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77749295866
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77749265252
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3 worked well too for this reaction but was somewhat more difficult to separate from, complex 3 during the purification step
-
3 worked well too for this reaction but was somewhat more difficult to separate from, complex 3 during the purification step.
-
-
-
-
36
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77749265275
-
-
It is important to conduct the reaction under a stream of argon to remove the liberated carbon monoxide (in a closed vial the yields remained low)
-
It is important to conduct the reaction under a stream of argon to remove the liberated carbon monoxide (in a closed vial the yields remained low).
-
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37
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77749292652
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3SiCl concentration below 6 equiv
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3SiCl concentration below 6 equiv.
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44
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37049096497
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τ is the angular parameter commonly used to describe the geometry around the metal center in pentacoordinate complexes and is defined as % = (α - β)/60 (α and β are the two largest L-M-L bond angles, with α > β): Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J. V. J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
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77749292673
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77749292651
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6 by determinatiion of the cell parameters by an X-ray diffraction analysis
-
6 by determinatiion of the cell parameters by an X-ray diffraction analysis.
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65
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77749265251
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2 molecule. We believe the decomposition of our Ti/Mo compounds might be inherent to the presence of external donors such as the aniline that can further displace carbonyl ligands
-
2 molecule. We believe the decomposition of our Ti/Mo compounds might be inherent to the presence of external donors such as the aniline that can further displace carbonyl ligands.
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66
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77749292650
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Isolated compound 6 could be regarded as intermediate Å in Scheme 4 for formation of 4; however, attempted direct conversion of 6 into 4 has proved so far unsuccessful
-
Isolated compound 6 could be regarded as intermediate Å in Scheme 4 for formation of 4; however, attempted direct conversion of 6 into 4 has proved so far unsuccessful.
-
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