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Volumn 44, Issue 46, 2005, Pages 7506-7510

Extending mechanistic routes in heterazolium catalysis-promising concepts for versatile synthetic methods

Author keywords

Aldehydes; Carbenes; Nitrogen heterocycles; Stereoselective catalysis; Umpolung

Indexed keywords

ALDEHYDES; CARBOXYLATION; SPECTRUM ANALYSIS;

EID: 28244479394     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502617     Document Type: Review
Times cited : (401)

References (43)
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    • a) Movassaghi et al. only recently reported on the development of a carbene-catalyzed amidation reaction of unactivated esters with amino alcohols. In contrast, based on preliminary mechanistic studies an alternative, uncharged mechanistic mode of catalysis via a carbene-alcohol intermediate followed by rapid O→N acyl transfer is suggested: M. Movassaghi, M. A. Schmidt, Org. Lett. 2005, 7, 2453-2456;
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    • b) A NHC-mediated transesterification is supposed to be part of the formation of γ-butyrolactones from benzoins with methyl acrylate in a tandem reaction: W. Ye, G. Cai, Z. Zhuang, X. Jia, H. Zhai, Org. Lett. 2005, 7, 3769-3771.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.