Mechanistic study on the cleavage and reorganization of C(sp3)-H and C=N bonds in carbodiimides: Synthesis of 1,2-dihydrothiopyrimidines and 2,3-dihydropyrimidinthiones through four-component coupling

Chemistry - A European Journal

Volumn 19, Issue 32, 2013, Pages 10643-10654

  Wang, Yang ^a   Zhao, Fei ^a   Zhou, Yi ^a   Chi, Yue ^a   Wang, Zitao ^a   Zhang, Wen Xiong ^a,b   Xi, Zhenfeng ^a  

^a PEKING UNIVERSITY   (China)

^b NANKAI UNIVERSITY   (China)

Author keywords

C H activation; multicomponent reactions; reaction intermediates; reaction mechanisms; synthetic methods

Indexed keywords

[2+2] CYCLOADDITION; C-H ACTIVATION; IN-DEPTH UNDERSTANDING; MULTI-COMPONENT REACTIONS; RATE DETERMINING STEP; REACTION MECHANISM; SYNTHETIC METHODS; THREE COMPONENT REACTIONS;

ACTIVATION ANALYSIS; SYNTHESIS (CHEMICAL);

REACTION INTERMEDIATES;

AZETIDINE DERIVATIVE; CARBON; CYANAMIDE; DEUTERIUM; HYDROGEN; NITROGEN;

ARTICLE; C H ACTIVATION; CHEMISTRY; CONFORMATION; CYCLOADDITION; MULTICOMPONENT REACTIONS; QUANTUM THEORY; REACTION INTERMEDIATES; REACTION MECHANISMS; SYNTHESIS; SYNTHETIC METHODS; X RAY CRYSTALLOGRAPHY;

C H ACTIVATION; MULTICOMPONENT REACTIONS; REACTION INTERMEDIATES; REACTION MECHANISMS; SYNTHETIC METHODS;

AZETINES; CARBODIIMIDES; CARBON; CRYSTALLOGRAPHY, X-RAY; CYCLOADDITION REACTION; DEUTERIUM; HYDROGEN; MOLECULAR CONFORMATION; NITROGEN; QUANTUM THEORY;

EID: 84880948433     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201301633     Document Type: Article

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