Syntheses of polycarbonate and polyurethane precursors utilizing CO2 over highly efficient, solid as-synthesized MCM-41 catalyst

Tetrahedron Letters

Volumn 47, Issue 25, 2006, Pages 4213-4217

  Srivastava, R ^a   Srinivas, D ^a   Ratnasamy, P ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Carbamates; Carbon dioxide utilization; CO2 fixation; Cyclic carbonates; Eco friendly processes; MCM 41; Polycarbonates; Polyurethanes

Indexed keywords

CARBON DIOXIDE; POLYCARBONATE; POLYURETHAN;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CYCLOADDITION; SOLID; SOLVATION; SYNTHESIS;

EID: 33646496350     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.04.057     Document Type: Article

References (38)

1. Shaikh A.G., and Sivaram S. Chem. Rev. 96 (1996) 951-976
2. Clements J.H. Ind. Eng. Chem. Res. 42 (2003) 663-674
3. Darensbourg D.J., and Holtcamp M.W. Coord. Chem. Rev. 153 (1996) 155-174
4. In: Kroschwitz J.I., and Howe-Grant M. (Eds). Kirk-Othmer Encyclopedia of Chemical Technology. 4th ed. Vol. 19 (1996), John Wiley & Sons, New York 584-608
5. Iwasaki T., Kihara N., and Endo T. Bull. Chem. Soc. Jpn. 73 (2000) 713-719
6. Kim H.S., Kim J.J., Lee B.G., Jung O.S., Jang H.G., and Kang S.O. Angew. Chem., Int. Ed. 39 (2000) 4096-4098
7. Paddock R.L., and Nguyen S.T. J. Am. Chem. Soc. 123 (2001) 11498-11499
8. Shen Y.-M., Duan W.-L., and Shi M. J. Org. Chem. 68 (2003) 1559-1562
9. Lu X.-B., Liang B., Zhang Y.-J., Tian Y.-Z., Wang Y.-M., Bai C.-X., Wang H., and Zhang R. J. Am. Chem. Soc. 126 (2004) 3732-3733
10. Peng J., and Deng Y. New J. Chem. 25 (2001) 639-641
11. Kawanami H., Sasaki A., Matsui K., and Ikushima Y. Chem. Commun. (2003) 896-897
12. Caló V., Nacci A., Monopoli A., and Fanizzi A. Org. Lett. 4 (2002) 2561-2563
13. Yano T., Matsui H., Koike T., Ishiguro H., Fujihara H., Yoshihara M., and Maeshima T. Chem. Commun. (1997) 1129-1130
14. Yamaguchi K., Ebitani K., Yoshida T., Yoshida H., and Kaneda K. J. Am. Chem. Soc. 121 (1999) 4526-4527
15. Tu M., and Davis R.J. J. Catal. 199 (2001) 85-91
16. Bhanage B.M., Fujita S., Ikushima Y., and Arai M. Appl. Catal. A 219 (2001) 259-266
17. BASF starts alkylene carbonate plant (product review),. In: Reidy R. (Ed). Filtration Industry Analyst 27 (1999), Elsevier Advanced Technology, Oxford, UK 2 (ISSN 1365-6937)
18. Fukuoka S., Kawamura M., Komiya K., Tojo M., Hachiya H., Hasegawa K., Aminaka M., Okamoto H., Fukawa I., and Konno S. Green Chem. 5 (2003) 497-507
19. Srivastava R., Srinivas D., and Ratnasamy P. Catal. Lett. 91 (2003) 133-139
20. Srivastava R., Srinivas D., and Ratnasamy P. Catal. Lett. 89 (2003) 81-85
21. Srivastava R., Srinivas D., and Ratnasamy P. Stud. Surf. Sci. Catal. 154C (2004) 2703-2710
22. Srivastava R., Srinivas D., and Ratnasamy P. J. Catal. 233 (2005) 1-15
23. Srivastava R., Srinivas D., and Ratnasamy P. Microporous Mesoporous Mater. 90 (2006) 314-326
24. Srivastava R., Srinivas D., and Ratnasamy P. Appl. Catal. A: Gen. 189 (2005) 128-134
25. Adams P., and Baron F.A. Chem. Rev. 65 (1965) 567-602
26. Chong P.Y., Janicki S.Z., and Petillo P.A. J. Org. Chem. 63 (1998) 8515-8521
27. An Ullmann Encyclopedia: Industrial Organic Chemicals: Starting Materials and Intermediates Vol. 2 (1999), Wiley-VCH, New York pp. 1045-1056
28. Li K.T., and Peng Y.J. J. Catal. 143 (1993) 631-634
29. Ragini F., and Cenini S. J. Mol. Catal. A: Chem. 109 (1996) 1-25
30. Shi F., Deng Y., Sima T., and Yang H. J. Catal. 203 (2001) 525-528
31. Dell'Amico D.B., Calderazzo F., Labella L., Marchetti F., and Pampaloni G. Chem. Rev. 103 (2003) 3857-3898
32. Aresta M., and Quaranta E. Tetrahedron 48 (1992) 1515-1530
33. Wolf A., and Schuth F. Appl. Catal. A 226 (2002) 1-13
34. Sima T., Guo S., Shi F., and Deng Y. Tetrahedron Lett. 43 (2002) 8145-8147
35. Inesi A., Mucciante V., and Rossi L. J. Org. Chem. 63 (1998) 1337-1338
36. Srivastava R., Manju M.D., Srinivas D., and Ratnasamy P. Catal. Lett. 97 (2004) 41-47
37. 2/g, pore volume = 0.75 cc/g, average pore diameter = 2.7 nm
38. 1H NMR, as described above. In some cases, the products were isolated by column chromatography (silica gel 60-120 mesh; 98:2 petroleum ether:ethyl acetate mixture as eluent) and a mass balance was established.