XPS Studies of Multiphase Polymer Systems

Handbook of Multiphase Polymer Systems

Volumn 1, Issue , 2011, Pages 585-637

  Chehimi, Mohamed M ^a   Djouani, Fatma ^a   Benzarti, Karim ^b  

^a UNIVERSITÉ PARIS DIDEROT   (France)

^b University Paris Est LCPC   (France)

Author keywords

Applications of XPS to polymeric materials; Arsenal of surface sensitive techniques for analyzing polymers; Interpenetrated polymer network (IPN) combination of two polymers in network form; Overlayer thickness, property surface analysis, identification of elements and functional groups; Polymers, in packaging, paints, adhesives sealants, automotive industry, biomedical diagnostic kits; Random and block copolymers XPS, characterizing surface of copolymers; State of the art XPS machines parallel imaging facility; XP spectrometer and required basic components; XPS studies of multiphase polymer systems; XPS studies on plasma deposition of polymers, and polymer plasma treatment

Indexed keywords

EID: 84881537753     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9781119972020.ch15     Document Type: Chapter

References (151)

1. NIST X-ray Photoelectron Spectroscopy Database. NIST Standard Reference Database 20, Version 3.5. Data compiled and evaluated by C. D. Wagner, A. V. Naumkin, A. Kraut-Vass, J. W. Allison, C. J. Powell, John R. Rumble, Jr. NIST Database. http://srdata.nist.gov/xps/
2. A. A. Galuska andD. EricHalverson, Quantitative analysis of surface ethylene concentrations in ethylene-propylene polymers using XPS valence bands, Surf. Interface Anal., 26, 425-432 (1998).
3. D. A. Shirley, C. S. Fadley, X-ray photoelectron spectroscopy in North America-the early years, J. Electron Spectrosc. Relat. Phenom., 137-140, 43-58 (2004).
4. G. Beamson and D. Briggs (Eds.) in High Resolution XPS of Organic Polymers. The Scienta ESCA300 Database. Wiley, Chichester (1992).
5. B. R. Strohmeier, The effects of O2 plasma treatments on the surface composition and wettability of cold-rolled aluminum foil, J. Vac. Sci. Technol. A, 7, 3238-3245 (1989).
6. M. P. Seah and W. A. Dench, Quantitative electron spectroscopy of surfaces: A standard data base for electron inelastic mean free paths in solids, Surf. Interface. Anal., 1, 2-11 (1979).
7. D. Briggs, M.P. Seah (Eds.), Practical Surface Analysis, Auger and X-Ray Photoelectron Spectroscopy, second ed., vol. 1, John Wiley, Chichester, UK, (1983) p. 201 p. 531.
8. D. Briggs (Ed.), Surface analysis of polymers by XPS and static SIMS. Cambridge University Press, Cambridge, U), 1998, pp. 34-39.
9. P. J. Cumpson, M. P. Seah, Elastic scattering corrections in AES and XPS. II. Estimating attenuation lengths and conditions required for their valid use in overlayer/substrate experiments, Surf. Interface Anal., 25, 430-446 (1997).
10. S. Tougaard, Surface nanostructure determination by x-ray photoemission spectroscopy peak shape analysis, J. Vac. Sci. Technol. A 14, 1415-1423 (1996).
11. S. Tougaard, Accuracy of the non-destructive surface nanostructure quantification technique based on analysis of the XPS or AES peak shape, Surf. Interface Anal., 26, 249-269 (1998).
12. http://www.quases.com/
13. S. Tanuma, C. J. Powell, D. R. Penn. Surf. Interface. Anal. 21, 165-176 (1993).
14. S. Tougaard. Surf. Interface Anal. 25, 137-155 (1997).
15. S. Gam-Derouich, B. Carbonnier, M. Turmine, P. Lang, M. Jouini, D. Ben Hassen-Chehimi, M. M. Chehimi. Electrografted aryl diazonium initiators for surface-confined photopolymerization: a new approach to design functional polymer coatings. Langmuir, 26, 11830-11840 (2010).
16. M. Lampimäki, K. Lahtonen, P. Jussila, M. Hirsimäki, M. Valden. Morphology and composition of nanoscale surface oxides on Fe-20Cr-18Ni{111} austenitic stainless steel. J. Electron Spectrosc. Relat. Phenom. 154, 69-78 (2007).
17. P. Jussila, H. Ali-Löytty, K. Lahtonen, M. Hirsimäki, M. Valden. Inhibition of initial surface oxidation by strongly bound hydroxyl species and Cr segregation: H2O andO2 adsorption on Fe-17Cr. Surf. Sci. 603, 3005-3010 (2009)
18. I. Preda, A. Gutiérrez, M. Abbate, F. Yubero, J. Méndez, L. Alvarez, L. Soriano. Interface effects in the Ni 2p x-ray photoelectron spectra of NiO thin films grown on oxide substrates. Phys. Rev. B 77, 075411-1 to 7 (2008).
19. V. Kisand, A. Kikas, E. Kukk, E. Nõmmiste, K. Kooser, T. Käämbre, R. Ruus, M. Valden, M. Hirsimäki, P. Jussila, M. Lampimäki, H. Aksela, S. Aksela. Substrate-induced effects in the creation and decay of potassium 2p core excitations in ultrathin films of KCl on copper. J. Phys.: Condens. Matter 20, 145206 (9pp) (2008).
20. M. Schleberger. Quantitative investigation of amorphous Fe/Ge and Fe/Si by inelastic peak shape analysis. Surf. Sci. 445, 71-79 (2000).
21. F. Yubero, C. Mansilla, F. J. Ferrer, J. P. Holgado, and A. R. González-Elipe. Size and shape of supported zirconia nanoparticles determined by x-ray photoelectron spectroscopy. J. Appl. Phys. 101, 124910 (2007).
22. C. López-Santos, F. Yubero, J. Cotrino, A. Barranco, A. R. González-Elipe. Plasmas and atom beam activation of the surface of polymers. J. Phys. D: Appl. Phys. 41, 225209 (12pp) (2008)
23. S. Hajati, V. Zaporojtchenko, F. Faupel, S. Tougaard. Characterization of Au nano-cluster formation on and diffusion in polystyrene using XPS peak shape analysis. Surf. Sci. 601, 3261-3267 (2007).
24. M. C. López-Santos, F. Yubero, J. P. Espinós, A. R. González-Elipe. Non-destructive depth compositional profiles by XPS peak-shape analysis. Anal. Bioanal. Chem. 396, 2757-2768 (2010).
25. S. Hajati, S. Coultas, C. Blomfield, S. Tougaard, Nondestructive quantitative XPS imaging of depth distribution of atoms on the nanoscale, Surf. Interface Anal., 40, 688-691 (2008).
26. W. Geyer, V. Stadler,W. Eck, M. Zharnikov, A. Gölzhäuser, M. Grunze. Electron-induced crosslinking of aromatic self-assembled monolayers: Negative resists for nanolithography. Appl. Phys. Lett. 75, 2401-2403 (1999).
27. M. Steenackers, A. Küller, N. Ballav, M. Zharnikov, M. Grunze, R. Jordan. Morphology control of structured polymer brushes. Small 3, 1764-1773 (2007).
28. K. Artyushkova. Structure determination of nanocomposites through 3D imaging using laboratory XPS and multivariate analysis. J. Electron Spectrosc. Relat. Phenom. 178-179, 292-302 (2010).
29. L. J. Gerenser, XPS of in-situ plasma modified polymers. In Plasma surface modification of polymers, M. Strobel, C. S. Lyons, K. L. Mittal (Eds.) pp. 43-64. / Polymer surface modification, K. L. Mittal (Ed.), VSP, Utrecht (The Netherlands), 2000.
30. M. Manso , A. Rodriguez, A. Paul, J. Barrero, F. Rossi, Plasma functionalization, surface characterization and protein retention of multiple-sized polymer beads, Surf. Interface Anal., 38, 322-325 (2006).
31. D. J. Balazs, K. Triandafillu, Y. Chevolot, B.-O. Aronsson, H. Harms, P. Descouts, H. J. Mathieu, Surf. Interface Anal., 35, 301-309 (2003).
32. A. Vesel, M. Mozetic, A. Zalar, XPS characterization of PTFE after treatment with RF oxygen and nitrogen plasma, Surf. Interface Anal., 40, 661-663 (2008).
33. S. Edmondson, V. L. Osborne, W. T. S. Huck, Polymer brushes via surface-initiated polymerizations, Chem. Soc. Rev., 33, 14-22 (2004).
34. Y. Tsujii, K. Ohno, S. Yamamoto, A. Goto, T. Fukuda, Structure and properties of high-density polymer brushes prepared by surface-initiated living radical polymerization, Adv. Polym. Sci., 197, 1-45 (2006).
35. T. Matrab, M.M. Chehimi, C. Perruchot, A. Adenier, V. Guillez, M. Save, B. Charleux, E. Cabet-Deliry, J. Pinson, Novel approach for metallic surface-initiated atom transfer radical polymerization using electrografted initiators based on aryl diazonium salts, Langmuir, 21, 4686-4694 (2005).
36. Qin Jia Cai, Guo Dong Fu, Fu Rong Zhu, En-Tang Kang, Koon-Gee Neoh, GaAs-polymer hybrids formed by surface-initiated atom-transfer radical polymerization of methyl methacrylate, Ang. Chem. Int. Ed., 44, 1104-1107 (2005).
37. T. Matrab, M.M. Chehimi, J. Pinson, S. Slomkowski, T. Basinska, Growth of polymer brushes by atom transfer radical polymerization from glassy carbon modified by electro-grafted initiators based on aryl diazonium salts , Surf. Interface Anal., 38, 565-568, (2006).
38. M. N. Nguyen, T. Matrab, C. Badre, M. Turmine, M. M. Chehimi, Interfacial aspects of polymer brushes prepared on conductive substrates by aryl diazonium salt surface-initiated ATRP, Surf. Interface Anal., 40, 412-417 (2008).
39. T. Matrab, M. Save, B. Charleux, J. Pinson, E. Cabet-Deliry, A. Adenier, M. M. Chehimi, M. Delamar, Grafting densely-packed poly(n-butyl methacrylate) chains from an iron substrate by aryl diazonium surface-initiated ATRP: XPS monitoring, Surf. Sci., 601, 2357-2366 (2007).
40. D. Li, Q. He, Y. Cui, J. Li, Thermoresponsive gold nanoparticles with adjustable lower critical solution temperature as colorimetric sensors for temperature, pH and salt Concentration, Chem. Mater., 19, 412-417 (2007).
41. F.J. Xu, S.P. Zhong, L.Y.L. Yung, Y.W. Tong, En-Tang Kang, K.G. Neoh, Thermoresponsive comb-shaped copolymer-Si(1 0 0) hybrids for accelerated temperature-dependent cell detachment, Biomater., 27, 1236-1245 (2006).
42. C. Sun, F. Zhou, L. Shi, B. Yu, P. Gao, J. Zhang, W. Liu, Tribological properties of chemically bonded polyimide films on silicon with polyglycidyl methacrylate brush as adhesive layer, Appl. Surf. Sci., 253, 1729-1735 (2006).
43. H. Ma, D. Li, X. Sheng, B. Zhao, A. Chilkoti, Protein-resistant polymer coatings on silicon oxide bysurface-initiated atom transfer radical polymerization, Langmuir, 22, 3751-3756 (2006).
44. B. Mrabet, M. N. Nguyen, A. Majbri, S. Mahouche, M. Turmine, A. Bakhrouf, M. M. Chehimi, Anti-fouling poly(2-hydoxyethyl methacrylate) surface coatings with specific bacteria recognition capabilities, Surf. Sci. 603, 2422-2429 (2009).
45. S. Gam-Derouich, M. N. Nguyen, A. Madani, N. Maouche, P. Lang, C. Perruchot, M. M. Chehimi. Aryl diazonium salt surface chemistry and ATRP for the preparation of molecularly imprinted polymer grafts on gold substrates. Surf. Interface Anal., 42, 1050-1056 (2010).
46. T. Matrab, M. N. Nguyen, S. Mahouche, P. Lang, C. Badre, M. Turmine, G. Girard, J. Bai, M. M. Chehimi, Aryl diazonium salts for carbon fiber surface-initiated atom transfer radical polymerization, J. Adhes., 84, 684-701 (2008).
47. T. Matrab,M.M. Chehimi, J. P. Boudou, F. Benedic, J.Wang, N.N. Naguib, J. A. Carlisle, Surface functionalization of ultrananocrystalline diamond using atom transfer radical polymerization (ATRP) initiated by electro-grafted aryldiazonium salts, Diamond Relat. Mater., 15, 639-644 (2006).
48. S. Mahouche Chergui, N. Abbas, T. Matrab, M. Turmine, E. Bon Nguyen, R. Losno, J. Pinson, M. M. Chehimi, Uptake of copper ions by carbon fiber/polymer hybrids prepared by tandem diazonium salt chemistry and in situ atom transfer radical polymerization, Carbon, 48, 2106-2111 (2010).
49. Y. Shaulov, R. Okner, Y. Levi, N. Tal, V. Gutkin, D. Mandler, A. J. Domb. Poly(methyl methacrylate) grafting onto stainless steel surfaces: application to drug-eluting stents. ACS Appl. Mater. Interfaces, 1, 2519-2528 (2009).
50. D. J. Dyer, Photoinitiated synthesis of grafted polymers, Adv. Polym. Sci., 197, 47-65, (2006).
51. (a) C. Slim, Y. Tran, M. M. Chehimi, N. Garraud, J.-P. Roger, C. Combellas, F. Kanoufi. Microelectrochemical patterning of surfaces with polymer brushes. Chem. Mater. 20, 6677-6685 (2008).
52. F. Hauquier, T. Matrab, F. Kanoufi, C. Combellas. Local direct and indirect reduction of electrografted aryldiazonium/gold surfaces for polymer brushes patterning. Electrochim. Acta 54, 5127-5136 (2009).
53. M. C. Davies, R. A. P. Lynn, S. S. Davis, J. Hearn, J. F. Watts, J. C. Vickerman, A. J. Paul, Preparation of polymer latex particles with immobilized sugar residues and their surface characterization by X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry, Langmuir, 9, 1637-1645 (1993)
54. M. C. Davies, R. A. P. Lynn, J. Hearn, A. J. Paul, J. C. Vickerman, and J. F.Watts, Surface chemical characterization using XPS and ToF-SIMS of latex particles prepared by the emulsion copolymerization of methacrylic acid and styrene, Langmuir, 12, 3866-3875 (1996).
55. Y. Deslandes, D. F. Mitchell, A. J. Paine, X-ray photoelectron spectroscopy and static time-of-flight secondary ion mass spectrometry study of dispersion polymerized polystyrene latexes, Langmuir, 9, 1468-1472 (1993).
56. E. Pacard, M. A. Brook, A. M. Ragheb, C. Pichot, C. Chaix, Elaboration of silica colloid/polymer hybrid support for oligonucleotide synthesis, Colloids Surf. B: Biointerfaces, 47, 176-188 (2006).
57. T. Basinska, S. Slomkowski, S. Kazmierski, A. Dworak, M. M. Chehimi, Studies of the surface layer structure and properties of poly(styrene/a-t-butoxy--polyglycidol) microspheres by carbon nuclear magnetic resonance, X-ray photoelectron spectroscopy, and the adsorption of human serum albumin and -globulins, J. Polym. Sci. A: Polym. Chem., 42, 615-623 (2004).
58. R.Díaz-López, N. Tsapis,D. Libong, P. Chaminade, C. Connan, M. M. Chehimi, R. Berti, N. Taulier , W. Urbach, V. Nicolas, E. Fattal, Phospholipid decoration of microcapsules containing perfluorooctyl bromide used as ultrasound contrast agents, Biomater., 30, 1462-1472 (2009).
59. C. Pichot, Surface-functionalized latexes for biotechnological applications, Curr. Op. Colloid Interface Sci., 9, 213-221 (2004).
60. T. Basinska, S. Slomkowski, A.Dworak, I. Panchev,M.M. Chehimi, Synthesis and characterization of poly(styreneco- a-t-butoxy-o-vinylbenzyl-polyglycidol) microspheres, Colloid Polym. Sci., 279, 916-924 (2001).
61. P. Bardonnet (Ed.) Résines Epoxydes: composants et propriétés. Techniques de l'ingénieur (1992), traité Plastiques et Composites.
62. B. De'Neve, Ph.D. Thesis, Ecole Nationale Supérieure des Mines de Paris, 1993. 56. R. G. Dillingham, F. J. Boerio, Interphase composition in aluminum/epoxy adhesive joints, J. Adhes., 24, 315-335 (1987).
63. M. Kinzler, D. M. Grunge, N. Blank, X-ray photoelectron microscopy applied to metal/epoxy laminates, J. Vac. Sci. Technol. A10, 2691-2697 (1992).
64. J. F. Watts, A. Rattana, M.-L. Abel, Interfacial chemistry of adhesives on hydrated aluminium and hydrated aluminium treated with an organosilane. Surf. Interface Anal., 36, 1449-1468 (2004).
65. J. A. Kelber and R. K. Brow. Model epoxy/metal-oxide chemical interactions: diethandamine on oxidized copper and aluminium. Appl. Surf. Sci., 59, 273-280 (1992).
66. S. Afrossman, R. F. Comrie, S.M.MacDonald. Interaction of a model epoxy resin compound, diethanolamine, with aluminium surfaces studied by static SIMS and XPS. J. Chem. Soc., Faraday Trans., 94, 289-294 (1998).
67. R. B. Borade, A. Sayari, A. Adnot and S. Kaliaguine, Characterization of acidity in ZSM-5 zeolites: an X-ray photoelectron and IR spectroscopy study, J. Phys. Chem., 94, 5989-5994 (1990).
68. R. B. Borade and A. Clearfeld, Characterization of acid sites in Beta and ZSM-20 zeolites, J. Phys. Chem., 96, 6729-6737 (1992).
69. J. H. Roh, J. H. Lee, N. I. Kim, H. M. Kang, T.-H. Yoon, K. H. Song, DSC analysis of epoxy molding compound with plasma polymer-coated silica fillers. J. Appl. Polym. Sci., 90, 2508-2516 (2003).
70. S. Scierka, A. Forster, W. Kosik, An XPS analysis of the interfacial interaction between oxides and epoxy resin. Federation of Societies for Coatings Technology, 492 Norristown Rd., Blue Bell, PA 19422 USA.
71. F. Awajaa, P. J. Pigram, Surface molecular characterisation of different epoxy resin composites subjected to UV accelerated degradation using XPS and ToF-SIMS, Polym. Degrad. Stab., 94, 651-658 (2009).
72. S.-G. Hong, The thermal-oxidative degradation of an epoxy adhesive on metal substrates: XPS and RAIR analyses, Polym. Degrad. Stab., 48, 211-218 (1995).
73. G. Z. Xiao, M. Delamar, M. E. R. Shanahan, Irreversible Interactions Between Water and DGEBA/DDA. Epoxy Resin During Hygrothermal Aging. J. Appl. Polym. Sci. 65, 449-458 (1997).
74. S. R. Leadley, J. F. Watts, C. J. Blomfield, C. Lowe. The Use of high-resolution XPS and ToF-SIMS to investigate segregation phenomena of minor components of a model coil coating formulation. Surf. Interface Anal. 26, 444-454 (1998).
75. M. I. Baeta Neves, V. Oliva, B.Mrabet, C. Connan, M. M. Chehimi, M. Delamar, S. Hutton, A. Roberts, K. Benzarti, Surface chemistry of cement pastes: a study by x-ray photoelectron spectroscopy, Surf. Interface Anal. 33, 834-841 (2002).
76. F. Djouani, C. Connan, M. M. Chehimi, K. Benzarti. Interfacial chemistry of epoxy adhesives on hydrated cement paste. Surf. Interface Anal. 40, 146-150 (2008).
77. T. A. Skotheim, (Ed.), Handbook of Conducting Polymers, vols 1 and 2, Marcel Dekker, New York (1986).
78. T. A. Skotheim, R. L. Elsenbaumer and J. R. Reynolds (Eds.), Handbook of conducting polymers, second edition. Marcel Dekker, New York (1998).
79. M. Aldissi (Ed.), Intrinsically conducting polymers: an emerging technology, Kluwer Academic Publishers, Dordrecht, The Netherlands (1993).
80. H. S. Nalwa (Ed.), Handbook of organic conductive molecules and polymers: Vol. 2. Conductive polymers: synthesis and electrical properties. John Wiley & Sons Inc, New York (1997).
81. T. A. Skotheim and J. Reynolds, Handbook of conducting polymers, third edition, CRC Press, Boca Raton, USA (2006).
82. S. Sadki, P. Schottland, N. Brodiec, G. Sabouraud, The mechanisms of pyrrole electropolymerization, Chem. Soc. Rev., 29, 283-293 (2000).
83. I. L. Lehra and S. B. Saidman, Morphology and properties of polypyrrole electrosynthesized onto iron from a surfactant solution, Synth. Met., 159, 1522-1528 (2009)
84. I. L. Lehra and S. B. Saidman, Corrosion protection of iron by polypyrrole coatings electrosynthesised from a surfactant solution, Corr. Sci., 49, 2210-2225 (2007).
85. W. Khan, M. Kapoor, N. Kumar, Covalent attachment of proteins to functionalized polypyrrole-coated metallic surfaces for improved biocompatibility, Acta Biomater., 3, 541-549 (2007).
86. M. Bazzaoui1, J. I. Martins, E. A. Bazzaoui, T. C. Reis, and L. Martins, Pyrrole electropolymerization on copper and brass in a single-step process from aqueous solution, J. Appl. Electrochem., 34, 815-822 (2004).
87. S. Cosnier, M. Holzinger, Design of carbon nanotube-polymer frameworks by electropolymerization of SWCNTpyrrole derivatives, Electrochim. Acta, 53, 3948-3954 (2008).
88. J. C. Thiéblemont, M.F. Planche, C. Petrescu, J.M. Bouvier, G. Bidan, Stability of chemically synthesized polypyrrole films, Synth. Met., 59, 81-96 (1993)
89. K. Cheah, M. Forsyth, V.-T. Truong, C. Olsson-Jacques, Mechanisms governing the enhanced thermal stability of acid and base treated polypyrrole, Synth. Met., 84, 829-830 (1997).
90. M. A. Khan, S. P. Armes, Conducting polymer-coated latexes, Adv. Mater., 12, 671 (2000).
91. M. M. Chehimi, A. Azioune, S. Bousalem, A. Ben Slimane, A. Yassar, Preparation, characterisation and biomedical applications of conducting polymer particles, in Colloid polymers. Synthesis and characterization, H. Elaissari (Ed.), Marcel Dekker Inc. (NY), Surfactant Science Series, 115, 245-284 (2003), Chap.10.
92. A. Azioune, A. Ben Slimane, L. Ait Hamou, A. Pleuvy, M. M. Chehimi, C. Perruchot, S. P. Armes, Synthesis and characterization of active ester-functionalized polypyrrole-silica nanoparticles: application to the covalent attachment of proteins, Langmuir, 20, 3350-3356 (2004).
93. S. Bousalem, S. Benabderrahmane, Y. Yip Cheung Sang, C. Mangeney, M. M. Chehimi, Covalent immobilization of human serum albumin onto reactive polypyrrole-coated polystyrene latex particles, J. Mater. Chem., 15, 3109-3116 (2005).
94. M. Omastová, K. Boukerma,M.M.Chehimi,M. Trchova,Novel silicon carbide/polypyrrole composites; preparation and physicochemical properties, Mater. Res. Bull., 40, 749-765 (2005).
95. A. Ben Slimane, C. Connan, M.-J.Vaulay, M. M. Chehimi, Preparation and surface analysis of pigment@polypyrrole composites, Colloids Surf. A: Physicochem. Eng. Asp., 332, 157-163 (2009).
96. C. Mangeney, S. Bousalem, C. Connan, M.-J. Vaulay, S. Bernard, M. M. Chehimi, Latex and hollow particles of reactive polypyrrole: preparation, properties, and decoration by gold nanospheres Langmuir, 22, 10163-10169 (2006).
97. A. Madani, B. Nessark, R. Brayner, H. Elaissari, M. Jouini, C. Mangeney, M. M. Chehimi. Carboxylic acid-functionalized, coreeshell polystyrene@polypyrrole microspheres as platforms for the attachment of CdS nanoparticles. Polymer, 51, 2825-2835 (2010).
98. J. Jang, H. Yoon, Formation mechanism of conducting polypyrrole nanotubes in reverse micelle systems, Langmuir, 21, 11484-11489 (2005).
99. K. Boukerma, J.-Y. Piquemal, M. M. Chehimi, M. Mravcáková, M. Omastová, P. Beaunier, Synthesis and interfacial properties of montmorillonite/polypyrrole nanocomposites, Polymer, 47, 569-576 (2006).
100. M. Mravcáková, K. Boukerma, M. Omastová and M. M. Chehimi, Montmorillonite/polypyrrole nanocomposites. The effect of organic modification of clay on the chemical and electrical properties, Mater. Sci. Eng. C, 26, 306-313 (2006).
101. S. Cosnier, Affinity biosensors based on electropolymerized films, Electroanal. 17, 1701-1715 (2005).
102. C. Perruchot, M. M. Chehimi, M. Delamar, F. Dardoize, C haracterisation of the chromatographic properties of a silica-polypyrrole composite stationary phase by inverse liquid chromatography, J. Chrom. A, 969, 167-180 (2002).
103. U. Lange, N. V. Roznyatovskaya1, V.M.Mirsky, Conducting polymers in chemical sensors and arrays, Anal. Chim. Acta, 614, 1-26 (2008).
104. D.M. Lenz, M. Delamar, C.A. Ferreira, Application of polypyrrole/TiO2 composite films as corrosion protection of mild steel, J. Electroanal. Chem., 540, 35-44 (2003).
105. D. M. Lenz, M. Delamar, C. A. Ferreira, Improvement of the anticorrosion properties of polypyrrole by zinc phosphate pigment incorporation, Prog. Org. Coat., 58, 64-69 (2007).
106. D.E. Tallman, G.P. Bierwagen, Corrosion protection using conducting polymers, in: Handbook of conducting polymers, third edition: Conjugated polymers - processing and applications, CRC Press, 2006, pp. 15-1 to 15-53 (Chapter 15).
107. K. Boukerma, M. Micusík, M. Mravcáková, M. Omastová, M.-J. Vaulay, P. Beaunier, M. M. Chehimi, Surfactantassisted control of the surface energy and interfacial molecular interactions of polypyrrole, Colloids Surf. A Physicochem. Eng. Asp., 293, 28-38 (2007).
108. E. T. Kang, K. G. Neoh and K. L. Tan, The intrinsic redox states in polypyrrole and polyaniline: A comparative study by XPS, Surf. Interface Anal., 19, 33-37 (1992).
109. B. Saoudi, N. Jammul, M.-L. Abel, M. M. Chehimi and G. Dodin, DNA adsorption onto conducting polypyrrole, Synth. Met., 87, 97-103 (1997).
110. E. T. Kang, K. G. Neoh, X. Zhang, K. L. Tan and D. J. Liaw, Surface modification of electroactive polymer films by ozone treatment, Surf. Interface Anal., 24, 51-58 (1996).
111. B. Saoudi, N. Jammul, M. M. Chehimi, A.-S. Jaubert, C. Arkam and Michel Delamar, XPS study of the adsorption mechanisms of DNA onto polypyrrole particles, Spectrosc. Int. J., 18, 519-535 (2004).
112. M. M. Chehimi, E. Abdeljalil, Astudy of the degradation and stability of polypyrrole by inverse gas chromatography, X-ray photoelectron spectroscopy, and conductivity measurements, Synth. Met., 145, 15-22 (2004).
113. E. T. Kang, K. G. Neoh and K. L. Tan, X-ray photoelectron spectroscopic studies of electroactive polymers, Adv. Polym. Sci., 106, 135-190 (1993).
114. L. Sabbatini, C. Malitesta, E. De Giglio, I. Losito, L. Torsi, P. G. Zambonin, Electrosynthesised thin polymer films: the role of XPS in the design of application oriented innovative materials, J. Electron Spectrosc.Relat. Phenom., 100, 35-53 (1999).
115. A. Azioune,M.M. Chehimi, B.Miksa, T. Basinska, S. Slomkowski, Hydrophobic protein-polypyrrole interactions: the role of van der Waals and Lewis acid-base forces as determined by contact angle measurements, Langmuir, 18, 1150-1156 (2002).
116. A. Voelkel, B. Strzemiecka, K. Adamska, K. Milczewska, Inverse gas chromatography as a source of physiochemical data, J. Chrom. A, 1216, 1551-1566 (2009).
117. K. Boukerma, M. Omastová, P. Fedorko, M. M. Chehimi, Surface properties and conductivity of bis(2-ethylhexyl) sulfosuccinate-containing polypyrrole, Appl. Surf. Sci. 249, 303-314 (2005).
118. C. Malitesta, L. Losito, L. Sabbatini, P.G. Zambonin, New findings on polypyrrole chemical structure by XPS coupled to chemical derivatization labelling, J. Electron Spectrosc. Relat. Phenom., 76, 629-634 (1995).
119. M. M. Chehimi, M-L. Abel and Z. Sahraoui, An inverse gas chromatographic study of the PMMA/conducting polypyrrole interface, J. Adhes. Sci. Technol., 10, 287-303 (1996).
120. M.-L. Abel, M. M. Chehimi, F. Fricker and M. Delamar, A. M. Brown and J. F. Watts, Adsorption of PMMA and PVC blends onto polypyrrole: a study by XPS, ToF-SSIMS and inverse gas chromatography, J. Chrom. A, 969, 273-285 (2002).
121. M. M. Chehimi, M.-L. Abel, C. Perruchot, M. Delamar, S. F. Lascelles, S. P. Armes, The determination of the surface energy of conducting polymers by inverse gas chromatography at infinite dilution, Synth. Met., 104, 51-59 (1999).
122. F. M. Fowkes, Quantitative characterization of the acid-base properties of solvents, polymers, and inorganic surfaces, J. Adhes. Sci. Technol., 4, 669-691 (1990)
123. M. M. Chehimi, A. Azioune, E. Cabet-Deliry, Acid-base interactions: relevance to adhesion and adhesive bonding, in Handbook of adhesive technology, K. L. Mittal and A. Pizzi (Eds.), Marcel Dekker Inc. (NY), 2003, Chap. 5, pp. 95-144.
124. M.-L. Abel, M. M Chehimi, Effect of acid-base interactions on the adsorption of PMMA on chloride-doped polypyrrole from neutral, acidic and basic solvents: an XPS study. Synth. Met., 66, 225-233 (1994).
125. S. Bousalem, C. Mangeney, Y. Alcote, M. M. Chehimi, T. Basinska, S. Slomkowski, Immobilization of proteins onto novel, reactive polypyrrole-coated polystyrene latex particles, Colloids Surf. A Physicochem. Eng. Asp., 249, 91-94 (2004).
126. S. Benabderrahmane, S. Bousalem, C. Mangeney, A. Azioune, M.-J. Vaulay, M. M. Chehimi, Interfacial physicochemical properties of functionalized conducting polypyrrole particles, Polymer, 46, 1339-1346 (2005).
127. T. K. Kwei, The effect of hydrogen bonding on the glass transition temperatures of polymer mixtures, J. Polym. Sci. Polym. Lett. Ed. 22, 307-313 (1984)
128. T. K. Kwei, E. M. Pearce, J. R. Pennacchia, M. Charton, Correlation between the glass transition temperatures of polymer mixtures and intermolecular force parameters, Macromolecules, 20, 1174-1176 (1987).
129. E. M. Pearce, T. K. Kwei, S. Lu, Miscible blends through hydrogen bonding: effects on polymer properties, Polym. Adv. Technol. 5, 600-602 (1994).
130. Y. Duan, E. M. Pearce, T. K. Kwei, X. Hu, M. Rafailovich, J. Sokolov, K. Zhou, S. Schwarz, Surface enrichment in polymer blends involving hydrogen bonding, Macromolecules 34, 6761-6767 (2001)
131. X.-M. Zeng, C.-M. Chan, L.-T.Weng, L. Li, Surface characterization and quantitative study of poly(4-vinyl phenol) and poly(4-vinyl pyridine) blends by XPS and ToF-SIMS, Polymer 41, 8321-8329 (2000).
132. L. Jong, E. M. Pearce, T. K. Kwei, NMR study of hydrogen bonded polymer blends: influence of the tacticity of poly(methyl methacrylate) on its miscibility with poly(styrene-co-vinylphenol), Polymer, 34, 48-55 (1993).
133. L. Kailas, B. Nysten, J.-N. Audinot, H.-N. Migeon, P. Bertrand, Multitechnique characterization of thin films of immiscible polymer systems: PS-b-PMMA diblock copolymers and PS-PMMA symmetric blends, Surf. Interface Anal., 37, 435-443 (2005)
134. G. Beamson, P. Mokarian-Tabari, M. Geoghegan, Composition depth profiling of polystyrene/poly(vinyl ethyl ether) blend thin films by angle resolved XPS, J. Electron Spectrosc. Relat. Phenom. 171, 57-63 (2009).
135. D. Briggs in ref. 8, section 6.5, pp. 177-184.
136. D. Briggs, Spectrosc.Eur. 5, 8 (1993).
137. Y.G. Lei, Z.-L. Cheung, K.-M. Ng, Lin Li, Lu-Tao Weng, Chi-Ming Chan, Surface chemical and morphological properties of a blend containing semi-crystalline and amorphous polymers studied with ToF-SIMS, XPS and AFM, Polymer 44, 2883-2890 (2003).
138. C. Perruchot, M. A. Khan, A. Kamitsi, S. P. Armes, J. F. Watts, T. von Werne, T. E. Patten. XPS characterisation of core-shell silica-polymer composite particles synthesised by atom transfer radical polymerisation in aqueous media. Eur. Polym. J. 40, 2129-2141 (2004).
139. F. Djouani, F. Herbst, M.M. Chehimi, K. Benzarti. Synthesis, characterization and reinforcing properties of novel, reactive clay/poly(glycidyl methacrylate) nanocomposites. Construct. Build. Mater. 25, 424-431 (2011).
140. Firas Awaja, Jin Bum Moon, Shengnan Zhang, M. Gilbert, Chun Gon Kim, P. J. Pigram. Surface molecular degradation of 3D glass polymer composite under low earth orbit simulated space environment. Polym. Degrad. Stab., 95, 987-996 (2010).
141. L. A. Pothan, F. Simon, S. Spange, S. Thomas. XPS Studies of chemically modified banana fibers. Biomacromolecules, 7, 892-898 (2006).
142. J. Kurdi, A. Kumar, Structuring and characterization of a novel highly microporous PEI/BMI semi-interpenetrating polymer network. Polymer, 46, 6910-6922 (2006).
143. R. Vendamme, S.-Y. Onoue, A. Nakao, T. Kunitake, Robust free-standing nanomembranes of organic/inorganic interpenetrating networks. Nature Mater. 5, 494-501 (2006)
144. F. Garbassi, M. Morra, E. Occhiello (Eds.), Polymer surfaces. From physics to technology. John Wiley & Sons Ltd, Chichester 1994, p. 103.
145. Shiyong Liu, Lu-TaoWeng, Chi-Ming Chan, Lin Li, Nick K. Ho, Ming Jiang. Quantitative surface characterization of poly(styrene)/poly(4-vinyl phenol) random and block copolymers by ToF-SIMS and XPS. Surf. Interface Anal. 31, 745-75 (2001)
146. A. Sezai Sarac, S. A.M. Tofail, M. Serantoni, J. Henry, V. J. Cunnane, J. B.McMonagle, Surface characterisation of electrografted random poly[carbazole-co-3-methylthiophene] copolymers on carbon fiber: XPS, AFM and Raman spectroscopy. Appl. Surf. Sci. 222, 148-165 (2004).
147. Tatsuo Teraya, Atsushi Takahara, Tisato Kajiyama, Surface chemical composition and surface molecular mobility of diblock and random copolymers with hydrophobic and hydrophilic segments. Polymer 31, 1149-1153 (1990).
148. K.B. Wiles, C.M. de Diego, J. de Abajo, J.E. McGrath. Directly copolymerized partially fluorinated disulfonated poly(arylene ether sulfone) random copolymers for PEM fuel cell systems: Synthesis, fabrication and characterization of membranes and membrane-electrode assemblies for fuel cell applications. J. Membrane Sci. 294, 22-29 (2007).
149. D. T. Clark, J. Peeling, J. M. O'Malley. Application of ESCA to polymer chemistry .8. surface-structures of ab block copolymers of polydimethylsiloxane and polystyrene. J. Polym. Sci. Polym. Chem. Ed. 14, 543-551 (1976).
150. Shiyong Liu, Yinghua Ma, S. P. Armes, C. Perruchot, J. F. Watts. Direct verification of the core-shell structure of shell cross-linked micelles in the solid state using x-ray photoelectron spectroscopy. Langmuir, 18, 7780-7784 (2002).
151. S. Turgeon, R. W. Paynter, On the determination of carbon sp2 / sp3 ratios polystyrene-polyethylene copolymers by photoelectron spectroscopy. Thin Solid Films, 394, 44-48 (2001).