (2005) 3668-3678.
129. Y. Xiao, Z. Wang, and K. Ding, Intramolecularly dinuclear magnesium complex catalyzed copolymerization of cyclohexene oxide with CO2 under ambient CO2 pressure: kinetics and mechanism, Macromolecules, 39 (2006) 128-137.
130. H. Sugimoto, H. Ohshima, and S. Inoue, Alternating copolymerization of carbon dioxide and epoxide by manganese porphyrin: the first example of polycarbonate synthesis from 1- atm carbon dioxide. J. Polym. Sci., Part A: Polym. Chem., 41 (2003) 3549-3555.
131. N. H. Pilkington, and R. Robson, Complexes of binucleating ligands, III. novel complexes of a macrocyclic binucleating ligand, Aust. J. Chem., 23 (1970) 2225-2236.
132. B. F. Hoskins, R. Robson, and G.A. Williams, Complexes of binucleating ligands, VIII. The preparation, structure and properties of some mixed valence cobalt(II)-cobalt(III) complexes of a macrocyclic binucleating ligand, Inorg. Chim. Acta, 16 (1976) 121-133.
133. S. K. Mandal, L. K. Thompson, M. J. Newlands, E. J. Gabe, and K. Nag, Structural and magnetic studies on macrocyclic dicopper(II) complexes: influence of electron-withdrawing axial ligands on spin exchange, Inorg. Chem., 29 (1990) 1324-1327.
134. S. K. Mandal, L. K. Thompson, M. J. Newlands, and E. J. Gabe, Structural, magnetic, and electrochemical studies on macrocyclic dicopper(II) complexes with varying chelate ring size, Inorg. Chem., 28 (1989) 3707-3713.
135. A. J. Atkins, D. Black, A. J. Blake, A. Marin-Becerra, S. Parsons, L. Ruiz-Ramirez, and M. Schroder, Schiff-base compartmental macrocyclic complexes, Chem. Commun., (1996) 457-464.
136. H. Okawa, H. Furutachi, and D. E. Fenton, Heterodinuclear metal complexes of phenolbased compartmental macrocycles, Coord. Chem. Rev., 174 (1998) 51-75.
137. A. J. Atkins, D. Black, R. L. Finn, A. Marin-Becerra, A. J. Blake, L. Ruiz-Ramirez, W. -S. Li, and M. Schroeder, Synthesis and structure of mononuclear and binuclear zinc(II) compartmental macrocyclic complexes, Dalton Trans., (2003) 1730-1737.
138. M. R. Kember, P. D. Knight, P. T. R. Reung, and C. K. Williams, Highly active dizinc catalyst for the copolymerization of carbon dioxide and cyclohexene oxide at one atmosphere pressure, Angew. Chem., Int. Ed., 48 (2009) 931-933.
139. M. W. J. Van, R. Duchateau, C. E. Koning, and G. -J. M. Gruter, Unexpected side reactions and chain transfer for zinc-catalyzed copolymerization of cyclohexene oxide and carbon dioxide, Macromolecules, 38 (2005) 7306-7313.
140. A. Dedieu, C. Bo, and F. Ingold, In metal-ligand interactions: from atoms, to clusters, to surfaces, NATO ASI Series; D. Salahub, Ed., Kluwer: Dordrecht, The Netherlands, (1992).
141. O. R. Allen, S. J. Dalgarno, L. D. Field, P. Jensen, and A. C. Willis, Insertion of CO2 into the Ru-C bonds of cis- and trans-Ru(dmpe)2Me2 (dmpe = Me2PCH2CH2PMe2), Organometallics, 28 (2009) 2385-2390.
142. D. J. Darensbourg, C. Ovalles, and M. Pala, Homogeneous catalysts for carbon dioxide/hydrogen activation. Alkyl formate production using anionic ruthenium carbonyl clusters as catalysts, J. Am. Chem. Soc., 105 (1983) 5937-5939.
143. D. J. Darensbourg, and C. Ovalles, Anionic group 6B metal carbonyls as homogeneous catalysts for carbon dioxide/hydrogen activation: the production of alkyl formats, J. Am. Chem. Soc., 106 (1984) 3750-3754.
144. D. J. Darensbourg, and C. Ovalles, Homogeneous catalytic synthesis of alkyl formats from the reaction of alkyl halides, carbon dioxide, and hydrogen in the presence of anionic Group 6 carbonyl catalysts and sodium salts, J. Am. Chem. Soc., 109 (1987) 3330-3336.
145. M. Takimoto, Y. Nakamura, K. Kimura, and M. Mori, Highly enantioselective catalytic carbon dioxide incorporation reaction: nickel-catalyzed asymmetric carboxylative cyclization of bis-1,3-dienes, J. Am. Chem. Soc., 126 (2004) 5956-5957.
146. C. M. Williams, J. B. Johnson, and T. Rovis, Nickel-catalyzed reductive carboxylation of styrenes using CO2, J. Am. Chem. Soc., 130 (2008) 14936-14937.
147. J. Takaya, and N. Iwasawa, Hydrocarboxylation of allenes with CO2 catalyzed by silyl pincer-type palladium complex, J. Am. Chem. Soc., 130 (2008) 15254-15255.
148. S. N. Riduan, Y. Zhang, and J. Y. Ying, Conversion of carbon dioxide into methanol with silanes over N-heterocyclic carbene catalysts, Angew. Chem., Int. Ed., 48 (2009) 3322-3325.
149. I. I. F. Boogaerts, and S. P. Nolan, Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes, J. Am. Chem. Soc., 132 (2010) 8858-8859.
150. P. G. Jessop, F. Joo, and C. -C. Tai, Recent advances in the homogeneous hydrogenation of carbon dioxide, Coord. Chem. Rev., 248 (2004) 2425-2442.
151. A. D. Getty, C. -C. Tai, J. C. Linehan, P. G. Jessop, M. M. Olmstead, and A. L. Rheingold, Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: a mechanistic investigation using high-pressure NMR spectroscopy, Organometallics, 28 (2009) 5466-5477.
152. A. Rokicki, and W. Kuran, The application of carbon dioxide as a direct material for polymer syntheses in polymerization and polycondensation reactions, J. Macromol. Sci., Rev. Macromol. Chem., C21 (1981) 135-186.
153. D. C. Webster, Cyclic carbonate functional polymers and their applications, Progre. Org. Coatings, 47 (1) (2003) 77-86.
154. D. J. Darensbourg, J. R. Wildeson, S. J. Lewis, and J. C. Yarbrough, Solution and solid-state structural studies of epoxide adducts of cadmium phenoxides: chemistry relevant to epoxide activation for ring-opening reactions, J. Am. Chem. Soc., 124 (2002) 7075-7083.
155. C. Baleizao, and H. Garcia, Chiral salen complexes: an overview to recoverable and reusable homogeneous and heterogeneous catalysts, Chem. Rev., 106 (2006) 3987-4043.
156. L. Phan, J. R. Andreatta, L. K. Horvey, C. F. Edie, A. -L. Luco, A. Mirchandani, D. J. Darensbourg, and P. G. Jessop, Switchable-polarity solvents prepared with a single liquid component, J. Org. Chem., 73 (1) (2008) 127-132.
157. M. H. Chisholm, and Z. Zhou, New generation polymers: the role of metal alkoxides as catalysts in the production of polyoxygenates, J. Mater. Chem., 14 (2004) 3081-3092.
158. B. Ochiai, and T. Endo, Carbon dioxide and carbon disulfide as resources for functional polymers. Prog. Polym. Sci., 30 (2005) 183-215.
159. K. Nakano, N. Kosaka, T. Hiyama, and K. Nozaki, Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates, Dalton Trans., (2003) 4039-4050.
160. D. J. Darensbourg, and A. I. Moncada, Mechanistic insight into the initiation step of the coupling reaction of oxetane or epoxides and CO2 catalyzed by (salen)CrX complexes, Inorg. Chem., 47 (2008) 10000-10008.
161. D. J. Darensbourg, A. I. Moncada, W. Choi, and J. H. Reibenspies, Mechanistic studies of the copolymerization reaction of oxetane and carbon dioxide to provide aliphatic polycarbonates catalyzed by (Salen)CrX complexes, J. Am. Chem. Soc., 130 (2008) 6523-6533.
162. D. J. Darensbourg, and S. B. Fitch, Copolymerization of epoxides and carbon dioxide: evidence supporting the lack of dual catalysis at a single metal site, Inorg. Chem., 48 (2009) 8668-8677.
163. B. L. Seal, T. C. Otero, and A. Panitch, Polymeric biomaterials for tissue and organ regeneration, Mater. Sci. Eng., R, R34 (2001) 147-230.
164. S. Harder, From limestone to catalysis: application of calcium compounds as homogeneous catalysts, Chem. Rev., 110 (2010) 3852-3876.
165. D. J. Darensbourg, W. Choi, O. Karroonnirun, and N. Bhuvanesh, Ring-opening polymerization of cyclic monomers by complexes derived from biocompatible metals: production of poly(lactide), poly(trimethylene carbonate), and their copolymers, Macromolecules, 41 (2008) 3493-3502.
166. A. -P. Zeng, and H. Biebl, Bulk chemicals from biotechnology: The case of 1,3-propanediol production and the new trends. Adv. Biochem. Eng./Biotechnol., 74 (2002) 239-259.
167. C. E. Nakamura, and G. M. Whited, Metabolic engineering for the microbial production of 1,3-propanediol, Curr. Opin. Biotechnol., 14 (2003) 454-459.
168. W. -M. Ren, Z. -W. Liu, Y. -Q. Wen, R. Zhang, and X. -B. Lu, Mechanistic aspects of the copolymerization of CO2 with epoxides using a thermally stable single-site cobalt(III) catalyst, J. Am. Chem. Soc., 131 (32) (2009) 11509-11518.
169. G. -P. Wu, S. -H. Wei, X. -B. Lu, W. -M. Ren, and D. J. Darensbourg, Highly selective synthesis of CO2 copolymer from styrene oxide, Macromolecules, 43 (21) (2010) 9202-9204.
170. O. V. Krylov, and A. K. Mamedov, Heterogeneous catalytic reactions of carbon dioxide, Russian Chem. Rev, 64 (9) (1995) 877.
171. nd edn., Wiley-VCH, Germany, (2008), p. 3717-3732.
172. P. Tundo, and M. Selva, The chemistry of dimethyl carbonate, Acc. Chem. Res., 35 (2002) 706-716.
173. D. Chaturvedi, and S. Ray, Versatile use of carbon dioxide in the synthesis of carbamates, Monatsh. Chem., 137 (2006) 127-145.
174. T. Toda, Reactions of carbon dioxide with α-bromoacylophenones: formation of oxazolidone derivatives, Chem. Lett., (1977) 957-958.
175. F. Kojima, T. Aida, and S. Inoue, Fixation and activation of carbon dioxide on aluminum porphyrin: catalytic formation of a carbamic ester from carbon dioxide, amine, and epoxide, J. Am. Chem. Soc., 1986, 108 (3), 391-395.
176. M. Aresta, and E. Quaranta, Role of the macrocyclic polyether in the synthesis of alkylcarbamate esters from primary amines, carbon dioxide and alkyl halides in the presence of crown ethers, Tetrahedron, 48 (1992) 1515-1530.
177. W. D. McGhee, Y. Pan, and D. P. Riley, Highly selective generation of urethanes from amines, carbon dioxide and alkyl chlorides, J. Chem. Soc., Chem. Commun., (1994) 699-700.
178. W. D. McGhee, D. P. Riley, M. E. Christ, and K. M. Christ, Palladium-catalyzed generation of O-allylic urethanes and carbonates from amines/alcohols, carbon dioxide, and allylic chlorides, Organometallics, 12 (1993) 1429-1433.
179. K. -I. Tominaga, and Y. Sasaki, Synthesis of 2-oxazolidinones from CO2 and 1,2-aminoalcohols catalyzed by n-Bu2SnO, Synlett, (2002) 307-309.
180. 2-imine system: new pathway to vicinal diamines, Organometallics, 29 (9) (2010) 1997-2000.
181. H. Ochiai, M. Jang, K. Hirano, H. Yorimitsu, and K. Oshima, Nickel-catalyzed carboxylation of organozinc reagents with CO2, Org. Lett., 10 (13) (2008) 2681-2683.
182. M. Aresta, C. F. Nobile, V. G. Albano, E. Forni, and M. Manassero, New nickel-carbon dioxide complex: synthesis, properties, and crystallographic characterizaiotn of (carbon dioxide)bis(tricyclohexylphosphine) nickel, J. Chem. Soc., Chem. Commun., (1975) 636-637.
183. [] K. Biswas, O. Prieto, P. J. Goldsmith, and S. Woodward, Remarkably stable (Me3Al)2·DABCO and stereo selective nickel catalyzed AlR3 (R = Me, Et) additions to aldehydes, Angew. Chem., Int. Ed., 44 (2005) 2232-2234.
184. [] A. Krasovskiy, and P. Knochel, A LiCl-mediated Br/Mg exchange reaction for the preparation of functionalized aryl- and heteroaryl magnesium compounds from organic bromides, Angew. Chem., Int. Ed., 43 (2004) 3333-3336.
185. C. S. Yeung, and V. M. Dong, Beyond Aresta's complex: Ni- and Pd-catalyzed organozinc coupling with CO2, J. Am. Chem. Soc., 130 (25) (2008) 7826-7827.
186. G. W. Ebert, W. L. Juda, R. H. Kosakowski, B. Ma, L. Dong, K. E. Cummings, M. V. B. Phelps, A. E. Mostafa, and J. Luo, Carboxylation and esterification of functionalized arylcopper reagents, J. Org. Chem., 70 (2005) 4314-4317.
187. K. Ukai, M. Aoki, J. Takaya, and N. Iwasawa, Rhodium(I)-catalyzed carboxylation of aryland alkenylboronic esters with CO2, J. Am. Chem. Soc., 128 (2006) 8706-8707.
188. X. Yin, and J. R. Moss, Recent developments in the activation of carbon dioxide by metal complexes, Coord. Chem. Rev., 181 (1999) 27-59.
189. G. A. Olah, B. Toeroek, J. P. Joschek, I. Bucsi, P. M. Esteves, G. Rasul, and G. K. S. Prakash, Efficient chemoselective carboxylation of aromatics to arylcarboxylic acids with a superelectrophilically activated carbon dioxide-Al2Cl6/Al system, J. Am. Chem. Soc., 124 (2002) 11379-11391.
190. S. Derien, J. C. Clinet, E. Dunach, and J. Perichon, Activation of carbon dioxide: nickelcatalyzed electrochemical carboxylation of diynes, J. Org. Chem., 58 (1993) 2578-2588.
191. P. W. Jolly, K. Jonas, C. Krueger, and Y. H. Tsay, Preparation, reactions, and structure of bis[bis(tricyclohexylphosphine)nickel] dinitrogen, {[(C6H11)3P]2Ni}2N2, J. Organometal. Chem., 33 (1971) 109-122.
192. T. Yu, T. Yamada, G. C. Gaviola, and R. G. Weiss, Carbon dioxide and molecular nitrogen as switches between ionic and uncharged room-temperature liquids comprised of amidines and chiral amino alcohols, Chem. Mater., 20 (16) (2008) 5337-5344.
193. O. R. Allen, S. J. Dalgarno, and L. D. Field, Reductive disproportionation of carbon dioxide at an Iron(II) center, Organometallics, 27 (14) (2008) 3328-3330.
194. M. M. T. Khan, S. B. Halligudi, and S. Shukla, Reduction of carbon dioxide by molecular hydrogen to formic acid and formaldehyde and their decomposition to carbon monoxide and water, J. Mol. Catal., 57 (1989) 47-60.
195. K. Leung, I. M. B. Nielsen, N. Sai, C. Medforth, and J. A. Shelnutt, Cobalt-porphyrin catalyzed electrochemical reduction of carbon dioxide in water, 2. Mechanism from first principles, J. Phys. Chem. A, 114 (37) (2010) 10174-10184.
196. I. M. B. Nielsen, and K. Leung, Cobalt-porphyrin catalyzed electrochemical reduction of carbon dioxide in water, 1. a density functional study of intermediates, J. Phys. Chem. A, 114 (37) (2010) 10166-10173.
197. J. M. Smieja, and C. P. Kubiak, Re(bipy-tBu)(CO)3Cl-improved catalytic activity for reduction of carbon dioxide: IR-spectroelectrochemical and mechanistic studies, Inorg. Chem, 49 (20) (2010) 9283-9289.
198. B. Sarkar, B. J. Liaw, C. S. Fang, and C. W. Liu, Phosphonate- and ester-substituted 2-cyanoethylene-1,1-dithiolateclusters of zinc: aerial CO2 fixation and unusual binding patterns, Inorg. Chem., 47 (7) (2008) 2777-2785.
199. C. S. Chen, J. H. Wu, and T. W. Lai, Carbon dioxide hydrogenation on Cu nanoparticles, The Journal of Physical Chemistry C, 114 (35) (2010) 15021-15028.
200. S. F. Li, and Z. X. Guo, CO2 activation and total reduction on titanium (0001) surface, J. Phys. Chem. C, 114 (26) (2010) 11456-11459.
201. S. Paulussen, B. Verheyde, X. Tu, C. D. Bie, T. Martens, D. Petrovic, A. Bogaerts, and B. Sels, Conversion of carbon dioxide to value-added chemicals in atmospheric pressure dielectric barrier discharges, Plasma Sources Sci. Tech., 19 (3) (2010) 034015.
202. M. Noji, K. Suzuki, T. Tashiro, M. Suzuki, K. Harada, K. Masuda, and Y. Kidani, Syntheses and antitumor activities of 1R,2R-cyclohexanediamine platinum(II) complexes containing dicarboxylates, Chem. Pharm. Bull., 35 (1987) 221-228.
203. W. C. Neikam, Electrolytic preparation of organic carbonates, Sun Oil Co., (1967) p. 3.
204. S. Gambino, A. Gennaro, G. Filardo, G. Silvestri, and E. Vianello, Electrochemical carboxylation of styrene, J. Electrochem. Soc., 134 (1987) 2172-2175.
205. S. Derien, J. C. Clinet, E. Dunach, and J. Perichon, Electrochemical incorporation of carbon dioxide into alkenes by nickel complexes, Tetrahedron, 48 (1992) 5235-5248.
206. D. Ballivet-Tkatchenko, J. -C. Folest, and J. Tanji, Electrocatalytic reduction of CO2 for the selective carboxylation of olefins, Appl. Organomet. Chem., 14 (2000) 847-849.
207. H. Senboku, H. Komatsu, Y. Fujimura, and M. Tokuda, Efficient electrochemical dicarboxylation of phenyl -substituted alkenes: Synthesis of 1-phenylalkane-1,2-dicarboxylic acids, Syn. Let., 3 (2001) 418-420.
208. G. -Q. Yuan, H. -F. Jiang, C. Lin, and S. -J. Liao, Efficient electrochemical synthesis of 2-arylsuccinic acids from CO2 and aryl-substituted alkenes with nickel as the cathode, Electrochimica Acta, 53 (5) (2008) 2170-2176.
209. J. -L. Tao, K. -W. Jun, and K. -W. Lee, Co-production of dimethyl ether and methanol from CO2 hydrogenation: development of a stable hybrid catalyst, Appl. Organomet. Chem., 15 (2001) 105-108.
210. S. Wang, D. Mao, X. Guo, G. Wu, and G. Lu, Dimethyl ether synthesis via CO2 hydrogenation over CuO-TiO2-ZrO2/HZSM-5 bifunctional catalysts, Catal. Commun., 10 (2009) 1367-1370.
211. X. An, Y. -Z. Zuo, Q. Zhang, D. -Z. Wang, and J. -F. Wang, Dimethyl Ether Synthesis from CO2 Hydrogenation on a CuO-ZnO-Al2O3-ZrO2/HZSM-5 bifunctional Catalyst, Ind. Eng. Chem. Res., 47 (2008) 6547-6554.
212. J. Erena, R. Garona, J. M. Arandes, A. T. Aguayo, and J. Bilbao, Effect of operating conditions on the synthesis of dimethyl ether over a CuO-ZnO-Al2O3/NaHZSM-5 bifunctional catalyst, Catal. Today, 107-108 (2005) 467-473.
213. G. -X. Qi, J. -H. Fei, X. -M. Zheng, and Z. -Y. Hou, DME synthesis from carbon dioxide and hydrogen over Cu-Mo/HZSM-5, Catal. Lett., 72 (2001) 121-124.
214. K. Sun, W. Lu, M. Wang, and X. Xu, Low-temperature synthesis of DME from CO2/H2 over Pd-modified CuO-ZnO-Al2O3-ZrO2/HZSM-5 catalysts, Catal. Commun., 5 (2004) 367-370.
215. T. Inui, M. Anpo, K. Lzui, S. Yanagida, and T. Yamaguchi, Advances in chemical conversion for mitigating carbon dioxide, Stud. Sur. Sci. Catal., 114 (1998) 19-30.
216. G. Menard, and D. W. Stephan, Room temperature reduction of CO2 to methanol by Albased frustrated Lewis pairs and ammonia borane, J. Am. Chem. Soc., 132 (6) (2010) 1796-1797.
217. A. E. Ashley, A.L. Thompson, and D. O'Hare, Non-metal-mediated homogeneous hydrogenation of CO2 to CH3OH, Angew. Chem., Int. Ed., 48 (2009) 9839-9843.
218. R. Obert, and B. C. Dave, Enzymatic conversion of carbon dioxide to methanol: Enhanced methanol production in silica sol-gel matrices, J. Am. Chem. Soc., 121 (51) (1999) 12192-12193.
219. S. J. Geier, and D. W. Stephan, Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity, J. Am. Chem. Soc., 131 (2009) 3476-3477.
220. T. Matsuo, and H. Kawaguchi, From carbon dioxide to methane: homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes, J. Am. Chem. Soc., 128 (2006) 12362-12363.
221. D. Enders, O. Niemeier, and A. Henseler, Organocatalysis by N-heterocyclic carbenes, Chem. Rev., 107 (2007) 5606-5655.
222. N. Marion, S. Diez-Gonzalez, and S. P. Nolan, N-heterocyclic carbenes as organocatalysts, Angew. Chem., Int. Ed., 46 (2007) 2988-3000.
223. G. A. Olah, Beyond oil and gas: The methanol economy, Angew. Chem., Int. Ed., 44 (2005) 2636-2639.
224. K. Zeitler, Extending mechanistic routes in heterazolium catalysis - promising concepts for versatile synthetic methods, Angew. Chem., Int. Ed., 44 (2005) 7506-7510.
225. J. Seayad, P. K. Patra, Y. Zhang, and J. Y. Ying, Organocatalytic synthesis of Nphenylisoxazolidin-5-ones and a one-pot synthesis of β-amino acid esters, Org. Lett., 10 (2008) 953-956.
226. F. T. Wong, P. K. Patra, J. Seayad, Y. Zhang, and J. Ying, N-heterocyclic carbene (NHC)- catalyzed direct amidation of aldehydes with nitroso compounds, Org. Lett., 10 (2008) 2333-2336.
227. Y. Zhang, S. N. Riduan, and J. Y. Ying, Microporous polyisocyanurate and its application in heterogeneous catalysis, Chem. -Eur. J., 15 (2009) 1077-1081.
228. G. Yong, Y. Zhang, and J. Ying, Efficient catalytic system for the selective production of 5-hydroxymethylfurfural from glucose and fructose, Angew. Chem., Int. Ed., 47 (2008) 9345-9348.
229. H. A. Duong, T. N. Tekavec, A. M. Arif, and J. Louie, Reversible carboxylation of Nheterocyclic carbenes, Chem. Commun., (2004) 112-113.
230. A. M. Voutchkova, M. Feliz, E. Clot, O. Eisenstein, and R. H. Crabtree, Imidazolium carboxylates as versatile and selective N-heterocyclic carbene transfer agents: synthesis, mechanism, and applications, J. Am. Chem. Soc., 129 (2007) 12834-12846.
231. I. Tommasi, and F. Sorrentino, Utilization of 1,3-dialkylimidazolium-2-carboxylates as CO2-carriers in the presence of Na+ and K+: application in the synthesis of carboxylates, monomethyl carbonate anions and halogen-free ionic liquids, Tetrahedron Lett., 46 (2005) 2141-2145.
232. J. -H. Jeoung, and H. Dobbek, Carbon dioxide activation at the Ni, Fe-cluster of anaerobic carbon monoxide dehydrogenase, Science, 318 (2007) 1461-1464.
233. A. Parkin, J. Seravalli, K. A. Vincent, S. W. Ragsdale, and F. A. Armstrong, Rapid and efficient electrocatalytic CO2/CO interconversions by carboxydothermus hydrogenoformans CO dehydrogenase I on an electrode, J. Am. Chem. Soc., 129 (2007) 10328-10329.
234. P. M. Zimmerman, A. Paul, Z. Zhang, and C. B. Musgrave, The role of free N-heterocyclic carbene (NHC) in the catalytic dehydrogenation of ammonia borane in the nickel NHC system, Angew. Chem., Int. Ed., 48 (2009) 2201-2205.
235. P. M. Zimmerman, A. Paul, and C. B. Musgrave, Catalytic dehydrogenation of ammonia borane at Ni monocarbene and dicarbene catalysts, Inorg. Chem., 48 (2009) 5418-5433.
236. L. M. Ellerby, C. R. Nishida, F. Nishida, S. A. Yamanaka, B. Dunn, J. S. Valentine, and J. I. Zink, Encapsulation of proteins in transparent porous silicate glasses prepared by the sol-gel method, Science, 255 (1992) 1113-1115.
237. S. -W. Xu, Y. Lu, J. Li, Z. -Y. Jiang, and H. Wu, Efficient conversion of CO2 to methanol catalyzed by three dehydrogenases co-encapsulated in an alginate-silica (ALG-SiO2) hybrid gel, Ind. Eng. Chem. Res., 45 (2006) 4567-4573.
238. P. Liu, Y. Choi, Y. Yang, and M. G. White, Methanol synthesis from H2 and CO2 on a Mo6S8 cluster: a density functional study, J. Phys. Chem. A, 114 (11) (2009) 3888-3895.
239. F. W. Chang, M. T. Tsay, and S. P. Liang, Hydrogenation of CO2 over nickel catalysts supported on rice husk ash prepared by ion exchange, Appl. Catal., A, 209 (2001) 217-227.
240. F. -W. Chang, T. -J. Hsiao, and J. -D. Shih, Hydrogenation of CO2 over a rice husk ash supported nickel catalyst prepared by deposition-precipitation, Ind. Eng. Chem. Res., 37 (1998) 3838-3845.
241. G. D. Weatherbee, and C. H. Bartholomew, Hydrogenation of carbon dioxide on Group VIII metals, I. Specific activity of nickel/silica, J. Catal., 68 (1981) 67-76.
242. T. Kodama, and N. Gokon, Thermochemical cycles for high-temperature solar hydrogen production, ChemInform, 38 (51) (2007) 4048-4077.
243. C. Agrafiotis, M. Roeb, A. G. Konstandopoulos, L. Nalbandian, V. T. Zaspalis, C. Sattler, P. Stobbe, and A. M. Steele, Solar water splitting for hydrogen production with monolithic reactors, Solar Energy, 79 (4) (2005) 409-421.
244. M. Roeb, J. P. Säck, P. Rietbrock, C. Prahl, H. Schreiber, M. Neises, L. de Oliveira, D. Graf, M. Ebert, W. Reinalter, M. Meyer-Grünefeldt, C. Sattler, A. Lopez, A. Vidal, A. Elsberg, P. Stobbe, D. Jones, A. Steele, S. Lorentzou, C. Pagkoura, A. Zygogianni, C. Agrafiotis, and A. G. Konstandopoulos, Test operation of a 100 kW pilot plant for solar hydrogen production from water on a solar tower, Solar Energy, 85 (4) (2011) 634-644.
245. E. Thimsen, F. L. Formal, M. Gratzel, and S. C. Warren, Influence of plasmonic Au nanoparticles on the photoactivity of Fe2O3 electrodes for water splitting, Nano Lett, 11 (2011) 35.
246. G. Maag, and A. Steinfeld, Design of a 10 MW particle-flow reactor for syngas production by steam-gasification of carbonaceous feedstock using concentrated solar energy, Energy Fuels, 24 (2010) 6540-6547.
247. W. C. Chueh, C. Falter, M. Abbott, D. Scipio, P. Furler, S. M. Haile, and A. Steinfeld, Highflux solar-driven thermochemical dissociation of CO2 and H2O using nonstoichiometric ceria, Science, 330 (2010) 1797-1801.
248. G. A. Le, S. Abanades, and G. Flamant, CO2 and H2O splitting for thermochemical production of solar fuels using nonstoichiometric ceria and ceria/zirconia solid solutions, Energy Fuels, 25 (2011) 4836-4845.
249. J. J. Spivey, E. M. Wilcox, and G. W. Roberts, Direct utilization of carbon dioxide in chemical synthesis: vinyl acetate via methane carboxylation, Catal. Commun., 9 (2008) 685-689.
250. E. M. Wilcox, G. W. Roberts, and J. J. Spivey, Direct catalytic formation of acetic acid from CO2 and methane, Catal. Today, 88 (2003) 83-90.
251. E. M. Wilcox, M. R. Gogate, J. J. Spivey, and G. W. Roberts, Direct synthesis of acetic acid from methane and carbon dioxide, Stud. Surf. Sci. Catal., 136 (2001) 259-264.
252. K. E. Vidalin, and D. M. Thiebaut, Methanol plant retrofit for the manufacture of acetic acid, 2004, Acetex Cyprus Limited, Cyprus, p. 16 pp., Cont.-in-part of U.S. 6,232,352.
253. K. E. Vidalin, Methanol plant retrofit for acetic acid manufacture, 2001, Acetex Limited, Cyprus, p. 17 pp., Cont.-in-part of U.S. Ser. No. 430,888.
254. D. M. Thiebaut, and K. E. Vidalin, Methanol plant retrofit for the manufacture of acetic acid, 2001, Acetex Cyprus Limited, Cyprus, p. 44 pp.
255. N. Ikehara, K. Hara, A. Satsuma, T. Hattori, and Y. Murakami, Unique temperature dependence of acetic acid formation in CO2 hydrogenation on Ag-promoted Rh/SiO2 catalyst, Chem. Lett., (1994) 263-264.
256. III(EDTA-H)Cl]·2H2O, J. Mol. Catal., 53 (1989) 305-313.
257. M. M. T. Khan, S. B. Halligudi, N. N. Rao, and S. Shukla, Formic acid and formaldehyde as spin off products in ruthenium-EDTA-CO complex catalyzed liquid-phase water-gas shift reaction, J. Mol. Catal., 51 (1989) 161-170.
258. J. Wambach, and H. J. Freund, Carbon dioxide activation on transition metal surfaces, Spec. Publ. - R. Soc. Chem., 153 (1994) 31-43.
259. K. Kudo, H. Phala, N. Sugita, and Y. Takezaki, Synthesis of dimethyl formamide from carbon dioxide, hydrogen and dimethyl amine catalyzed by palladium(II) chloride, Chem. Lett., (1977) 1495-1496.
260. I. Omae, Aspects of carbon dioxide utilization, Catalysis Today, 115 (1-4) (2006) 33-52.
261. P. G. Jessop, Y. Hsiao, T. Ikariya, and R. Noyori, Catalytic production of dimethylformamide from supercritical carbon dioxide, J. Am. Chem. Soc., 116 (1994) 8851-8852.
262. L. Schmid, M. Rohr, and A. Baiker, A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine, Chem. Commun., (1999) 2303-2304.
263. O. Krocher, R. A. Koppel, and A. Baiker, Novel homogeneous and heterogeneous catalysts for the synthesis of formic acid derivatives from CO2, Chimia, 51 (1997) 48-51.
264. Y. Kayaki, T. Suzuki, and T. Ikariya, Water-soluble trialkylphosphine-ruthenium (II) complexes as efficient catalysts for hydrogenation of supercritical carbon dioxide, Chem. Lett., (2001) 1016-1017.
265. P. G. Jessop, Y. Hsiao, T. Ikariya, and R. Noyori, Homogeneous catalysis in supercritical fluids: hydrogenation of supercritical carbon dioxide to formic acid, alkyl formates, and formamides, J. Am. Chem. Soc., 118 (1996) 344-355.
266. O. Krocher, R. A. Koppel, and A. Baiker, Sol-gel derived hybrid materials as heterogeneous catalysts for the synthesis of N,N-dimethylformamide from supercritical carbon dioxide. Chem. Commun., 13 (1996) 1497-1498.
267. F. Liu, M. B. Abrams, R. T. Baker, and W. Tumas, Phase-separable catalysis using room temperature ionic liquids and supercritical carbon dioxide, Chem. Commun., (2001) 433-434.
268. B. Jezowska-Trzebiatowska, and P. Sobota, Catalytic fixation of carbon dioxide under mild conditions in the system: Titanium tetrachloride + magnesium + molecular hydrogen in tetrahydrofuran, J. Organomet. Chem., 80 (1974) C27-C28.
269. C. P. Lau, and Y. Z. Chen, Hydrogenation of carbon dioxide to formic acid using a 6,6'- dichloro-2,2'-bipyridine complex of ruthenmiu, cis-[Ru(6,6'-Cl2bpy)2(H2O)2](CF3SO3)2, J. Mol. Catal. A: Chem., 101 (1995) 33-36.
270. W. Leitner, E. Dinjus, and F. Gassner, Activation of carbon dioxide: IV - rhodium catalyzed hydrogenation of carbon dioxide to formic acid, J. Organomet. Chem., 475 (1994) 257-266.
271. R. Fornika, H. Goerls, B. Seemann, and W. Leitner, Complexes [(P2)Rh(hfacac)] (P2 = bidentate chelating phosphane, hfacac = hexafluoroacetylacetonate) as catalysts for CO2 hydrogenation: correlations between solid state structures, 103Rh NMR shifts and catalytic activities, J. Chem. Soc., Chem. Commun., (1995) 1479-1481.
272. K. Kudo, N. Sugita, and Y. Takezaki, Kinetic study on the synthesis of alkali formates from carbon dioxide and hydrogen catalyzed by palladium(II) chloride in an aqueous alkali solution, Nippon Kagaku Kaishi, (1977) 302-309.
273. F. Gassner, and W. Leitner, Carbon dioxide activation, 3. Hydrogenation of carbon dioxide to formic acid using water-soluble rhodium catalysts, J. Chem. Soc., Chem. Commun., (1993) 1465-1466.
274. P. G. Jessop, T. Ikarlya, and R. Noyori, Homogeneous catalytic hydrogenation of supercritical carbon dioxide, Nature (London), 368 (1994) 231-233.
275. P. Munshi, A. D. Main, J. C. Linehan, C. -C. Tai, and P. G. Jessop, Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of certain alcohols and amines, J. Am. Chem. Soc., 124 (2002) 7963-7971.
276. Z. Zhang, S. Hu, J. Song, W. Li, G. Yang, and B. Han, Hydrogenation of CO2 to formic acid promoted by a diamine functionalized ionic liquid, ChemSusChem, 2 (2009) 234-238.
277. N. N. Ezhova, N. V. Kolesnichenko, A. V. Bulygin, E. V. Slivinskii, and S. Han, Hydrogenation of CO2 to formic acid in the presence of the Wilkinson complex, Russ. Chem. Bull., 51 (2002) 2165-2169.
278. Y. Gao, J. K. Kuncheria, H. A. Jenkins, R. J. Puddephatt, and G. P. A. Yap, The interconversion of formic acid and hydrogen/carbon dioxide using a binuclear ruthenium complex catalyst, Dalton, (2000) 3212-3217.
279. M. L. Man, Z. Zhou, S. M. Ng, and C. P. Lau, Synthesis, characterization and reactivity of heterobimetallic complexes (η5-C5R5)Ru(CO)(μ-dppm)M(CO)2(η5-C5H5) (R = H, CH3; M = Mo, W): interconversion of hydrogen/carbon dioxide and formic acid by these complexes, Dalton Trans., (2003) 3727-3735.
280. C. Yin, Z. Xu, S. -Y. Yang, S. M. Ng, K. Y. Wong, Z. Lin, and C. P. Lau, Promoting effect of water in ruthenium-catalyzed hydrogenation of carbon dioxide to formic acid, Organometallics, 20 (2001) 1216-1222.
281. S. M. Ng, C. Yin, C. H. Yeung, T. C. Chan, and C. P. Lau, Ruthenium-catalyzed hydrogenation of carbon dioxide to formic acid in alcohols, Eur. J. Inorg. Chem., (2004) 1788-1793.
282. T. -T. Thai, B. Therrien, and G. Suss-Fink, Arene ruthenium oxinato complexes: Synthesis, molecular structure and catalytic activity for the hydrogenation of carbon dioxide in aqueous solution, J. Organomet. Chem., 694 (2009) 3973-3981.
283. S. Sanz, A. Azua, and E. Peris, '(η6-arene)Ru(bis-NHC)' complexes for the reduction of CO2 to formate with hydrogen and by transfer hydrogenation with iPrOH, Dalton Trans., 39 (2010) 6339-6343.
284. Y. Himeda, Conversion of CO2 into formate by homogeneously catalyzed hydrogenation in water: tuning catalytic activity and water solubility through the acid-base equilibrium of the ligand, Eur. J. Inorg. Chem., (2007) 3927-3941.
285. R. Tanaka, M. Yamashita, and K. Nozaki, Catalytic hydrogenation of carbon dioxide using Ir(III)-Pincer complexes, J. Am. Chem. Soc., 131 (2009) 14168-14169.
286. iPrOH, Organometallics, 29 (2010) 275-277.
287. T. -T. Thai, B. Therrien, and G. Suss-Fink, High-pressure combinatorial screening of homogeneous catalysts: hydrogenation of carbon dioxide, Inorg. Chem., 42 (2003) 7340-7341.
288. Y. Zhang, J. Fei, Y. Yu, and X. Zheng, Silica immobilized ruthenium catalyst used for carbon dioxide hydrogenation to formic acid (I): the effect of functionalizing group and additive on the catalyst performance, Catal. Commun., 5 (2004) 643-646.
289. Y. Inoue, Y. Sasaki, and H. Hasimoto, Synthesis of formates from alcohols, carbon dioxide, and hydrogen catalyzed by a combination of Group VIII transition metal complexes and tertiary amines, J. Chem. Soc., Chem. Commun., (1975) 718-719.
290. G. O. Evans, and C. J. Newell, Conversion of carbon dioxide, hydrogen and alcohols into formate esters using anionic iron carbonyl hydrides, Inorg. Chim. Acta, 31 (1978) L387-L389.
291. P. G. Jessop, Y. Hsiao, T. Ikariya, and R. Noyori, Methyl formate synthesis by hydrogenation of supercritical carbon dioxide in the presence of methanol, J. Chem. Soc., Chem. Commun., (1995) 707-708.
292. Y. Himeda, Conversion of CO2 into formate by homogeneously catalyzed hydrogenation in water: tuning catalytic activity and water solubility through the acid-base equilibrium of the ligand, Eur. J. Inorganic Chem., 2007 (25) (2007) 3927-3941.
293. Y. Inoue, H. Izumida, Y. Sasaki, and H. Hashimoto, Catalytic fixation of carbon dioxide to formic acid by transitionmetal complexes under mild conditions, Chem. Lett., (1976) 863-864.
294. W. Leiner, E. Dinjus, and F. Gassner, Aqueous-phase organometallic catalysis, concepts and applications (Eds.: B. Cornils, W. A. Herrmann), Wiley-VCH, Weinheim, (1998), 486-498.
295. G. Kovacs, G. Schubert, F. Joo, and I. Papai, Theoretical investigation of catalytic HCO3- hydrogenation in aqueous solutions, Catal. Today, 115 (2006) 53-60.
296. H. Horvath, G. Laurenczy, and A. Katho, Water-soluble (η6-arene)ruthenium(II)-phosphine complexes and their catalytic activity in the hydrogenation of bicarbonate in aqueous solution, J. Organomet. Chem., 689 (2004) 1036-1045.
297. J. Elek, L. Nadasdi, G. Papp, G. Laurenczy, and F. Joo, Homogeneous hydrogenation of carbon dioxide and bicarbonate in aqueous solution catalyzed by water-soluble ruthenium(II) phosphine complexes, Appl. Catal., A, 255 (2003) 59-67.
298. F. Joo, G. Laurenczy, P. Karady, J. Elek, L. Nadasdi, and R. Roulet, Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under mild conditions with water soluble rhodium(I)- and ruthenium(II)-phosphine catalysts, Appl. Organomet. Chem., 14 (2000) 857-859.
299. G. Laurenczy, F. Joo, and L. Nadasdi, Formation and characterization of water-soluble hydrido-ruthenium(II) complexes of 1,3,5-triaza-7-phosphaadamantane and their catalytic activity in hydrogenation of CO2 and HCO3- in aqueous solution, Inorg. Chem., 39 (2000) 5083-5088.
300. P. G. Jessop, Handbook of Homogeneous Hydrogenation (Eds.: J. G. De Vries, C. J. Elsevier), Wiley-VCH, Weinheim, 2007, 1, p. 489-511.
301. W. Leitner, Carbon dioxide as a raw material: the synthesis of formic acid and its derivatives from CO2, Angew. Chem., Int. Ed. Engl., 34 (1995) 2207-2221.
302. P. G. Jessop, T. Ikariya, and R. Noyori, Homogeneous hydrogenation of carbon dioxide, Chem. Rev., 95 (1995) 259-272.
303. I. Joszai, and F. Joo, Hydrogenation of aqueous mixtures of calcium carbonate and carbon dioxide using a water-soluble rhodium(I)-tertiary phosphine complex catalyst, J. Mol. Catal. A: Chem., 224 (2004) 87-91.
304. O. Krocher, R. A. Koppel, M. Froba, and A. Baiker, Silica hybrid gel catalysts containing Group (VIII) transition metal complexes: preparation, structural, and catalytic properties in the synthesis of N,Ndimethylformamide and methyl formate from supercritical carbon dioxide, J. Catal., 178 (1998) 284-298.
305. Y. Kayaki, Y. Shimokawatoko, and T. Ikariya, Amphiphilic resin-supported ruthenium(II) complexes as recyclable catalysts for the hydrogenation of supercritical carbon dioxide, Adv. Synth. Catal., 345 (2003) 175-179.
306. S. -E. Park, J. -S. Chang and K.-W. Lee, Carbon dioxide utilization for global sustainability, Studies in Surface Science and Catalysis, Elsevier, Amsterdam, 2004, 153.
307. M. M. Bhasin, J. H. McCain, B. V. Vora, T. Imai, and P. R. Pujado, Dehydrogenation and oxydehydrogenation of paraffins to olefins, Appl. Catal., A, 221 (2001) 397-419.
308. F. Cavani, and F. Trifiro, Alternative processes for the production of styrene, Appl. Catal., A, 133 (1995) 219-39.
309. G. Raju, B. M. Reddy, B. Abhishek, Y. -H. Mo, and S. -E. Park, Synthesis of C4 olefins from n-butane over a novel VOx/SnO2-ZrO2 catalyst using CO2 as soft oxidant, Appl. Catal., A, 423-424 (2012) 168-175.
310. K. N. Rao, B. M. Reddy, and S. -E. Park, Novel CeO2 promoted TiO2-ZrO2 nanooxide catalysts for oxidative dehydrogenation of p-diethylbenzene utilizing CO2 as soft oxidant, Appl. Catal., B, 100 (2010) 472-480.
311. K. N. Rao, B. M. Reddy, B. Abhishek, Y. -H. Seo, N. Jiang, and S. -E. Park, Effect of ceria on the structure and catalytic activity of V2O5/TiO2-ZrO2 for oxidehydrogenation of ethylbenzene to styrene utilizing CO2 as soft oxidant, Appl. Catal., B, 91 (2009) 649-656.
312. B. M. Reddy, S. -C. Lee, D. -S. Han, and S. -E. Park, Utilization of carbon dioxide as soft oxidant for oxydehydrogenation of ethylbenzene to styrene over V2O5-CeO2/TiO2-ZrO2 catalyst, Appl. Catal., B, 87 (2009) 230-238.
313. B. M. Reddy, N. Jiang, and S. -E. Park, Oxidehydrogenation of ethylbenzene to styrene over zirconia-based catalysts with carbon dioxide as soft oxidant, Prepr. - Am. Chem. Soc., Div. Pet. Chem., 53 (2008) 30-33.
314. B. M. Reddy, N. Jiang, and S. -E. Park, Oxidehydrogenation of ethylbenzene to styrene over zirconia-based catalysts with carbon dioxide as soft oxidant, Am. Chem. Soc., Div. Petro. Chem. Preprints, 53 (2) (2008) 30-33.
315. B. M. Reddy, D. -S. Han, N. Jiang, and S. -E. Park, Dehydrogenation of ethylbenzene to styrene with carbon dioxide over ZrO2-based composite oxide catalysts, Catal. Surv. Asia, 12 (2008) 56-69.
316. T. Seki, and A. Baiker, Catalytic oxidations in dense carbon dioxide, Chem. Rev., 109 (6) (2009) 2409-2454.
317. D. Abbott, Keeping the energy debate clean: how do we supply the world's energy needs? Proceedings of the IEEE, 98 (1) (2010) 42-66.
318. R. Priddle, World Energy Outlook 2002, International Energy Agency and Energy Technology Analysis, 2002, IEA/OECD, Second Edition(Paris, France): p. http://www.iea.org/textbase/nppdf/free/2000/weo2002.pdf.
319. World electric power-plants database. Utility Data Institute, 2003. McGraw-Hill, Washington DC.
320. World oil and gas review 2004. ENI, 2004. Rome, Italy(http://www.agip.it/).
321. WEC, W.E.C., 19th survey of world energy resources. World Energy Council, 2001, London, (hUtKtp://www.worldenergy.org/wecgeis/publications/default/launches/ser/ser.asp).
322. G. Moritis, EOR continues to unlock oil resources. Oil & Gas Journal, 12 (April) (2004) 53.
323. I. E. Agency, Key World Energy Statistics, 2009, IEA, 2009. Paris (France) (2010).
324. M. Pehnt, Fuel cells in the power market: separating the hope from the hype, presented at CAN Europe meeting, 27 May, Brussels, Belgium, 2004, http://www.climnet.org/CTAP/workshop2004/PresentationsWS2.htm/.
325. N. S. Lewis, G. Crabtree, A. Nozik, M. Wasielewski, and P. Alivisatos, Basic research needs for solar energy utilization, US Department of Energy, 2005, Washington DC.
326. J. Garcia-Martinez, Nanotechnology for the Energy Challenge. Wiley-VCH, 2010, Weinheim, Germany.
327. T.B.C. Group, Batteries for Electric Cars: Challenges, Opportunities, and the Outlook to 2020. BCG, 2010. Boston, MA, USA(September): p. http://www.bcg.com/documents/file36615.pdf.
328. E. Mobil, Exxon Mobil Algae Biofuels Research and Development Program, http://www.exxonmobil.com/corporate/files/news_pub_algae_factsheet.pdf/, 2012. 1(1).
329. M. Khoshtinat, N. A. S. Amin, and I. Noshadi, A review of methanol production from methane oxidation via non-thermal plasma reactor, World Academy of Science, Engineering and Technology, 2010, 62: p. 354.
330. A. Aruchamy, G. Aravamudan, and G.V.S. Rao, Semiconductor based photoelectrochemical cells for solar energy conversion - an overview. Bull. Mater. Sci., 4 (5) (1982) 483.
331. L. R. Sheppard, and J. Nowotny, Materials for photoelectrochemical energy conversion, Adv. Appl. Ceram., 106 (1-2) (2007) 9.
332. N. S. Lewis, and D.G. Nocera, Powering the planet: chemical challenges in solar energy utilization, Proc. Natl. Acad. Sci. U. S. A., 103 (2006) 15729.
333. J. J. Conti, L. E. Doman, K. A. Smith, L. D. Mayne, E. M. Yucel, J. L. Barden, A. M. Fawzi, P. D. Martin, V. V. Zaretskaya, M. L. Mellish, D. R. Kearney, B. T. Murphy, K. R. Vincent, P. M. Lindstrom, M. T. Leff, A. Geagla, J. Holte, B. Kapilow-Cohen, M. LaRiviere, C. L. Smith, J. Staub, G. Sweetnam, and P. Wells, International Energy Outlook 2010, The U.S. Energy Information Administration (EIA), U.S. Department of Energy, 2010, DOE/EIA- 0484 (2010), Washington, DC(1): p. 338.
334. [] M. Stocker, Biofuels and biomass-to-liquid fuels in the biorefinery: catalytic conversion of lignocellulosic biomass using porous materials, Angew. Chem., Int. Ed., 47 (2008) 9200-9211.
335. P. Gallezot, Catalytic conversion of biomass: challenges and issues, ChemSusChem, 1 (2008) 734-737.
336. G. W. Huber, S. Iborra, and A. Corma, Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering, Chem. Rev., 106 (2006) 4044-4098.
337. G. Centi, and S. Perathoner, Towards solar fuels from water and CO2, ChemSusChem, 3 (2010) 195-208.
338. A. J. Nozik, Nanoscience and nanostructures for photovoltaics and solar fuels, Nano Lett., 10 (2010) 2735-2741.
339. S. C. Roy, O. K. Varghese, M. Paulose, and C. A. Grimes, Toward solar fuels: photocatalytic conversion of carbon dioxide to hydrocarbons, ACS Nano, 4 (2010) 1259-1278.
340. H. Tributsch, Photovoltaic hydrogen generation, Int. J. Hydrogen Energy, 33 (2008) 5911-5930.
341. T. L. Gibson, and N. A. Kelly, Optimization of solar powered hydrogen production using photovoltaic electrolysis devices, Int. J. Hydrogen Energy, 33 (2008) 5931-5940.
342. S. Manisha, and R. Banerjee, Comparison of biohydrogen production processes, Int. J. Hydrogen Energy, 33 (1) (2008) 279-286.
343. S. M. Kotaya, and D. Das, Biohydrogen as a renewable energy resource - Prospects and potentials, Int. J. Hydrogen Energy, 33 (1) (2008) 258-263.
344. T. Kodama, and N. Gokon, Thermochemical cycles for high-temperature solar hydrogen production, Chem. Rev., 107 (2007) 4048-4077.
345. A. Kudo, and Y. Miseki, Heterogeneous photocatalyst materials for water splitting, Chem. Soc. Rev., 38 (2009) 253-278.
346. Y. R. M. Navarro, G. M. C. Alvarez, V. F. del, d. l. M. J. A. Villoria, and J. L. G. Fierro, Water splitting on semiconductor catalysts under visible-light irradiation, ChemSusChem, 2 (2009) 471-485.
347. A. Currao, Photoelectrochemical water splitting, Chimia, 61 (2007) 815-819.
348. N. A. Kelly, and T. L. Gibson, Design and characterization of a robust photoelectrochemical device to generate hydrogen using solar water splitting. Int. J. Hydrogen Energy, 31 (2006) 1658-1673.
349. A. J. Morris, G.J. Meyer, and E. Fujita, Molecular approaches to the photocatalytic reduction of carbon dioxide for solar fuels, Acc. Chem. Res., 42 (2009) 1983-1994.
350. G. Krajacic, R. Martins, A. Busuttil, N. Duic, and G. C. M. da, Hydrogen as an energy vector in the islands' energy supply, Int. J. Hydrogen Energy, 33 (2008) 1091-1103.
351. P. P. Edwards, V. L. Kuznetsov, and W. I. F. David, Hydrogen energy, Philos. Trans. R. Soc., A, 365 (2007) 1043-1056.
352. A. Sartbaeva, V. L. Kuznetsov, S. A. Wells, and P. P. Edwards, Hydrogen nexus in a sustainable energy future, Energy Environ. Sci., 1 (2008) 79-85.
353. D. G. Vlachos, and S. Caratzoulas, The roles of catalysis and reaction engineering in overcoming the energy and the environment crisis, Chem. Eng. Sci., 65 (2009) 18-29.
354. R. J. Farrauto, Building the hydrogen economy, Hydrocarbon Eng., 14 (2009) 25-26.
355. N. Z. Muradov, and T. N. Veziroglu, Green path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies, Int. J. Hydrogen Energy, 33 (2008) 6804-6839.
356. H. W. Cooper, Fuel cells, the hydrogen economy and you, Chem. Eng. Prog., 103 (2007) 34-43.
357. F. Mueller-Langer, E. Tzimas, M. Kaltschmitt, and S. Peteves, Techno-economic assessment of hydrogen production processes for the hydrogen economy for the short and medium term, Int. J. Hydrogen Energy, 32 (2007) 3797-3810.
358. D. Strahan, Hydrogen's long road to nowhere, New Sci., 200 (2008) 40-43.
359. J. O. M. Bockris, Hydrogen no longer a high cost solution to global warming: new ideas, Int. J. Hydrogen Energy, 33 (2008) 2129-2131.
360. J. Nowotny, and L. R. Sheppard, Solar-hydrogen, Int. J. Hydrogen Energy, 32 (2007) 2607-2608.