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We were unable to determine the ratio 1:2 by NMR spectroscopy due to the strong paramagnetism of 2. A visual determination under microscope showed this ratio to be approximately 1.
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We were unable to determine the ratio 1:2 by NMR spectroscopy due to the strong paramagnetism of 2. A visual determination under microscope showed this ratio to be approximately 1.
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45
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37049096497
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τ is the angular parameter commonly used to describe the geometry around the metal center in pentacoordinate complexes and defined as τ, α-β)/60 α and β are the two largest L-M-L bond angles, with α ≥ β, Addison, A. W, Rao, T. N, Reedijk, J, van Rijn, J. V. J. Chem. Soc, Dalton Trans. 1984, 1349-1356
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τ is the angular parameter commonly used to describe the geometry around the metal center in pentacoordinate complexes and defined as τ = (α-β)/60 (α and β are the two largest L-M-L bond angles, with α ≥ β). Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J. V. J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
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48
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47249084666
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Although we used isolated TiCl2(NMe2)2 in most of the syntheses reported in this article, we have checked that in-situ-prepared TiCl2(NMe2)2 (from equimolar amounts of TiCl4 and Ti(NMe2)4) or TiCl2(NMe2)2(THF)2 (from equimolar amounts of TiCl4 and Ti(NMe2)4 in THF) can be used as well for convenience
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4 in THF) can be used as well for convenience.
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49
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0003600638
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52
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47249104657
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For simplicity, discussion has been limited to only one of the two independent units of 3e in the unit cell. There are no significant differences in the bond parameters between these two species.
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For simplicity, discussion has been limited to only one of the two independent units of 3e in the unit cell. There are no significant differences in the bond parameters between these two species.
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53
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2 rings) are 3.545 and 3.410 Å; offset angle between the ring normal of the aryl-imido and the centroid of the vector are 18.5° and 21.1° (for a review on π-π stacking, see: Janiak, C. Dalton Trans. 2000, 3885-3896).
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2 rings) are 3.545 and 3.410 Å; offset angle between the ring normal of the aryl-imido and the centroid of the vector are 18.5° and 21.1° (for a review on π-π stacking, see: Janiak, C. Dalton Trans. 2000, 3885-3896).
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