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Crystal data: C28H35N3O2S, Mr, 477.65 g mol-1, orthorhombic, Pbcn, a, 17.220(3, b, 11.154(2, c, 27.154(5) Å, V, 5215.4(18) Å3, Z, 8, T, 293(2) K, crystal size, 0.37 × 0.34 × 0.20 mm3, ρcalcd, 1.217 g cm -3, μ(Mo Kα, 0.153 mm-1, θmax, 27.41, measured/independent reflections, 46044/5941 (Rint, 0.0339, S, 1.064, final R1, 0.0411 (for 4456 data I > 2σ(I, Rw, 0.1090 all data, CCDC-635462 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
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w = 0.1090 (all data). CCDC-635462 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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