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Volumn 42, Issue 34, 2013, Pages 12203-12219

Novel aspects of the transamination reaction between Ti(NMe 2)4 and primary amines

Author keywords

[No Author keywords available]

Indexed keywords

2 ,6-DIISOPROPYLANILINE; ALKYL AMINES; EQUILIBRIUM REACTIONS; EXPERIMENTAL CONDITIONS; MULTIPLE SPECIES; PRIMARY AMINES; TRANSAMINATION REACTION; X-RAY DIFFRACTION STUDIES;

EID: 84881464933     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt50840d     Document Type: Article
Times cited : (17)

References (92)
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  • 69
    • 0001027517 scopus 로고    scopus 로고
    • The X-ray structure of 3 is given in ESI, and a related synthesis of 3 was recently reported during the course of our investigations by Johnson et al. who used a thermal reaction [see ref. 5f] to produce the same compound that crystallized with different cell parameters
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    • 2 and/or trapping transient species. The example of pyridine is described later in the text Dichloromethane as a solvent gave rise to the formation of chlorinated products For comparison with related TiNR complexes, see, for example, ref. 2f, 5c, 9 and J. Inorg. Organomet. Polym. Mater. 2007 17 423 437.
    • (2007) J. Inorg. Organomet. Polym. Mater. , vol.17 , pp. 423-437
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  • 76
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    • however, in this example the bridging mode of the aryl-imido ligand is likely to be due to further additional coordination of two pyrrol ortho-substituents For other examples of mono-bridged imido with additional bridging ligands (oxo, azo), see
    • S. H. Lee C. J. Wu U. G. Joung B. Y. Lee J. Park Dalton Trans. 2007 4608 4614
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    • 4756-4758
    • 3SiNHAr*). In certain cases oligomeric complexes are obtained, see the recent study: C. Lorber and L. Vendier, Inorg. Chem., 2013, 52 Bergman Org. Lett. 2002 4 1475 1477
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.