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34247855230
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2: After 5 h the major compound is 1. After 1 day we noted the presence of several species (or isomers) including 3. After 3 days the major compound is 4.
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2: After 5 h the major compound is 1. After 1 day we noted the presence of several species (or isomers) including 3. After 3 days the major compound is 4.
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118
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34247890295
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Ti-N bond distances in structurally characterized terminal imido complexes usually range 1.66-1.76 Å (Cambridge Crystallographic Database).
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Ti-N bond distances in structurally characterized terminal imido complexes usually range 1.66-1.76 Å (Cambridge Crystallographic Database).
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119
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33748216611
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120
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33751392439
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3SiCl as chlorinated agent by cleavage of Ti-N(amido) bond in group 4 complexes, see the following: (a) Arney, D. J.; Bruck, M. A.; Huber, S. R.; Wigley, D. E. Inorg. Chem. 1992, 31, 3749-3755.
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3SiCl as chlorinated agent by cleavage of Ti-N(amido) bond in group 4 complexes, see the following: (a) Arney, D. J.; Bruck, M. A.; Huber, S. R.; Wigley, D. E. Inorg. Chem. 1992, 31, 3749-3755.
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34247844726
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2 will be described elsewhere.
-
2 will be described elsewhere.
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126
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34247894145
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Vanadium Organometallics
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Crabtree, R. H, Mingos, D. M. P, Eds, Elsevier: Oxford, U.K
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34247849575
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-
1/c (a = 13.2975(10), b = 8.5345(8), and c = 15.5771(14) ?, and β = 98.878(10)°; see Supporting Information).
-
1/c (a = 13.2975(10), b = 8.5345(8), and c = 15.5771(14) ?, and β = 98.878(10)°; see Supporting Information).
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33751553250
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1/c): Zhang, Y.; Holm, R. H. Inorg. Chem. 1990, 29, 911-917.
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1/c): Zhang, Y.; Holm, R. H. Inorg. Chem. 1990, 29, 911-917.
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34247869168
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-
3SiCl. The optimum conditions for maximum yield in 6 were not optimized.
-
3SiCl. The optimum conditions for maximum yield in 6 were not optimized.
-
-
-
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131
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34247876320
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-
At this point, we do not know the exact nature of the byproducts, but we suggest that they result from electrophylic attack of the trimethylchlorosilane on either Ti-Namido or Ti-Nimido of Ti(NMe 2)4 or preformed 1 or 6
-
4 or preformed 1 or 6.
-
-
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132
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34247878962
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-
2 ligands in one of these molecules (syn vs anti).
-
2 ligands in one of these molecules (syn vs anti).
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-
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133
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34247851162
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Heating a toluene solution of 1 to higher temperatures (110°C) led to the formation of intractable products.
-
Heating a toluene solution of 1 to higher temperatures (110°C) led to the formation of intractable products.
-
-
-
-
134
-
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34247883004
-
-
3SiCl.
-
3SiCl.
-
-
-
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135
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34247870006
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3SiCl, see the following: (a) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
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3SiCl, see the following: (a) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
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0032547302
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