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The X-ray structure of 3 is given in ESI, and a related synthesis of 3 was recently reported during the course of our investigations by Johnson et al. who used a thermal reaction [see ref. 5f] to produce the same compound that crystallized with different cell parameters
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2 and/or trapping transient species. The example of pyridine is described later in the text Dichloromethane as a solvent gave rise to the formation of chlorinated products For comparison with related TiNR complexes, see, for example, ref. 2f, 5c, 9 and J. Inorg. Organomet. Polym. Mater. 2007 17 423 437.
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