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Volumn 131, Issue 10, 2009, Pages 3476-3477

Lutidine/B(C6F5)3: At the boundary of classical and frustrated lewis pair reactivity

Author keywords

[No Author keywords available]

Indexed keywords

LEWIS ACID-BASE ADDUCTS; LUTIDINE; RING OPENING;

EID: 67749116259     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja900572x     Document Type: Article
Times cited : (289)

References (29)
  • 20
    • 53549098192 scopus 로고    scopus 로고
    • Sumerin, V.; Schulz, F.; Nieger, M.; Leskela, M.; T., R.; Rieger, B. Angew. Chem., Int. Ed. 2008, 47, 6001.
    • Sumerin, V.; Schulz, F.; Nieger, M.; Leskela, M.; T., R.; Rieger, B. Angew. Chem., Int. Ed. 2008, 47, 6001.
  • 23
    • 70249122187 scopus 로고    scopus 로고
    • The mixture of BMe3/lutidine1 is the first reference to our knowledge to what we refer to as a frustrated Lewis pair.
    • The mixture of BMe3/lutidine1 is the first reference to our knowledge to what we refer to as a "frustrated Lewis pair".
  • 24
    • 70249109527 scopus 로고    scopus 로고
    • Reversible 4-MeC5H4N binding to boron has been previously observed: Clegg, W.; Dai, C.; Lawlor, F. J.; Marder, T. B.; Nguyen, P.; Norman, N. C.; Pickett, N. L.; Power, W. P.; Scott, A. J. J. Chem. Soc., Dalton Trans. 1997, 83, 9-846.
    • Reversible 4-MeC5H4N binding to boron has been previously observed: Clegg, W.; Dai, C.; Lawlor, F. J.; Marder, T. B.; Nguyen, P.; Norman, N. C.; Pickett, N. L.; Power, W. P.; Scott, A. J. J. Chem. Soc., Dalton Trans. 1997, 83, 9-846.
  • 26
    • 70249141427 scopus 로고    scopus 로고
    • X-ray data. 1: P21/n, a, 12.8108(4) ̊, b, 13.4663(4) ̊, c, 13.3937(4) ̊, β 100.156(2)°, V, 2274.40(12) ̊3, data (>3σ, 7942, var. 379, R, 0.0494, Rw, 0.1475, GOF 1.055. 2: P21/c, a, 17.8525(12) ̊, b, 9.8407(7) ̊, c, 15.2683(10) ̊, β 115.010(3)°, V, 2430.8(3) ̊3,data (>3σ, 8206, var. 383, R, 0.0516, Rw, 0.1680, GOF 1.005. 3:Pna21, a, 17.4334(9) ̊, b, 10.6793(6) ̊, c, 14.4679(8) ̊, V, 2693.6(3)°, data >3σ, 13 352, var. 424, R, 0.0389, R w, 0.1146, GOF1.046
    • w = 0.1146, GOF1.046.
  • 28
    • 70249092336 scopus 로고    scopus 로고
    • Addition of pyridine to (2) with heating to 100°C for 8 h prompts complete loss of H2 and formation of (py)B(C6F5)3.
    • Addition of pyridine to (2) with heating to 100°C for 8 h prompts complete loss of H2 and formation of (py)B(C6F5)3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.